Pre-Variscan geological events in the Austrian part of the Bohemian Massif deduced from U–Pb zircon ages

In an attempt to elucidate the pre-Variscan evolution history of the various geological units in the Austrian part of the Bohemian Massif, we have analysed zircons from 12 rocks (mainly orthogneisses) by means of SHRIMP, conventional multi-grain and single-grain U–Pb isotope-dilution/mass-spectrometry. Two of the orthogneisses studied represent Cadomian metagranitoids that formed at ca. 610 Ma (Spitz gneiss) and ca. 580 Ma (Bittesch gneiss). A metagranite from the Thaya batholith also gave a Cadomian zircon age (567±5 Ma). Traces of Neoproterozoic zircon growth were also identified in several other samples, underlining the great importance of the Cadomian orogeny for the evolution of crust in the southern Bohemian Massif. However, important magmatic events also occurred in the Early Palaeozoic. A sample of the Gföhl gneiss was recognised as a 488±6 Ma-old granite. A tonalite gneiss from the realm of the South Bohemian batholith was dated at 456±3 Ma, and zircon cores in a Moldanubian metagranitic granulite gave similar ages of 440–450 Ma. This Ordovician phase of magmatism in the Moldanubian unit is tentatively interpreted as related to the rifting and drift of South Armorica from the African Gondwana margin. The oldest inherited zircons, in a migmatite from the South Bohemian batholith, yielded an age of ca. 2.6 Ga, and many zircon cores in both Moravian and Moldanubian meta-granitoid rocks gave ages around 2.0 Ga. However, rocks from the Moldanubian unit show a striking lack of zircon ages between 1.8 and 1.0 Ga, reflecting an ancestry from Armorica and the North African part of Gondwana, respectively, whereas the Moravian Bittesch gneiss contains many inherited zircons with Mesoproterozoic and Early Palaeoproterozoic ages of ca. 1.2, 1.5 and 1.65–1.8 Ga, indicating a derivation from the South American part of Gondwana.     

Elimination of Swimming Pool Water Disinfection By‐products with Advanced Oxidation Processes (AOPs)

Ozonation is a treatment step which was first applied in the 1960s in pool water treatment for disinfection as well as for oxidation of pool water contaminants. Contact time between ozone and pool water was identified to be of significance with an increased elimination efficiency regarding chloramines, trihalogenmethane formation potential and the permanganate index for longer reaction times. Oxidation via OH radicals might be the dominating pathway. In this study ozonation was compared with the ozone based advanced oxidation processes ozone/UV and ozone/hydrogen peroxide regarding the elimination efficiency of both disinfection by‐products (DBPs) and DBP precursors. It was observed that AOPs in comparison to ozonation showed an increased elimination efficiency regarding total organic carbon (TOC), the organically bound halogens adsorbable on activated carbon (AOX) and AOX formation potential. A contact time of 3 minutes between pool water and oxidant turned out to be practically sufficient. Just for the trihalomethane (THM) formation potential ozonation showed a slight advantage compared to the AOPs because ozonation is a highly selective oxidant and OH radical reactions are known to produce small reactive molecules which are easier transformed to THMs. Combination of membrane filtration and AOPs resulted in an elimination of 10 to 90 % of the DBPs and their precursors. The ozone/hydrogen peroxide process is suggested for pool water treatment because of the higher elimination rates compared to ozonation and of economic reasons compared to the ozone/UV process.     

Energetic Electrons as a Field Line Topology Tracer in the High Latitude Boundary/CUSP Region: Cluster Rapid Observations

Energetic electrons (e.g., 50 keV) travel along field lines with a high speed of around 20 R_Es⁻¹. These swift electrons trace out field lines in the magnetosphere in a rather short time, and therefore can provide nearly instantaneous information about the changes in the field configuration in regions of geospace. The energetic electrons in the high latitude boundary regions (including the cusp) have been examined in detail by using Cluster/RAPID data for four consecutive high latitude/cusp crossings between 16 March and 19 March 2001. Energetic electrons with high and stable fluxes were observed in the time interval when the IMF had a predominately positive B_z component. These electrons appeared to be associated with a lower plasma density exhibiting no obvious tailward plasma flow (<20 keV). On the other hand, no electrons or only spike-like electron events have been observed in the cusp region during southward IMF. At that time, the plasma density was as high as that in the magnetosheath and was associated with a clear tailward flow. The fact that no stable energetic electron fluxes were observed during southward IMF indicates that the cusp has an open field line geometry. The observations indicate that both the South and North high latitude magnetospheric boundary regions (including both North and South cusp) can be energetic particle trapping regions. The energetic electron observations provide new ways to investigate the dynamic cusp processes. Finally, trajectory tracing of test particles has been performed using the Tsyganenko 96 model; this demonstrates that energetic particles (both ions and electrons) may be indeed trapped in the high latitude magnetosphere.     

Holocene recolonization and extinction of the pond turtle, Emys orbicularis (L., 1758), in Europe

We reconstruct the Holocene range fluctuations of the European pond turtle (Emys orbicularis) for northern and Central Europe. Based on 529 subfossil records and radiocarbon dating of critical finds, we provide evidence that E. orbicularis experienced a rapid range expansion with Holocene warming. Phylogeographic data argue for a colonization of northern and Central Europe from a glacial refuge located in the south-eastern Balkans. Already in the Late Preboreal (9100–8600 cal BC) the species occurred in northern Central Europe and was widespread in Denmark and southern Sweden (Skåne) during the Boreal (8600–7100 cal BC). The maximum range extension occurred during the Holocene climatic optimum (Atlantic: 7100–3750 cal BC), with records in southern England, middle Sweden, and northern Estonia. After the early Subboreal (3750–1750 cal BC) northern populations collapsed, coinciding with a climatic cooling and oceanization. Northern populations were most likely established via long distance dispersal (rafting using rivers debouching in the North and Baltic Seas); after northern Europe was reached, a minimum dispersal of 50 km per 100 years may be hypothesized for the Boreal.     

Conventional and in situ geochronology of the Teplá Crystalline unit, Bohemian Massif: implications for the processes involving monazite formation

The Teplá Crystalline unit (TCU), western Bohemian Massif, proves highly suitable for studying the effects of differential metamorphic reworking on the U–Th–Pb systematics in monazite, as the overprint of Variscan regional metamorphism onto high-grade Cadomian paragneisses intensifies progressively towards the northwest. Although variably hampered by scarcity, small size, and low uranium contents of monazite, isotope dilution–thermal ionisation mass spectrometry of monazite from paragneisses from the garnet, staurolite, and kyanite zones of the TCU gives a narrow ²⁰⁶Pb/²³⁸U age range from 387 to 382 Ma for Variscan peak metamorphism. These data are supported by 382–373 Ma monazite ages derived from electron microprobe analyses. Inheritance of older components in grains from the central TCU imply major “resetting” of pre-Variscan monazite around 380 Ma, possibly due to widespread garnet growth during Variscan metamorphism, which led to the consumption of pre-Variscan high-Y monazite and subsequent growth of new low-Y monazite. Concordant 498–494 Ma monazite ages in a migmatitic paragneiss close to the adjacent Mariánské Lázně Complex (MLC) grew in response to metagabbro emplacement in the MLC from 503 to 496 Ma and not during either Cadomian or Variscan regional metamorphism. Backscatter imaging and electron microprobe analyses reveal that discordant monazite of the migmatite comprises a mix of various age domains that range from ca. 540 to 380 Ma. Combined evidence presented here suggests that instead of Pb loss by volume diffusion, the apparent resetting of the U–Th–Pb systematics in monazite rather involves new crystal growth or regrowth by recrystallisation and dissolution/reprecipitation.     

Chemical alteration in the micro weathering environment within a spheroidally-weathered anorthosite boulder

A chemical and mineralogical study of the innermost rindlets of a spheroidally weathered boulder from the Wichita Mountains, Oklahoma details incipient alteration of minerals along solution channels. Alteration products in plagioclase areas are highly aluminous, whereas ferruginous residuum is commonly found in olivine alteration zones. Alteration of plagioclase along solution channels results in sharp weathering contacts as contrasted with wider zones of “limonite” bordering solution channels in olivine. In certain instances, cores of fresh olivine are surrounded by limonite indicating that diffusion may play a role in this type of alteration.Mobility of sesquioxides is evidenced by aluminum-rich debris adjacent to mafic materials in solution channels and iron-bearing material in channels cutting through plagioclase. Not resolved is whether the movement of sesquioxides in solution channels is by transport of colloidal particulates or by diffusion of dissolved species.Calcic plagioclase alters to calcite along the innermost solution channel. It is postulated that solution, exterior to the boulder and undersaturated with respect to calcite, enters the rind system via solution channels. Cut off from the CO₂ reservoir of the atmosphere by the narrow confines of this solution channel, the solution reacts with the bytownite to precipitate calcite.Apart from the occurrence of calcite, no crystalline weathering products were found in the innermost rindlet samples. A poorly crystallized illite was identified in the outermost rindlet. These findings suggest that initial alteration products on weathering rinds are amorphous and that, with time, these products attain a degree of identifiable crystallinity.     

Corry bog, pennsylvania: A case study of the radiocarbon dating of marl

New radiocarbon dates, carbon and oxygen isotope analyses of mollusks and marl, and palynologic analysis have clarified age relationships at the Corry kettle bog in northwestern Pennsylvania. A 4000-yr difference in radiocarbon dates between basal peat and marl top, previously interpreted as caused by the presence of an unconformity, is reinterpreted as due to “hard-water effects” from carbonate bedrock and glacial deposits. A radiocarbon date of 14,000 yr from basal marl, previously used as a minimum age for glacial deposition, is also likely too old; instead a similar age is estimated for the base of the underlying lake clay. Radiocarbon dates on marl should be used with caution and supported by isotopic and pollen analyses.     

Construction on dolomite in south Africa

Damage to structures and loss of life have been more severe on dolomite than on any other geological formation in southern Africa. The subsidence that occurs on dolomitic terrain following development or during dewatering has given dolomite a notorious reputation and engineers and geologists became reluctant to recommend development on the material. This has led to the pioneering of founding methods for a wide variety of structures aimed at reducing the risk of severity of damage due to subsidence settlement Structures successfully founded on dolomitic terrane include residential and industrial buildings, gold mine reduction works and shaft structures, tailings dams, water retaining structures, and road and rail links. In this article, various methods of construction, some ot which were developed by the authors, are presented. It commences with a classification of a dolomite site in terms of overburden thickness followed by a discussion of the relevant construction methods The methods include mattresses of compacted soil supported by pinnacles or “floating” in residuum, deep foundations such as caissons, the use of specialized piling techniques, and soil improvement by dynamic consolidation     

Die Berechnung der Angströmschen Trübungskonstanten aus Sonnenstrahlungsmessungen in verschiedenen Filtergebieten

Zusammenfassung Zur Bearbeitung von mehreren hundert Messungen der direkten Sonnenstrahlung mit fünf verschiedenen Farbfiltern werden Neuberechnungen derAngstr?mschen Formel (Gleichung 1) für die einzelnen Wellenl?ngen mit insgesamt 144 verschiedenen Werten für die Luftmassem, den Wellenl?ngenexponenten α der Zerstreuungsfunktion, dem Trübungskoeffizienten β und dem WasserdampfgehaltW der Atmosph?re durchgeführt. Es wurde hierbei festgestellt, da? es m?glich ist, die Filterdifferenzen für die Spektralbereiche Blau, Gelb, Rot und zwei Infrarot durch einfache algebraische Formeln darzustellen (Gleichungen 3 und 5), aus denen α und β errechnet werden k?nnen (Gleichungen 6 und 7). Bezüglich des Wasserdampfgehaltes ergab sich, da? es nicht m?glich ist, die Wasserdampfabsorption durch ein einziges Gliedf(mW) darzustellen, das additiv zu dem Zerstreuungsterm derAngstr?mschen Formel hinzugefügt wird, wie es bisher meist geschah. Es wurde eine neue Fassung des additiven Gliedes für die Wasserdampfabsorptionf(α, β, m, mW) berechnet und durch eine Formel (12) wiedergegeben. Auf die Bedeutung der neuen Absorptionsfunktion des Wasserdampfes für die vom Verfasser kürzlich entwickelte Kalibrierung der Aktinometer aus dem Beobachtungsmaterial wird eingegangen (Gleichung 14). Zum Schlu? werden neue Gleichungen (20) entwickelt, die die Bestimmung von α im langwelligen Spektralgebiet der Sonnenstrahlung erm?glichen, in dem auch der Wasserdampf absorbiert. Dies ist wichtig, weil das α, das bisher nur aus dem kurzwelligen Teil des Sonnenspektrum bestimmt werden konnte, nicht notwendig übereinzustimmen braucht mit dem α im langwelligen Gebiet.

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Summary DeterminingAngstr?m’s turbidity constants from several hundred sets of readings of the solar radiation with five different glass filters,Angstr?m’s formula (equ. 1) was calculated for a total of 144 different values of air massesm, the wavelength exponent α of the scattering function, the turbidity coefficient β and water vapour content W of the atmosphere. It was found that it is possible to express the filter differences belonging to the spectral ranges blue, yellow, red, and two infrared ranges with simple algebraic formulae (equ. 3 and 5) which allow α and β to be calculated (equ. 6 and 7). With respect to the water vapour content it was pointed out that it is impossible to express, in the usual way, the water vapour absorption by a single termf(mW), which is added to the scattering term ofAngstr?m’s formula. A new form of the water vapour absorption was calculated and expressed as a formula (12). The significance of the new water vapour absorption function was discussed with reference to the author’s newly developed actinometer calibration from observational data (equ. 14). In conclusion new equations (20) were derived enabling to be determined in the long wave range of solar radiation, i.e. where the water vapour absorption exists. This is important because so far α could only be determined from the short wave range of solar radiation, which does not necessarily agree with that of the long wave range.

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Dr. Fritz H. W. Albrecht, 10, Belgravia Ave., Box Hill North E 12,Melbourne.