Geochemical modelling of fluid–rock interactions in the context of the Soultz-sous-Forêts geothermal system

The development of the Enhanced Geothermal System (EGS) at Soultz-sous-Forêts (France) has given to scientists an interesting opportunity for the application of geochemical modelling of water–rock interactions, combining theoretical studies with field and experimental data. The main results of four successive and complementary studies are summarized: geochemical modelling of fluid–rock interactions with prediction of dissolution/precipitation of minerals, feed-back effects on the mineralogy and petrography of the rock (major role of silicates in the geological past and of carbonates in the near future of the exploitation), experimental control of the dynamics of silicates under thermal gradient and relation between the evolution of the petrophysics of the rocks and the heat and mass transfers. The thermal cycle of the fluid, between 200 °C and 65 °C in the geothermal loop, may be responsible for dissolution/precipitation of minerals which modify the porosity and permeability of the granite, as it happened in the geological past, in relation with hydrothermal circulations in the Rhine Graben.     

Conversion of carbonaceous material to graphite within the Greywacke Zone of the Eastern Alps

Morphology and reflectance of carbonaceous material (CM) in Late Carboniferous metasediments of the eastern Greywacke Zone (Eastern Alps) indicate a mixture of vitrinite, grainy textured and lamellar shaped particles. As imaged by high-resolution atomic-force microscopy, vitrinite and the grainy textured particles show mesophase structures which can be described as facetted nanocrystals within the carbon matrix. High-resolution transmission electron microscopy has revealed two types of microtextures representing different degrees of graphitization. The first type is characterized by elongated ring-shaped microtextures, whereas the second type is characterized by graphite lamellae and polygonal flakes with long-range ordered aromatic layers. In spite of the heterogeneity of the CMs, the geographical distribution of quantitative metamorphic parameter (Raman spectra parameter, X-ray diffraction pattern, microscopic reflectance) suggests a graphitization process which is promoted by advective heat transport during post-collisional processes. In a tentative pressure-time path, Late Cretaceous thrusting results in a turbostratic ordering of the aromatic layer. Ordering to long-range ordered aromatic layers was achieved during the Late Cretaceous-Paleogene exhumation of mid-crustal rocks beneath the eastern Greywacke Zone.     

Coupling between Primary Terrestrial Succession and the Trophic Development of Lakes at Glacier Bay, Alaska

The natural eutrophication of lakes is still an accepted concept in limnology, arising as it does from the earliest efforts to classify lakes and place them in an evolutionary sequence. Recent studies of newly formed lakes at Glacier Bay, Alaska, only partially support this idea, and suggest more variable trends in lake trophic development which are under local (catchment-level) control. Here we use sediment cores from several lakes in Glacier Bay National Park to examine the relationship between successional changes in catchment vegetation and trends in water-column nitrogen (a limiting nutrient) and lake primary production. Terrestrial succession at Glacier Bay follows several different pathways, with older sites in the lower bay being colonized directly by spruce (Picea) and by-passing a prolonged alder (Alnus) stage that characterizes younger upper-bay sites. Sediment cores from three sites spanning this successional gradient demonstrate that the variability in nitrogen trends among lakes is a consequence of the establishment and duration of N-fixing alder in the lake catchment. In the lower-bay lakes, diatom-inferred nitrogen concentrations rise and then fall in concert with the transient appearance of alder in the catchment, while in the upper bay, high nitrogen concentrations are sustained by the continuous dominance of alder. Diatom accumulation, a proxy for whole-lake biological productivity, increases steadily at all three sites during the first century following lake formation, but declines in more recent times at the lower-bay sites in apparent response to the disappearance of alder and decreasing lake-water nitrogen. These results demonstrate a tight biogeochemical coupling between terrestrial succession and lake trophic change during the early developmental history of Glacier Bay lakes.     

Multiple Flux Rope Events at the High-Latitude Magnetopause: Cluster/Rapid Observation on 26 January, 2001

Cluster measurements of the cusp and high latitude magnetopause boundary on 26 January, 2001 confirm that the cusp is a dynamic region full of energetic charged particles and turbulence. An energetic ion layer at high-latitudes beyond and adjacent to the duskside magnetopause exists when the Interplanetary Magnetic Field (IMF) has a southward orientation. Multiple energetic ion flux bursts were observed in the energetic ion layer. Each energetic ion flux burst was closely related to a magnetic flux rope. The axes of the flux ropes lie in the direction pointing duskward/tailward and somewhat upward. An intense axis-aligned current flows inside the ropes, with the current density reaching ∼10⁻⁸ A/m². The main components of the energetic ions are protons, helium and CNO ions, which originate from the magnetosphere, flowing out into the magnetosheath along the axis of the flux ropes. The velocity of the magnetosheath thermal plasma relative to the deHoffman-Teller (DHT) frame is found to be basically along the axis of the flux ropes also, but towards the magnetosphere. These flux ropes seem to be produced somewhere away via magnetic reconnection and move at similar DHT velocities passing over the spacecraft. These observations further confirm that the high-latitude magnetopause boundary region plays an important role in the solar wind-magnetopause coupling.     

Observations of a Unique Cusp Signature at Low and Mid Altitudes

Observations of a unique cusp feature at low and mid altitudes are reported. This feature has a consistent double-peaked or “V”-shaped structure at the equatorward edge of high-latitude particle precipitation flux, and is predominantly present for high IMF B_y conditions. The observations are consistent with the Crooker (‘A split separator line merging model of the dayside magnetopause’, J. Geophys. Res. 90 (1985) 12104, ‘Mapping the merging potential from the magnetopause to the ionosphere through the dayside cusp’, J. Geophys. Res. (1988) 93 7338.) antiparallel merging model, which predicts a narrow wedge-shaped cusp whose geometry depends greatly on the dawn/dusk component of the IMF. Various observations are presented at low altitudes (DE-2, Astrid-2, Munin, UARS, DMSP) and at mid altitudes (DE-1, Cluster) that suggest a highly coherent cusp feature that is consistent with the narrow, wedge-shaped cusp of Crooker (1988), and contains persistent wave signatures that are compatible with previously reported high-altitude measurements. A statistical survey of Astrid-2 and DMSP satellite data is also presented, which shows this feature to be persistent and dependent on the IMF angle at the magnetopause, as expected. Thus, the cusp signatures observed at a wide range of altitudes present a coherent picture that may be interpreted in terms of a footprint of the magnetopause current layer.     

Simulation Studies of High-Latitude Magnetospheric Boundary Dynamics

Magnetic reconnection at the high-latitude magnetopause is studied using 2–1/2-dimensional (2−1/2-D) Hall-MHD simulation. Concentric flow vortices and magnetic islands appear when both Hall effect and sheared flow are considered. Plasma mixing across the magnetopause occurs in the presence of the flow vortices. Reconnected structure generated in the vicinity of the subsolar point changes its geometry with increasing flow shear while moving to high latitudes. In the presence of flow shear, with the Hall-MHD reconnection a higher reconnection rate than with the traditional MHD is obtained. The out-of-plane components of flow and magnetic field produced by the Hall current are redistributed under the action of the flow shear, which makes the plasma transport across the boundaries more complicated. The simulation results provide some help in understanding the dynamic processes at the high-latitude magnetopause.     

Ein räumlichesn-Schichtenproblem der Refraktionsseismik

Zusammenfassung Es wird vorausgesetzt, die Erdoberfläche sei eben und der Untergrund bestehe aus homogenen, isotropen Schichten, die durch Ebenen voneinander getrennt sind. Da diese Ebenen beliebige Lage haben, handelt es sich um ein räumlichesn-Schichten-Problem. Es wird gezeigt, wie die Frontgeschwindigkeiten und die Unstetigkeitsflächen mit Hilfe der seismischen Refraktionsmethode bestimmt werden können.

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Summary It is assumed that the subsoil is bounded by a plane surface and that plane interfaces of arbitrary position subdivide the subsoil into homogeneous isotropic solid layers. (Three dimensionaln-layer problem.) A method is presented to compute the front velocities and the positions of the interfaces in the subsoil on the basis of suitable seismic refraction measurements.

     

Sedimentological and palynological constraints on the basal Triassic sequence in Central Switzerland

In Central Switzerland, Mesozoic sedimentation began after erosion and peneplainisation of the Hercynian relief and late Paleozoic continental deposition in SW-NE striking pull-apart basins. The first Triassic sedimentary sequence overlaying a weathered crystalline basement consists of a relatively thin (<10 m), lithologically highly variable unit with coarse-grained siliciclastic deposits at the base, grading into a mixed sandstone/shale-dolomite sequence followed by well-bedded dolomites with chert nodules.Sedimentary texture analyses and petrological investigations revealed four different sedimentary units starting at the base with a regolith unit that represents the weathered crystalline basement. It is overlain by terrestrial plain deposits, followed by mixed siliciclastic-carbonaceous sediments and a sequence of dolomites, deposited between the supralittoral and eulittoral zones of a tidal flat (Mels-Formation), and the eulittoral to sublittoral zones of a carbonate tidal flat environment (Röti-Dolomit), respectively.Palynological data from four localities in Central Switzerland indicate a heterochronous early Anisian age (Aegean – Bithynian/Pelsonian) for the supra- to eulittoral mixed siliciclastic-carbonaceous sediments. These new biostratigraphic ages suggest that the first Triassic marine transgression in Central Switzerland is time equivalent with those of the basal Wellendolomit in Northern Switzerland but slightly older than in the Germanic Basin. Consequently, Central Switzerland was located at this time at the northern shoreline of the Tethys and not on the southern limit of the Germanic Basin.