The first ascent to the volcano Cotopaxi in Ecuador by Wilhelm Reiss (1838–1908)

The volcano Cotopaxi in South America is 5,897 m high and is one of the highest active volcanoes of the world and the second highest volcano in the Andes after the Chimborazo (6,310 m). In Ecuador, there are more than 20 volcanoes contributing to the spectacular mountain range diving this country between the western and eastern lowlands. There have been more than 50 reports of volcanic activity at Cotopaxi since 1738, among which those from the years 1744, 1768, and 1877 are the largest. During the 1877 eruption, the whole summit glacier collapsed and a huge mudflow spread out for more than 100 km and flooded the city of Latacunga. Five years prior to this catastrophic event, the German geologist Wilhelm Reiss from the University of Heidelberg ascended Cotopaxi for the first time together with his supporter Angel M. Escobar from Columbia.     

Hydraulic fracturing: a toxicological threat for groundwater and drinking-water?

This paper deals with the possible impact of hydraulic fracturing (fracking), employed in the exploitation of unconventional shale gas and tight gas reservoirs, on groundwater, which is the most important source of drinking-water in Germany and many other European countries. This assessment, which is part of an interdisciplinary study by a panel of neutral experts on the risks and environmental impact of hydraulic fracturing, is based mainly on data obtained from three ExxonMobil drilling sites in northern Germany. First, the basic technical aspects of fracking and its relevant water fluxes are explained. The type, purpose and fate of the constituents of the fracking fluids are discussed. The chemicals used in the fracking fluids are assessed with regard to their hazardous properties according to the Regulation (EC) No. 1272/2008 of the European Parliament and of the Council on the classification, labelling and packaging of substances and mixtures (CLP regulation) and the German “Water Hazard Classes”. Contamination of groundwater by ingredients of fracking fluids may occur from under ground or may result from above-ground accidents associated with the transport, storage and handling of hazardous substances used as additives in fracking fluids. The degree of groundwater contamination cannot be predicted in a general way. Therefore, different dilutions of the fracking fluid in groundwater are considered. It is shown that the concentrations of most ingredients resulting from a 1:10,000 up to 1:100,000 dilution of the fracking fluid in groundwater are below health-based reference values such as the limit values of the European Drinking Water Directive, the WHO Guideline Values for Drinking-water Quality, and other health-based guide values for drinking-water. Regarding the salinity of fracking fluids, a dilution of 1:1,000 is sufficient to reach concentrations which are acceptable for drinking-water. From the human-toxicological point of view, the constituents of flowback water are more problematic with respect to drinking-water produced from groundwater than those of the fracking fluids. The few reliable data which have become available, as well as hydrogeological considerations, point in the direction of considerable salt concentrations and toxic constituents, e.g., Hg, As, Pb, Zn, Cd, BTX, PAHs, or even radioactive elements. The identification and assessment of reaction products and metabolites, which are produced as a result of the fracking operation and the metabolic activity of microorganisms, are important topics for further research. The recommendations include the need for a better understanding of the environmental impact of fracking operations, especially with regard to the development of sustainable rules for planning, permission, performance and management of fracking, and for the monitoring of groundwater quality around fracked drilling sites.     

Experimental evidence for the potential impact ejection of viable microorganisms from Mars and Mars-like planets

Bacterial spores (Bacillus subtilis), cyanobacteria (Chroococcidiopsis sp.), and lichen (Xanthoria elegans) embedded in martian analogue rock (gabbro) were exposed to shock pressures between 5 and 50 GPa which is the range of pressures observed in martian meteorites. The survival of Bacillus subtilis and Xanthoria elegans up to 45 GPa and of Chroococcidiopsis sp. up to 10 GPa supports the possibility of transfer of life inside meteoroids between Mars and Earth and it implies the potential for the transfer of life from any Mars-like planet to other habitable planets in the same stellar system.     

Scale of relief growth in the forearc of the Andes of Northern Chile (Arica latitude, 18°S)

The stream profiles of rivers of northern Chile reveal two graded segments separated by 20‐km‐long knickzones. Their formation was initiated in the Late Miocene in response to surface uplift of the western flank of the Altiplano. This phase of uplift that was coeval with the shift of deformation from the Altiplano to the sub‐Andean zone caused relief to grow at the scale of the whole drainage basin. Above and beneath these knickzones, the presence of braided channels and the absence of erosion on adjacent pediplains suggest no substantial modification in the local relief. The knickzones, however, show bedrock channels, and fluvial dissection rates have exceeded erosion rates on adjacent pediplains by two orders of magnitudes. Hence, the data imply that the only geomorphic recorders of relief growth are the knickzones that currently transpose the effects of the Late Miocene phase of surface uplift from the coast to the Altiplano.     

Limits of sediment transfer in an alpine debris-flow catchment,Illgraben, Switzerland

The 9.5 km² Illgraben catchment, located in the Rhône valley in the Central Alps of Switzerland, is one of the most active debris flow torrents in the Alps. In this paper we present sediment yield data collected in 2006 for segments where hillslopes and channels form a fully connected network and contrast these with sediment yields measured for disconnected hillslopes. The data reveal that sediment yields are 1–2 orders of magnitude larger in segments where hillslopes are connected with the channel network than on disconnected hillslopes. Support for this conclusion is provided by observations made on 1959, 1999 and 2004 aerial photographs that the vegetation cover in the disconnected segments is still intact, whereas denudation rates of several centimeters per year in the connected segments have inhibited the establishment of a stable vegetation cover. Furthermore, sediment supplied from hillslopes during the past 40 years has temporarily accumulated along the Illgraben channel, indicating that the channel aggraded over this period and has not yet recovered. An implication of this observation is that initiation of debris flows in the Illgraben catchment is limited more by the availability of intense rainfall than sediment. In contrast, on disconnected hillslopes, sediment flux does not appear to be driven by precipitation.The petrographic composition of the Illgraben fan deposits indicates two distinct sediment sources, one related to rockfall and the other to landslides and debris flows. The presence of clasts from both sources implies multiple processes of erosion, deposition, mixing and re-entrainment in the catchment before the material is exported to the Illgraben fan and to the Rhône River. In addition, delivery of large amounts of coarse-grained sediment to the Rhône causes a modification of the flow pattern from meandering or anastomosing upstream to braided downstream. Hence, the direct connectivity between hillslope and channelized processes in the Illgraben catchment causes not only rapid topographic modifications in the catchment, but also morphologic adjustment in the Rhône valley downstream.     

The dilemma of disappearing diatoms: Incorporating diatom dissolution data into palaeoenvironmental modelling and reconstruction

Taphonomic issues pose fundamental challenges for Quaternary scientists to recover environmental signals from biological proxies and make accurate inferences of past environments. The problem of microfossil preservation, specifically diatom dissolution, remains an important, but often overlooked, source of error in both qualitative and quantitative reconstructions of key variables from fossil samples, especially those using relative abundance data. A first step to tackling this complex issue is establishing an objective method of assessing preservation (here, diatom dissolution) that can be applied by different analysts and incorporated into routine counting strategies. Here, we establish a methodology for assessment of diatom dissolution under standard light microscopy (LM) illustrated with morphological criteria for a range of major diatom valve shapes. Dissolution data can be applied to numerical models (transfer functions) from contemporary samples, and to fossil material to aid interpretation of stratigraphic profiles and taphonomic pathways of individual taxa. Using a surface sediment diatom-salinity training set from the Northern Great Plains (NGP) as an example, we explore a variety of approaches to include dissolution data in salinity inference models indirectly and directly. Results show that dissolution data can improve models, with apparent dissolution-adjusted error (RMSE) up to 15% lower than their unadjusted counterparts. Internal validation suggests improvements are more modest, with bootstrapped prediction errors (RMSEP) up to 10% lower. When tested on a short core from Devils Lake, North Dakota, which has a historical record of salinity, dissolution-adjusted models infer higher values compared to unadjusted models during peak salinity of the 1930s–1940s Dust Bowl but nonetheless significantly underestimate peak values. Site-specific factors at Devils Lake associated with effects of lake level change on taphonomy (preservation and re-working, implied by dissolution data) may override model improvements incorporating dissolution. Dissolution-adjusted salinity models are also applied to a 150-year sediment record from Spiritwood Lake, North Dakota, which suggests that this lake has a damped and lagged response to major regional climate forcing of salinity during the Dust Bowl. At this site, dissolution data also suggest different taphonomic behaviour of taxa related to their seasonal patterns of growth and sedimentation. Thus, dissolution data can improve models, and aid interpretation of sedimentary profiles as records of limnological, ecological and environmental change, filtered by taphonomy.     

Revisiting the infrared spectra of active galactic nuclei with a new torus emission model

We describe improved modelling of the emission by dust in a toroidal-like structure heated by a central illuminating source within active galactic nuclei (AGNs). We have chosen a simple but realistic torus geometry, a flared disc, and a dust grain distribution function including a full range of grain sizes. The optical depth within the torus is computed in detail taking into account the different sublimation temperatures of the silicate and graphite grains, which solves previously reported inconsistencies in the silicate emission feature in type 1 AGNs. We exploit this model to study the spectral energy distributions (SEDs) of 58 extragalactic (both type 1 and type 2) sources using archival optical and infrared data. We find that both AGN and starburst contributions are often required to reproduce the observed SEDs, although in a few cases they are very well fitted by a pure AGN component. The AGN contribution to the far-infrared luminosity is found to be higher in type 1 sources, with all the type 2 requiring a substantial contribution from a circumnuclear starburst. Our results appear in agreement with the AGN unified scheme, because the distributions of key parameters of the torus models turn out to be compatible for type 1 and type 2 AGNs. Further support to the unification concept comes from comparison with medium-resolution infrared spectra of type 1 AGNs by the Spitzer observatory, showing evidence for a moderate silicate emission around 10 μm, which our code reproduces. From our analysis we infer accretion flows in the inner nucleus of local AGNs characterized by high equatorial optical depths  ( A_V ≃ 100)  , moderate sizes  ( R _max < 100 pc)  and very high covering factors (   f ≃ 80  per cent) on average.