TOF‐SIMS analysis of Allende projectiles shot into silica aerogel

Abstract— Powdered Allende projectiles were fired into silica aerogel at 6.1 km/sec in order to evaluate particle retrieval and analysis techniques for samples from the Stardust mission. Since particles may disintegrate and ablate along the penetration paths in a high‐porosity aerogel, TOF‐SIMS analysis may be a suitable method to determine the distribution of such materials along the tracks as well as potential compositional modifications. Therefore, two ?350 μm‐sized tracks, residing at the surface of a keystone specimen that was flattened between two silicon chips, were analyzed. TOF‐SIMS allows for a detailed study of the chemical composition of particles that survived the impact mostly intact and of fine‐grained material from disintegrated projectiles. In the investigated keystone, material from light gas gun debris dominated. Besides the two tracks, a continuous, 40‐μm‐thick surface layer of implanted material—probably gun residue—was found. One of the two analyzed tracks is compositionally distinct from this surface layer and is likely to contain residual material of an Allende projectile. The analyses clearly demonstrate that tracks, resulting from impactors in the 5–10 μm size range, can be successfully analyzed with TOF‐SIMS.     

http://www.sciencedirect.com/science/article/pii/S1674987112001569

The southeastern Anatolia comprises numbers of tectono-magmatic/stratigraphic units such as the metamorphic massifs,the ophiolites,the volcanic arc units and the granitoid rocks.All of them play important role for the late Cretaceous evolution of the southern Neotethys.The spatial and temporal relations of these units suggest the progressive development of coeval magmatism and thrusting during the late Cretaceous northward subduction/accretion.Our new U-Pb zircon data from the rhyolitic rocks of the wide-spread volcanic arc unit show ages of(83.1±2.2)-(74.6±4.4) Ma. Comparison of the ophiolites,the volcanic arc units and the granitoids suggest following late Cretaceous geological evolution.The ophiolites formed in a suprasubduction zone(SSZ) setting as a result of northward intra-oceanic subduction.A wide-spread island-arc tholeiitic volcanic unit developed on the top of the SSZ-type crust during 83-75 Ma.Related to regional plate convergence, northward under-thrusting of SSZ-type ophiolites and volcanic arc units was initiated beneath the Tauride platform(Malatya-Keban) and followed by the intrusion of l-type calc-alkaline volcanic arc granitoids during 84-82 Ma.New U-Pb ages from the arc-related volcanic-sedimentary unit and granitoids indicate that under-thrusting of ophiolites together with the arc-related units beneath the Malatya-Keban platform took place soon after the initiation of the volcanic arc on the top of the SSZtype crust.Then the arc-related volcanic-sedimentary unit continued its development and lasted at～75 Ma until the deposition of the late Campanian—Maastrichtian shallow marine limestone.The subduction trench eventually collided with the Bitlis-Ptrge massif giving rise to HP-IT metamorphism of the Bitlis massif.Although the development of the volcanic arc units and the granitoids were coeval at the initial stage of the subduction/accretion both tectono-magmatic units were genetically different from each other.     

Spectroscopic characterisation and crystal field calculations of varicoloured kyanites from Loliondo, Tanzania

Orange, ochre-coloured, light green and dark blue varieties of kyanite, ideally Al₂SiO₅, from Loliondo, Tanzania, have been characterised by electron microprobe analysis and polarised infrared and optical absorption spectroscopy. All colour varieties show elevated Fe contents of 0.39 to 1.31 wt.% FeO, but Ti contents only in the range of the EMP detection limit. Orange and ochre-coloured crystals have Mn contents of 0.23 and 0.06 wt.% MnO, respectively, the dark blue kyanite contains 0.28 wt.% Cr₂O₃, while the light green sample is nearly free from transition metal cations other than Fe. Polarised infrared spectra reveal OH defect concentrations of 3 to 17 wt.ppm H₂O with structural OH defects partially replacing the O_B (O2) oxygen atoms. Polarised optical absorption spectra show that the colour of all four varieties is governed by crystal field d-d transitions of trivalent cations, i.e. Fe³⁺ (all samples), Mn³⁺ (orange and ochre) and Cr³⁺ (blue kyanite), replacing Al in sixfold coordinated triclinic sites of the kyanite structure. Intervalence charge transfer, the prevalent colour-inducing mechanism in ‘usual’ (Cr-poor) blue kyanites, seems to play a very minor, if any, role in the present samples. Crystal field calculations in both a ‘classic’ tetragonal and in the semiempirical Superposition Model approach, accompanied by distance- and angle-least-squares refinements, indicate that Fe³⁺ preferably occupies the Al4 site, Cr³⁺ prefers the Al1 and Al2 sites, and Mn³⁺ predominantly enters the Al1 site. In each case specific local relaxation effects were observed according to the crystal chemical preferences of these transition metal cations. Furthermore, the high values obtained in the calculations for the interelectronic repulsion parameter Racah B correspond to a high ionic contribution to Me³⁺–O bonding in the kyanite structure. In the particular case of the blue sample, band positions specifically related to the high Racah B value enable this ‘unusual’ type of blue colouration of kyanite solely due to Cr³⁺ cations.     

Why is the Eastern Baltic cod recovering?

The Eastern Baltic cod stock was until recently below safe biological limits and suffered from high fishing pressure. In most recent years, fishing mortality substantially declined and spawner biomass more than tripled. Similar developments have not been observed for any other depleted cod stock in the North Atlantic during the last few decades. This paper investigates relative impacts of changes in different ecological and management-related drivers, which could have contributed to the rapid recovery of the Eastern Baltic cod. The results show that the success to reduce fishing mortality below management target in 2008 was due to a combination of increased recruitment and improved compliance with TAC. The reversal of the negative trend in biomass and rebuilding of the stock to the present level were largely driven by increased recruitment. Harvest control rules of the multi-annual management plan for setting TACs currently maintain the fishing mortality at a low level, which allows the stock to accumulate biomass and further accelerate its recovery. Relatively strong incoming year-classes and recently better control over removals distinguish the Eastern Baltic cod from other depleted European cod stocks, which have not shown similar positive trends in recent years. Sound management measures and compliance to those as well as favourable biological conditions are required for a successful stock recovery.     

Effects of ambient and boat noise on hearing and communication in three fish species living in a marine protected area (Miramare, Italy)

The WWF-Natural Marine Reserve of Miramare (Trieste, Italy) is located in a major industrial and vacation area in the Adriatic Sea. Consequently, noise emanating from boating and shipping is an inevitable factor for local fishes. This study investigates the effects of ambient and ship noise on representatives of three vocal fish families with different hearing abilities. Ambient and ship noise were recorded, their sound pressure levels measured and played back in the lab. Auditory sensitivity was determined in Chromis chromis, Sciaena umbra and Gobius cruentatus, utilizing the auditory evoked potential recording technique. Compared to lab conditions, hearing thresholds determined during ambient noise playbacks were barely masked. Contrary, the noise emanating from a cabin-cruiser substantially reduced auditory sensitivity relative to thresholds in ambient noise. This masking effect was most pronounced in the frequency range where acoustic communication takes place. Boat noise potentially affects acoustic communication in fishes inhabiting the reserve.     

ISCO for Groundwater Remediation: Analysis of Field Applications and Performance

A critical analysis of in situ chemical oxidation (ISCO) projects was performed to characterize situations in which ISCO is being implemented, how design and operating parameters are typically employed, and to determine the performance results being achieved. This research involved design of a database, acquisition and review of ISCO project information, population of the database, and analyses of the database using statistical methods. Based on 242 ISCO projects included in the database, ISCO has been used to treat a variety of contaminants; however, chlorinated solvents are by far the most common. ISCO has been implemented at sites with varied subsurface conditions with vertical injection wells and direct push probes being the most common delivery methods. ISCO has met and maintained concentrations below maximum contaminant levels (MCLs), although not at any sites where dense nonaqueous phase liquids (DNAPL) were presumed to be present. Alternative cleanup levels and mass reduction goals have also been attempted, and these less stringent goals are met with greater frequency than MCLs. The use of pilot testing is beneficial in heterogeneous geologic media, but not so in homogeneous media. ISCO projects cost $220,000 on average, and cost on average $94/yd³ of target treatment zone. ISCO costs vary widely based on the size of the treatment zone, the presence of DNAPL, and the oxidant delivery method. No case studies were encountered in which ISCO resulted in permanent reductions to microbial populations or sustained increases in metal concentrations in groundwater at the ISCO-treated site.     

On A Low Cloud Phenomenon At The Breidamerkurjökull Glacier, Iceland

An impressive cloud wall has frequently been observed on the southern slopes of the Vatnajökull ice sheet, which is located in south-eastern Iceland. Its optical and dynamic features suggest a delicate balance of the atmospheric agents involved. This has been confirmed by a thorough analysis of a well documented event and by statistics covering a whole summer season. As an exemplary event, the regional development of the associated cloud has basically been documented with synchronous surface data along a suitable transect of the glacier. Data from tethered balloons, radiosoundings and routine synoptic data have also been exploited extensively. Cloud development was generally aided by a high moisture potential because of proximity to the open seas and the remnants of a frontal system. Furthermore the occurrence of the cloud phenomenon was associated with onshore (southerly) surface winds, assisting advection and lifting of the associated air masses above the slopes of the ice sheet. Northward protrusion of the associated cloud was apparently opposed by continuous katabatic winds and topographically induced lee effects.