Arsenic anomalies in shallow Venetian Plain (Northeast Italy) groundwater

A pilot area within the Venetian Plain was selected to assess the arsenic (As) contamination of groundwater. The area represents a typical residential, industrial and agricultural organization representative of most western countries, and is also devoid of lithologies with high or anomalous As content. Hydrogeological and chemical data have been collected, the latter spatialized by a geostatistical approach. The unconfined aquifer reservoir varies from a predominantly gravel composition in the north to a sandy and silt–clay composition further south, including peat layers. The hydrochemical features of the waters are rather homogeneous, featuring low mineral content and a Ca-bicarbonate signature. In contrast, the redox state is highly variable; oxidizing conditions are predominant in the northern and coarse parts of the aquifer, whereas reducing potentials prevail in the southern and silt–clay parts. Several well waters contain arsenic in excess of drinkable limits (=10 ppb), and most of these wells are located in the southern area. A large portion of the studied area has a high probability of containing non-potable water (up to 150 ppb As). Remarkably, As “hot spots” (As > 300 ppb, up to 431 ppb) were identified at the transition from gravel to silt–clay sediments. No industrial or agricultural source of As has been found.     

Chemical signature of intermediate water masses along western Portuguese margin

Although the circulation of intermediate water masses in the eastern North Atlantic remains poorly defined, the presence of fresher intermediate waters, the Sub-Artic (SAIW) and the Antarctic Intermediate Water (AAIW), as well the saline intermediate Mediterranean Water (MW), has been tracked using biogeochemical properties. Here we assess the hydrographic and chemical structures of intermediate waters along the western Portuguese margin by examining the vertical distributions and property-property plots of chemical tracers (oxygen and nutrients). AAIW was traced by low oxygen and high nutrients, while SAIW was recognized by low nutrients. The Mediterranean Water (MW) undercurrent is shown to spread towards the eastern flank of Gorringe bank. Concurrently, the fresher waters gained salt by direct incorporation of MW, while this water was enriched in nutrients on its way northward and westward owing, to a great extent, to the entrainment of an AAIW branch. The distributions of nutrients and apparent oxygen utilization are discussed in terms of regional ocean circulation. Our analysis suggests a circulation pattern of the various intermediate waters along the western Portuguese margin: MW extends all over the area, but its presence is more pronounced around cape St. Vincent; SAIW apparently moves southward, reaching the Gorringe bank region, and AAIW flows northward along the coast and around the bank.     

Laboratory study of deep-water breaking waves

In an attempt to elucidate the mechanics of deep-water wave breaking, a variety of breaking waves, including spilling and plunging waves, of different length scales and geometries was studied. The waves were generated through wave-wave interactions using wave packets with constant-steepness components, constant-amplitude components, and also components following the Pierson-Moskowitz distribution. Wave steepening prior to breaking were found to cause an increase in the high frequency spectral slope of the wave spectrum. The slopes were correlated to the type of breaking and the intensity of the breaking. The energy loss through breaking varied with the spectral characteristics of the wave packet. On the other hand, it was also noted that, irrespective of the wave packet, the losses were from the higher frequency end of the first harmonics.     

Invasions in Marine Communities: Contrasting Species Richness and Community Composition Across Habitats and Salinity

While many studies of non-native species have examined either soft-bottom or hard-bottom marine communities, including artificial structures at docks and marinas, formal comparisons across these habitat types are rare. The number of non-indigenous species (NIS) may differ among habitats, due to differences in species delivery (trade history) and susceptibility to invasions. In this study, we quantitatively compared NIS to native species richness and distribution and examined community similarity across hard-bottom and soft-sediment habitats in San Francisco Bay, California (USA). Benthic invertebrates were sampled using settlement panels (hard-bottom habitats) and sediment grabs (soft-bottom habitats) in 13 paired sites, including eight in higher salinity areas and five in lower salinity areas during 2 years. Mean NIS richness was greatest in hard-bottom habitat at high salinity, being significantly higher than each (a) native species at high salinity and (b) NIS richness at low salinity. In contrast, mean NIS richness in soft-bottom communities was not significantly different from native species richness in either high- or low-salinity waters, nor was there a difference in NIS richness between salinities. For hard-bottom communities, NIS represented an average of 79% of total species richness per sample at high salinity and 78% at low salinity, whereas the comparable values for soft bottom were 46 and 60%, respectively. On average, NIS occurred at a significantly higher frequency (percent of samples) than native species for hard-bottom habitats at both salinities, but this was not the case for soft-bottom habitats. Finally, NIS contributed significantly to the existing community structure (dissimilarity) across habitat types and salinities. Our results show that NIS richness and occurrence frequency is highest in hard-bottom and high-salinity habitat for this Bay but also that NIS contribute strongly to species richness and community structure across each habitat evaluated.     

Models of travel demand with endogenous preference change and heterogeneous agents

In the literatures of regional science, urban economics, and urban development planning, a working assumption is that individuals respond to incentives and regulations, given their preferences. Models for planning and policy analyses are used to consider what might occur if the incentives or regulations were different. In these models, however, preferences are usually assumed to be given and stable, and agents are usually assumed to be homogeneous. This paper focuses on the implications of making preferences in models of policy implementation endogenously determined and time varying heterogeneous agents. We consider first the recent literature on intertemporal choice and preference change, which cuts across many disciplines, and more briefly the literature on norm-regarding behavior. We then elaborate a simple model of transportation demand—from a static to a dynamic orientation, from fixed and exogenously given preferences of strictly self-regarding agents to endogenously determined and policy-induced preferences of heterogeneous agents—and illustrate its characteristics with simple numerical examples.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

E (B-V) determination from an UV-visual two-colour diagram: O and B stars in the catalogue of stellar ultraviolet fluxes

We present here, for the O and B type stars in the Catalogue of Stellar Ultraviolet Fluxes, an approach which does not require a precise knowledge of spectral type and luminosity class for derivingE(B-V) colour excesses. The method is based on the use of an UV-visual two-colour diagram; galactic variations in the interstellar extinction law are analyzed and fully taken into account. Our results have been compared with those derived by using the differences between observed and intrinsic colours for stars with known spectral classification. The very good agreement in a large number of cases (94 per cent) demonstrates that our approach permits the derivation of reliable colour excess values for early type stars even if only a rough spectral classification is available.     

The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.