Environmental predictors of decapod species richness and turnover along an extensive Australian continental margin (13–35° S)

The use of environmental data in biogeographic studies of the deep sea is providing greater insight into the processes underlying large‐scale patterns of diversity. Recent surveys of Australia's western continental margin (~100–1100 m) provide systematic sampling of invertebrate megafauna along a gradient of 22° of latitude (13–35° S). Diversity patterns of decapod crustaceans were examined and we investigated the relative importance of environmental and spatial predictor variables on both species richness (alpha diversity) and species turnover. Distance‐based linear models (DistLM) indicated a suite of variables were important in predicting species turnover, of which temperature and oxygen were the most influential. These reflected the oceanographic features that dominate distinct depth bathomes along the slope. The numbers of species within samples were highly variable; a small but significant increase in diversity towards the tropics was evident. Replicated sampling along the margin at ~100 m and ~400 m provided an opportunity to compare latitudinal patterns of diversity at different depths. On the shallow upper slope (~400 m) temperature was disassociated from latitude and the latter proved to be the best predictor of sample species richness. The predictive power of latitude over other variables indicates that proximity to the highly diverse Indo‐West Pacific (IWP) may be important, especially considering that almost 40% of species in this study had a wide IWP distribution. In the management of Australia's marine environments, geomorphic surrogates have been emphasised when defining areas for protection. We found sea‐floor characteristics were relatively less important in predicting richness or community composition.     

Future emissions of marine halogenated very-short lived substances under climate change

Halogenated Very Short-lived Substances (VSLS), such as bromoform, dibromomethane and methyl iodide, are naturally produced in the oceans and are involved in ozone depletion in the troposphere and the stratosphere. The effect of climate change on the oceanic emissions of these compounds is not well quantified. Based on present-day observed global oceanic and atmospheric concentrations, and historic and future data from three CMIP5 models, past and future sea-to-air fluxes of these VSLS are calculated. The simulations are used to infer possible effects of projected changes of physical forcing on emissions in different oceanic regimes. CMIP5 model output for 1979–2100 from the historical scenario and the RCP scenarios 2.6 and 8.5 are used as input data for the emission calculations. Of the parameters that have the main influence on the sea-to-air fluxes, the global sea surface temperatures show a steady increase during the twenty-first century, while the projected changes of sea surface wind speed is very small. The calculated emissions based on the historical CMIP5 model runs (1979–2005) increased over the 26 year period and agree well with the emissions based on ERA-Interim data. The future sea-to-air fluxes of VSLS generally increase during the twenty-first century under the assumption of constant concentration fields in the ocean and atmosphere. The multi-model mean global emissions of bromoform increase by 29.4% (9.0%) between 1986 and 2005 and 2081–2100 under RCP 8.5 (2.6) and dibromomethane and methyl iodide emissions increase by 23.3% (6.4%) and 5.5% (1.5%), respectively. Uncertainties of the future emission estimates, driven by ongoing environmental changes such as changing oceanic productivity (not considered in this study) are discussed.     

Tourmaline Reference Materials for the In Situ Analysis of Oxygen and Lithium Isotope Ratio Compositions

Three tourmaline reference materials sourced from the Harvard Mineralogical and Geological Museum (schorl 112566, dravite 108796 and elbaite 98144), which are already widely used for the calibration of in situ boron isotope measurements, are characterised here for their oxygen and lithium isotope compositions. Homogeneity tests by secondary ion mass spectrometry (SIMS) showed that at sub‐nanogram test portion masses, their ¹⁸O/¹⁶O and ⁷Li/⁶Li isotope ratios are constant within ± 0.27‰ and ± 2.2‰ (1s), respectively. The lithium mass fractions of the three materials vary over three orders of magnitude. SIMS homogeneity tests showed variations in ⁷Li/²⁸Si between 8% and 14% (1s), which provides a measure of the heterogeneity of the Li contents in these three materials. Here, we provide recommended values for δ¹⁸O, Δ’¹⁷O and δ⁷Li for the three Harvard tourmaline reference materials based on results from bulk mineral analyses from multiple, independent laboratories using laser‐ and stepwise fluorination gas mass spectrometry (for O), and solution multi‐collector inductively coupled plasma‐mass spectroscopy (for Li). These bulk data also allow us to assess the degree of inter‐laboratory bias that might be present in such data sets. This work also re‐evaluates the major element chemical composition of the materials by electron probe microanalysis and investigates these presence of a chemical matrix effect on SIMS instrumental mass fractionation with regard to δ¹⁸O determinations, which was found to be < 1.6‰ between these three materials. The final table presented here provides a summary of the isotope ratio values that we have determined for these three materials. Depending on their starting mass, either 128 or 512 splits have been produced of each material, assuring their availability for many years into the future.     

Tracing tsunami signatures of the ad 551 and ad 1303 tsunamis at the Gulf of Kyparissia (Peloponnese,Greece) using direct push in situ sensing techniques combined with geophysical studies

The western Peloponnese was repeatedly hit by major tsunami impacts during historical times as reported by historical accounts and recorded in earthquake and tsunami catalogues. Geological signatures of past tsunami impacts have also been found in many coastal geological archives. During the past years, abundant geomorphological and sedimentary evidence of repeated Holocene tsunami landfall was found between Cape Katakolo and the city of Kyparissia. Moreover, neotectonic studies revealed strong crust uplift along regional faults with amounts of uplift between 13 m and 30 m since the mid-Holocene. This study focuses on the potential of direct push in situ sensing techniques to detect tsunami sediments along the Gulf of Kyparissia. Direct push measurements were conducted on the landward shores of the Kaiafa Lagoon and the former Mouria Lagoon from which sedimentary and microfaunal evidence for tsunami landfall are already known. Direct push methods helped to decipher in situ high-resolution stratigraphic records of allochthonous sand sheets that are used to document different kinds of sedimentological and geomorphological characteristics of high-energy inundation, such as abrupt increases in grain size, integration of muddy rip-up clasts and fining upward sequences which are representative of different tsunami inundation pulses. These investigations were completed by sediment coring as a base for local calibration of geophysical direct push parameters. Surface-based electrical resistivity tomography and seismic data with highly resolved vertical direct push datasets and sediment core data were all coupled in order to improve the quality of the geophysical models. Details of this methodological approach, new in palaeotsunami research, are presented and discussed, especially with respect to the question of how the obtained results may help to facilitate tracing tsunami signatures in the sedimentary record and deciphering geomorphological characteristics of past tsunami inundation. Using direct push techniques and based on sedimentary data, sedimentary signatures of two young tsunami impacts that hit the Kaiafa Lagoon were detected. Radiocarbon age control allowed the identification of these tsunami layers as candidates for the ad 551 and ad 1303 earthquake and tsunami events. For these events, there is reliable historical data on major damage on infrastructure in western Greece and on the Peloponnese. At the former Mouria Lagoon, corroborating tsunami traces were found; however, in this case it is difficult to decide whether these signatures were caused by the ad 551 or the ad 1303 event.     

Effects of grain-size distribution and shape on sediment bed stability,near-bed flow and bed microstructure

Different studies investigating the stability of mixed sediment have found that the fine fraction can either stabilize or mobilize the bed. This study aims to find where the transition between these two modes occurs for sandy sediment and to identify the underlying (grain-scale) processes. Flume experiments with bimodal sediment were used to investigate near-bed processes of a non-cohesive sediment bed, and in particular how the grain shape and the ratio of different grain sizes influence bed mobility. Medium sand (D_50,c ≈ 400 μm) was mixed with 40 % fine material of different diameters (D_50,f = 53; 111; 193 μm) and subjected to increasing flow velocities (U = 1.3–22.2 cm s^-1). The bed mobility (i.e. the change of the bed level over time), turbidity and near-bed hydrodynamics were analysed. Selected results were compared with similar previous experiments with spherical glass beads. The findings indicate that, due to the complex grain shapes of natural sediment, a sand bed is more stable than a bed composed of glass beads. The grain-size ratio RD = D_c /D_f between the coarse and fine grain diameters controls whether the mixed bed is stabilized or mobilized by the presence of fines, with the transition between the modes occurring at RD = 4–5.5. Mixed beds with a very low RD < 2 behave like a unimodal bed. The results suggest that RD and grain shape influence bed roughness, near-bed flow, bed microstructure and the flow into and through the upper bed layers, which subsequently governs bed mobility. The interplay between all these processes can explain the transition between the stabilizing effect (high RD, small pore space) and the mobilizing effect (low RD, large pore space) of a fine fraction in a grain-size mixture. © 2018 John Wiley & Sons, Ltd.     

Internal Differentiation of the Archean Continental Crust: Fluid-Controlled Partial Melting of Granulites and TTG-Amphibolite Associations in Central Finland

Fault bound blocks of granulite and enderbite occur within upperamphibolite-facies migmatitic tonalitic–trondhjemitic–granodioritic(TTG) gneisses of the Iisalmi block of Central Finland. Theseunits record reworking and partial melting of different levelsof the Archean crust during a major tectonothermal event at2·6–2·7 Ga. Anhydrous mineral assemblagesand tonalitic melts in the granulites formed as a result ofhydrous phase breakdown melting reactions involving amphiboleat peak metamorphic conditions of 8–11 kbar and 750–900°C.A nominally fluid-absent melting regime in the granulites issupported by the presence of carbonic fluid inclusions. Thegeochemical signature of light rare earth element (LREE)-depletedmafic granulites can be modelled by 10–30 wt % partialmelting of an amphibolite source rock leaving a garnet-bearingresidue. The degree of melting in intermediate granulites isinferred to be less than 10 wt % and was restricted by the availabilityof quartz. Pressure–temperature estimates for the TTGgneisses are significantly lower than for the granulites at660–770°C and 5–6 kbar. Based on the P–Tconditions, melting of the TTG gneisses is inferred to haveoccurred at the wet solidus in the presence of an H₂O-rich fluid.A hydrous mineralogy, abundant aqueous fluid inclusions andthe absence of carbonic inclusions in the gneisses are in accordancewith a water-fluxed melting regime. Low REE contents and strongpositive Eu anomalies in most leucosomes irrespective of thehost rock composition suggest that the leucosomes are not meltcompositions, but represent plagioclase–quartz assemblagesthat crystallized early from felsic melts. Furthermore, similarplagioclase compositions in leucosomes and adjacent mesosomesare not a ‘migmatite paradox’, as both record equilibrationwith the same melt phase percolating along grain boundaries. KEY WORDS: Archean continental crust; fluid inclusion; granulite; migmatite; partial melting     

Trace element partitioning in the granulite facies

Analyses of trace elements in the mineral phases of granulites provide important information about the trace element distribution in the lower crust. Since granulites are often considered residues of partial melting processes, trace element characteristics of their mineral phases may record mineral/melt equilibria thus giving an opportunity to understand the nature and composition of melts in the lower continental crust. This study provides an extensive set of mineral trace element data obtained by LA-ICP-MS analyses of mafic and intermediate granulites from Central Finland. Mass balance calculations using the analytical data indicate a pronounced contribution of the accessory minerals apatite for the REE and ilmenite for the HFSE. Coherent mineral/mineral ratios between samples point to a close approach to equilibrium except for minerals intergrown with garnet porphyroblasts. Mineral trace element data were used for the formulation of a set of D ^mineral/melt partition coefficients that is applicable for trace element modelling under lower crustal conditions. D ^mineral/melt were derived by the application of predictive models and using observed constant mineral/mineral ratios. The comparison of the calculated D ^mineral/melt with experimental data as well as the relationship between mineral trace element contents and a leucosome with a composition close to an equilibrium melt provides additional constraints on mineral/melt partitioning. The D values derived in this study are broadly similar to magmatic partition coefficients for intermediate melt compositions. They provide a first coherent set of D values for Sc, V, Cr and Ni between clinopyroxene, amphibole, garnet, orthopyroxene, ilmenite and melt. In addition, they emphasize the strong impact that ilmenite exerts on the distribution of Nb and Ta.     

The effect of natural disasters on FDI attraction: a sector-based analysis over time and space

Natural Hazards - Extensive research has addressed the question of why some countries are able to attract a large amount of foreign direct investment (FDI), while others are not. Until now, this...