Uncertainties of geochemical modeling during CO<Subscript>2</Subscript> sequestration applying batch equilibrium calculations

One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical models. The application of geochemical models contributes significantly to calculate the fate of the CO₂ after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as well as the option to calculate pressure dependent equilibrium constants influence the CO₂ trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model for a virtual CO₂ injection into a saline Keuper aquifer. The amount of CO₂ which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC. Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying the thermodynamic database caused a range of 61% in the amount of trapped CO₂ calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in the calculated amount of trapped CO₂. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped CO₂. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling.     

Dental microwear texture analysis of late Pliocene Procynocephalus subhimalayanus (Primates: Cercopithecidae) of the Upper Siwaliks, India

Late Pliocene Procynocephalus subhimalayanus from the Upper Siwaliks, India is known from only three specimens. The dietary proclivities of this taxon have implications for reconstructing the paleoecology of the Upper Siwaliks. The dental microwear texture properties of Procynocephalus are compared to those from extant tropical forest primates including Alouatta palliata (n = 11), Cebus apella (n = 13), Gorilla gorilla (n = 9), Lophocebus albigena (n = 15) and Trachypithecus cristatus (n = 12). Dental microwear textures are generated by scanning the surface enamel of Facet 9 using white-light confocal microscopy at 100x. Four variables were extracted from scale-sensitive fractal analysis, and the data were ranked before ANOVA with post-hoc tests of significance and multivariate analyses were performed. Procynocephalus clusters closest to Lophocebus, Cebus and some Gorilla specimens suggesting hard-object feeding characterized a portion of its diet. The dental microwear texture of Procynocephalus supports interpretations of widespread grasslands of the Late Pliocene Kansal Formation (Pinjor zone). The extreme enamel complexity characterizing Procynocephalus may derive from consumption of underground storage organs, or other foods with high grit loads. Foods consumed near ground level carry a heavy load of abrasive minerals possibly contributing to greater enamel surface complexity and textural fill volume.     

Canary in a coal mine: perceptions of climate change risks and response options among Canadian mine operations

A survey documenting how climate change is perceived and responded to by Canadian mine operations was administered to a random sample of practitioners working at mine sites across Canada. Key findings include: (1) Mines are sensitive to climatic hazards; (2) There is concern about climate change among mine practitioners, but the majority have not yet noticed climate change to be affecting operations; (3) Future climate change is expected to have negative impacts for mine operations; (4) Mines are responding to climate change mainly through efforts to reduce greenhouse gas emissions but also through adaptation, although to a lesser degree; and (5) Knowledge of future climate change projections and impacts is limited, potentially constraining understanding of the nature of climate change risks. The survey compliments previous work documenting perceptions among upper level management on climate change in the Canadian mining industry. The results from both surveys are largely consistent, establishing that the mining sector perceives climate change as an emerging risk and is developing response options, but needs to invest more time and resources for adaptation to what are inevitable changes in climate. The results support the need for targeted in-depth research to assess the vulnerability of mining to climate change and to evaluate response options.     

Social identity, perception and motivation in adaptation to climate risk in the coffee sector of Chiapas, Mexico

Most investigation into climate adaptation to date has focused on specific technological interventions and socio-economic aspects of adaptive capacity. New perspectives posit that socio-cognitive factors may be as or more important in motivating individuals to take adaptive actions. Recent research indicates that incorporating insights from motivation theory can enhance theorization of adaptive capacity. Yet unexplored, and what we propose here, is the addition of social identity to models of adaptive capacity and adaptation. To apply this conceptual framework, the first author undertook in-depth interviews with a sample of farmers who had participated in broader surveys the previous year to explore their perceptions of their social identity, climate-related information and its sources, and climate risk. These interviews elicited compelling evidence that social identity mediates between risk perception and adaptation through its influence on motivation. Interviews revealed significant links between social identity and perception of information, risk perception and adaptation, of which the most salient were the relative credibility and legitimacy of information sources (related to us vs. them social group differentiation); the role of coffee organizations; and ethnicity and geographic marginalization. Strong in-group identity and perceptions of potentially influential out-groups such as the scientific community appear to particularly influence perception and use of information. These findings have rich policy implications for adaptation management and merit further investigation to identify how, where and why social identity plays a role in climate-risk perception, motivation and adaptation in other geographic areas of vulnerability worldwide.     

Magma at depth: a retrospective analysis of the 1975 unrest at Mount Baker,Washington, USA

Mount Baker volcano displayed a short interval of seismically-quiescent thermal unrest in 1975, with high emissions of magmatic gas that slowly waned during the following three decades. The area of snow-free ground in the active crater has not returned to pre-unrest levels, and fumarole gas geochemistry shows a decreasing magmatic signature over that same interval. A relative microgravity survey revealed a substantial gravity increase in the ~30 years since the unrest, while deformation measurements suggest slight deflation of the edifice between 1981–83 and 2006–07. The volcano remains seismically quiet with regard to impulsive volcano-tectonic events, but experiences shallow (<3 km) low-frequency events likely related to glacier activity, as well as deep (>10 km) long-period earthquakes. Reviewing the observations from the 1975 unrest in combination with geophysical and geochemical data collected in the decades that followed, we infer that elevated gas and thermal emissions at Mount Baker in 1975 resulted from magmatic activity beneath the volcano: either the emplacement of magma at mid-crustal levels, or opening of a conduit to a deep existing source of magmatic volatiles. Decadal-timescale, multi-parameter observations were essential to this assessment of magmatic activity.     

Receiver function study in northern Sumatra and the Malaysian peninsula

In this receiver function study, we investigate the structure of the crust beneath six seismic broadband stations close to the Sunda Arc formed by subduction of the Indo-Australian under the Sunda plate. We apply three different methods to analyse receiver functions at single stations. A recently developed algorithm determines absolute shear-wave velocities from observed frequency-dependent apparent incidence angles of P waves. Using waveform inversion of receiver functions and a modified Zhu and Kanamori algorithm, properties of discontinuities such as depth, velocity contrast, and sharpness are determined. The combination of the methods leads to robust results. The approach is validated by synthetic tests. Stations located on Malaysia show high-shear-wave velocities (V _S) near the surface in the range of 3.4–3.6 km s^− 1 attributed to crystalline rocks and 3.6–4.0 km s^− 1 in the lower crust. Upper and lower crust are clearly separated, the Moho is found at normal depths of 30–34 km where it forms a sharp discontinuity at station KUM or a gradient at stations IPM and KOM. For stations close to the subduction zone (BSI, GSI and PSI) complexity within the crust is high. Near the surface low V _S of 2.6–2.9 km s^− 1 indicate sediment layers. High V _S of 4.2 km s^− 1 are found at depth greater than 6 and 2 km at BSI and PSI, respectively. There, the Moho is located at 37 and 40 km depth. At station GSI, situated closest to the trench, the subducting slab is imaged as a north-east dipping structure separated from the sediment layer by a 10 km wide gradient in V _S between 10 and 20 km depth. Within the subducting slab V _S ≈ 4.7 km s^− 1. At station BSI, the subducting slab is found at depth between 90 and 110 km dipping 20° ± 8° in approximately N 60° E. A velocity increase in similar depth is indicated at station PSI, however no evidence for a dipping layer is found.     

Representing Grounding Line Dynamics in Numerical Ice Sheet Models: Recent Advances and Outlook

Recent satellite observations of the Antarctic and Greenland ice sheets show accelerated ice flow and associated ice sheet thinning along coastal outlet glaciers in contact with the ocean. Both processes are the result of grounding line retreat due to melting at the grounding line (the grounding line is the contact of the ice sheet with the ocean, where it starts to float and forms an ice shelf or ice tongue). Such rapid ice loss is not yet included in large-scale ice sheet models used for IPCC projections, as most of the complex processes are poorly understood. Here we report on the state-of-the art of grounding line migration in marine ice sheets and address different ways in which grounding line migration can be attributed and represented in ice sheet models. Using one-dimensional ice flow models of the ice sheet/ice shelf system we carried out a number of sensitivity experiments with different spatial resolutions and stress approximations. These are verified with semi-analytical steady state solutions. Results show that, in large-scale finite-difference models, grounding line migration is dependent on the numerical treatment (e.g. staggered/non-staggered grid) and the level of physics involved (e.g. shallow-ice/shallow-shelf approximation).     

Submarine hydrothermal activity and gold-rich mineralization at Brothers Volcano, Kermadec Arc, New Zealand

Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ??600?m in a SW?CNE direction with chimneys occurring over a ??145-m depth interval, between ??1,690 and 1,545?m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2?C3?m in height, with some reaching 6?C7?m. Their ages (at time of sampling) fall broadly into three groups: <4, 23, and 35?years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2?C3?m thick. Two main types of chimney predominate: Cu-rich (up to 28.5?wt.% Cu) and, more commonly, Zn-rich (up to 43.8?wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91?ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (??0.5?m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (??300°C), acidic (pH????2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (??122°C), more acidic (pH?1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO₄ and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3?years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO₂ (e.g., 206?mM/kg at the Cone site); high CO₂/³He; negative ??D and ??¹⁸O_H2O for vent fluids; negative ??³⁴S for sulfides (to ?4.6??), sulfur (to ?10.2??), and ??¹⁵N₂ (to ?3.5??); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu?+?Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in ³He/⁴He values for both Cone and NW Caldera sites, and overprinting of ??magmatic?? mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (??2.5?km long), narrow (??300-m diameter) ??pipes,?? consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members.     

Late Cambrian deformation in the Lesser Himalaya

The Tons Valley, situated in the central-easternmost part of the Himachal Lesser Himalaya, adjoining the Garhwal Himalaya, shows geological features suggestive of a strong pre-Tertiary deformational episode. The Paleoproterozoic Dharagad Group, overlain by the Mesoproterozoic Deoban and Neoproterozoic Simla groups rest as a thrust sheet over the Middle Cambrian Chilar Formation, which occurs as windows and also as tectonic slivers within the thrust sheet designated as the Dharagad Thrust Sheet (DTS). The mineral lineation, inclination of tectonic slivers and overturned beds suggest that the DTS was translated from the NE. The westernmost and southwesternmost leading edges of the DTS are exposed at Subathu and Morni WNW and WSW respectively of the Tons Valley. The position of the leading edges of the DTS vis-à-vis the windows in the Tons Valley suggest a minimum translation of about 50 km for the DTS. The Simla Group at Subathu and the Deoban at Morni, forming parts of the DTS, constitute basement for the Thanetian–Lutetian Subathu Formation of the Himalayan Foreland Basin (HFB). This stratigraphic relationship unambiguously demonstrates that the Simla and the Deoban Groups, forming leading edges of the allochthonous DTS, were already translated and emplaced at Subathu and Morni before the creation of the HFB in which the deposition commenced with the Subathu Formation in Thanetian. It implies that the DTS was translated from the NE to the present position at Subathu and Morni in pre-Thanetian time. There is no direct evidence to constrain the age of the thrusting.In view of regional regression in Late Cambrian, a distinct angular unconformity between the Cambrian and the overlying Ordovician, Early Paleozoic metamorphism and extensive development of Early Paleozoic granites and their rapid exhumation, a Late Cambrian age is suggested for the DTS thrusting. Not only the direction of movement of the DTS is same as that of the Tertiary thrust sheets but also Cambrian folds are co-axial with the Tertiary folds. This strange coincidence shows that similar kinematic field existed during two tectonic events. A ridge, like the present Central Crystalline Axis, was elevated between the Tethyan and Lesser Himalayan basins, which contributed zircons of the Early Cambrian age to both basins.     

Magmato-sedimentary Carboniferous to Jurassic evolution of the western Tauern window,Eastern Alps (constraints from U-Pb zircon dating and geochemistry)

New geochronological U-Pb (LA-ICP-MS) zircon data and geochemical analyses from the Variscan orthogneisses and metavolcanic rocks in the western Tauern window are presented and used to reconstruct the pre-Alpine evolution of this area. The late- and post-Variscan stage in the Tauern window was characterised by distinct magmatic pulses accompanied by the formation of volcano-sedimentary basins. The magmatic activity started in the Visean (335.4 ± 1.5 Ma) with the intrusion of a K-rich, durbachitic biotite-granite (protolith of the Ahorn gneiss). Following a period of exhumation and erosion, Westfalian–Stefanian volcanics were deposited (Grierkar meta-rhyodacite: 309.8 ± 1.5 Ma; Venntal meta-rhyolite: 304.0 ± 3.0 Ma). A renewed magmatic pulse occurred in the Early Permian, producing large volumes of tonalites and granodiorites (Tux meta-granodiorite: 292.1 ± 1.9 Ma). The youngest magmatism is characterised by pyroclastic and tuffitic deposits (Pfitsch meta-rhyolite: 280.5 ± 2.6 Ma; Schönach valley meta-andesite: 279.0 ± 4.8 Ma). This volcanism was probably related to crustal extensional faulting within an intra-continental graben and horst setting, asthenospheric upwelling and heat flow increase due to the onset of the Permian rifting. The Permo-Triassic peneplanation and subsidence is documented by shallow marine and evaporitic deposits. Probably in the Middle Jurassic times, the area was flooded and in the Late Jurassic the whole area was covered by limestones, representing post-rift sediments on the southern European continental margin.