Tectonic and sedimentary basin evolution of the eastern Bangong–Nujiang zone (Tibet): a Reading cycle

The ophiolite-bearing Bangong-Nujiang zone (BNZ) traversing central Tibet from east to west separates the Qiangtang block in the north from the Lhasa block in the south. Their stratigraphic development indicates that both blocks once formed a continuous continental platform until the Late Triassic. Following Late Paleozoic-Triassic rifting, ocean crust formed between both blocks during the Late Triassic creating the Dongqiao-Naqu basin (DNB) among other basins (Yu et al. 1991). The analysis of the rift flank sequences reveals that rifting was dominated by transtension. The basin was shortened by post-Mid-Cretaceous transpression. Thus, the overall basin evolution represents a Reading cycle despite some active margin processes which gave this cycle a special imprint. Major basin parts were preserved despite transpressional shortening suggesting that the eastern BNZ represents a remnant basin. Our understanding of the DNB solves the prior problem of viewing the BNZ as a Mid-Late Jurassic collisional suture although typical collision-related deformation, thickening, mountain building, as well as related molasse formation are lacking. Our model also explains the scattered linear ophiolite distribution by local transpression of remnant oceanic basin floor without having to consider problematic long range ophiolite thrusting.     

A review of mortality maps included in the annual reports on vital statistics for Ireland, 1864-1998

Since 1864, some 135 reports have been produced examining marriages, birth and deaths for Ireland. The reports produced during the period prior to World War I are notable for the maps and charts that are included and the level of detail provided. Recent reports have failed to include mortality maps, while those produced since 1950 generally show a declining level of detail.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Analyses of organic and inorganic contaminants in Salton Sea fish

Chemical contamination of fish from the Salton Sea, a quasi-marine lake in Southern California, could adversely impact millions of birds using the Pacific Flyway and thousands of humans using the lake for recreation. Bairdiella icistia (bairdiella), Cynoscion xanthulus (orangemouth corvina), and Oreochromis spp. (tilapia) were sampled from two river mouths and two nearshore areas of the Salton Sea. Muscle tissues were analyzed for a complete suite of 14 trace metals and 53 pesticides. Fish muscle tissues had concentrations of selenium ranging between 1.89 and 2.73 microg/g wet weight. 4,4'-DDE accounted for 94% of the total DDT metabolites. Total DDTs ranged between 17.1 and 239.0 and total PCBs between 2.5 and 18.6 ng/g wet weight. PCB congeners 132, 138, 153, 168, and 180 comprised over 50% of the total PCBs. Given the potential implementation of a commercial fishing at the Salton Sea in the future, the presence of persistent organic pollutants and selenium warrants further research into the effects of these mixtures on fish populations, and on wildlife and humans consuming fish.     

An empirical garnet (YAG) – xenotime thermometer

 A pronounced negative correlation between the yttrium concentration in garnet ([Y]_Grt) and temperature has been observed in xenotime (YPO₄)-bearing metapelites from central New England, USA. The [Y]_Grt decreases roughly two orders of magnitude (∼5500 to less than 100 ppm Y) over a 150 °C interval. A regression of ln([Y]_Grt) against estimated reciprocal temperature yields the following relationship:

The Equation of State of Lakes

In recent years, a number of workers have studied the stability of deep lakes such as Lake Tanganyika, Lake Baikal and Lake Malawi. In this paper, the methods that can be used to determine the effect that the components of lakes have on the equation of state are examined. The PVT properties of Lakes have been determined by using apparent molal volume data for the major ionic components of the lake. The estimated PVT properties (densities, expansibility and compressibilities) of the lakes are found to be in good agreement with the PVT properties (P) of seawater diluted to the same salinity. This is similar to earlier work that showed that the PVT properties of rivers and estuarine waters could also be estimated from the properties of seawater.The measured densities of Lake Tanganyika were found to be in good agreement (± 2 × 10^-6 g cm^-3) with the values estimated from partial molal properties and the values of seawater at the same total salinity (S_T = 0.568). The increase in the densities of Lake Tanganyika waters increased due to changes in the composition of the waters. The measured increase in the measured density (45 × 10^-6 g cm^-3) is in good agreement (46 × 10^-6 g cm^-3) with the values calculated for the increase in Na⁺, HCO₃ ^-, Mg²⁺, Ca²⁺ and Si(OH)₄.Methods are described that can be used to determine the conductivity salinity of lakes using the equations developed for seawater. By combining these relationships with apparent molal volume data, one can relate the PVT properties of the lake to those of seawater.     

Heavy metal inflow into the floodplains at the mouth of the river Weiße Elster (Central Germany)

From 1998 to 2002 investigations were carried out to estimate both the quantity and quality (heavy metal contents) of suspended matter loads discharged into a floodplain area measuring approx. 5 km² of the Central German river Weiße Elster, a tributary of the river Saale in the Elbe river basin. Flood sediments, suspended particulate matter, and floodplain soils were investigated especially for the main pollutants Cd, Zn, Cu, Pb, Cr, and Hg. Supplementary gamma spectroscopy examinations were performed to help to identify the age of deposits in order to estimate sedimentation rates for last decades. The recent flood sediments are contaminated by up to 33 times the geogenic background (Cd). Up to 55% of the total annual SPM load of the river Weiße Elster is relocated into the investigated retention area in the flood‐stricken year 2002. The sedimentation rates for the last 50 years vary between 0.5 mm/a and 1 mm/a in far away and rarely flooded parts and between 1 mm/a and 2 mm/a in the frequently flooded parts of the inflow of the retention area.     

Turbulent fluxes from Helipod flights above quasi-homogeneous patches within the LITFASS area

Turbulent fluxes of sensible and latent heat were measured with the helicopter-borne turbulence probe Helipod over a heterogeneous landscape around the Meteorological Observatory Lindenberg during the STINHO-2 and LITFASS-2003 field experiments. Besides the determination of area-averaged heat fluxes, the analysis focused on different aspects of the response of the turbulent structure of the convective boundary layer (CBL) on the surface heterogeneity. A special flight pattern was designed to study flux profiles both over quasi-homogeneous sub-areas of the study region (representing the major land use types—forest, farmland, water) and over a typical mixture of the different surfaces. Significant differences were found between the heat fluxes over the individual surfaces along flight legs at about 80 m above ground level, in agreement with large-aperture scintillometer measurements. This flux separation was still present during some flights at levels near the middle of the CBL. Different scales for the blending height and horizontal heterogeneity were calculated, but none of them could be identified as a reliable indicator of the mixing state of the lower CBL. With the exception of the flights over water, the latent heat flux measurements generally showed a larger statistical error when compared with the sensible heat flux. Correlation coefficients a nd integral length scales were used to characterise the interplay between the vertical transport of sensible and latent heat, which was found to vary between ‘fairly correlated’ and ‘decoupled’, also depending on the soil moisture conditions.     

Evaporation over a Heterogeneous Land Surface: EVA_GRIPS and the LITFASS-2003 Experiment—An Overview

The Evaporation at Grid/Pixel Scale (EVA_GRIPS) project was realised in order to determine the area-averaged evaporation over a heterogeneous land surface at the scale of a grid box of a regional numerical weather prediction or climate model, and at the scale of a pixel of a satellite image. EVA_GRIPS combined surface-based and airborne measurements, satellite data analysis, and numerical modelling activities. A mesoscale field experiment, LITFASS-2003, was carried out in the heterogeneous landscape around the Meteorological Observatory Lindenberg (MOL) of the German Meteorological Service in May and June, 2003. The experiment was embedded in the comprehensive, operational measurement program of the MOL. Experimental determination of surface fluxes on a variety of spatial scales was achieved by employing micrometeorological flux stations, scintillometers, a combination of ground-based remote sensing instruments, and the Helipod, a turbulence probe carried by a helicopter. Surface energy fluxes were also derived from satellite data. Modelling work included the use of different Soil–Vegetation–Atmosphere Transfer schemes, a large-eddy simulation model and three mesoscale atmospheric models. The paper gives an overview on the background of EVA_GRIPS, and on the measurements and meteorological conditions during LITFASS-2003. A few general results are discussed.     

Processing and quality control of flux data during LITFASS-2003

Different aspects of the quality assurance and quality control (QA/QC) of micrometeorological measurements were combined to create a comprehensive algorithm which was then applied to experimental data from LITFASS-2003 (Lindenberg Inhomogeneous Terrain—Fluxes between Atmosphere and Surface: a long term Study). Eddy-covariance measurements of the latent heat flux were the main focus of the QA/QC efforts. The results of a turbulence sensor intercomparison experiment showed deviations between the different eddy-covariance systems on the order of 15%, or less than 30 W m⁻², for the latent heat flux and 5%, or less than 10 W m⁻², for the sensible heat flux. In order to avoid uncertainties due to the post-processing of turbulence data, a comprehensive software package was used for the analysis of experimental data from LITFASS-2003, including all necessary procedures for corrections and quality control. An overview of the quality test results shows that for most of the days more than 80% of the available latent heat flux data are of high quality so long as there are no instrumental problems. The representativeness of a flux value for the target land-use type was analysed using a stochastic footprint model. Different methods to calculate soil heat fluxes at the surface are discussed and a sensitivity analysis is conducted to select the most robust method for LITFASS-2003. The lack of energy balance closure, which was found for LITFASS-2003, can probably be attributed to the presence of low-frequency flux contributions that cannot be resolved with an averaging time of 30 min. Though the QA/QC system has been developed for the requirements of LITFASS-2003, it can also be applied to other experiments dealing with similar objectives.