Effects of diffusional modification of garnet growth zoning on P-T path calculations

The effect of intragranular diffusion on chemical zoning in garnet and on P-T paths calculated from that zoning was evaluated using a numerical model of multicomponent diffusion in combination with simulations of garnet growth. Syn-and post-growth diffusion of Mg–Fe–Mn–Ca species in garnet was calculated for a model pelitic assemblage over a range of temperatures from 485 to 635°C. Compositions from zoned garnet, as modified by diffusion, hypothetical inclusions of plagioclase within garnet and matrix phases were used to reconstruct pressure-temperature (P-T) paths from isobaric and polybaric model histories. P-T path calculations, based on numerical simulations conducted over an input isobaric heating path that reached peak temperatures between 585 and 635°C, show that relaxation of garnet compositional gradients by diffusion can induce modest to appreciable curvature in the inferred paths. Retrieved paths also indicated somewhat smaller overall temperature changes relative to the actual temperature difference of the input path. The magnitude of these distortions is shown to depend upon the heating and cooling rate and garnet crystal size as well as the actual peak temperature condition. The effect of diffusion on path trajectories in simulations with thermal histories that also included cooling were comparable to heating-only models that reached peak temperatures approximately 15–30°C higher. Compositions of garnets with radii less than 1 mm, that reached actual peak temperatures of 605°C along temperature-time histories characteristic of regional metamorphism, experienced sufficient diffusional relaxation to introduce errors of hundreds of bars to in excess of one kilobar in path trajectories. Path distortions were significant at heating/cooling rates less than 10°C/Ma, but rapidly diminished for rates faster than this. In polybaric simulations diffusion effects were least noticeable when the actual pressure-temperature conditions changed in a clockwise sense (i.e., convex to higher P and higher T), but apprecciable modification was seen in path models that underwent counterclockwise changes in P and T. Reequilibration of garnet rim compositions occurred during cooling on all paths, and temperature maxima obtained from garnet-biotite geothermometry underestimated actual peak conditions by 40 to 70°C. Calculations suggest that P-T path trajectories calculated from garnets of at least 1 mm size, and that experienced actual thermal maxima below 585°C, are not likely to be distorted by diffusional effects during regional metamorphism. However, P-T path reconstructions based on garnet zonation with smaller grains or higher temperatures may lead to misinterpretation of crystallization history. The partitioning record of peak metamorphic temperatures may be destroyed by diffusional reequilibration of garnet rim compositions during cooling, seriously complicating the task of quantitatively estimating diffusion effects on path calculations.     

Spatial Response to Major Volcanic Events in or about AD 536, 934 and 1258: Frost Rings and Other Dendrochronological Evidence from Mongolia and Northern Siberia: Comment on R. B. Stothers, ‘Volcanic Dry Fogs, Climate Cooling, and Plague Pandemics in Europe and the Middle East’ (Climatic Change, 42, 1999)

Hypothesized large-scale climatic extremes require verification from distantregions in order toconfirm the magnitude and timing of such events. Three of the most massivehypothesized volcanic events of the past two millennia, occurring in or aboutAD 536, 934 and1258, had profound climatic and demographic repercussions over much of Europe,the MiddleEast, and other areas, according to historical accounts recently described inStothers (1998, 1999,2000) as well as other research. Here we report on frost ring and otherdendrochronologicalevidence derived from a 1738-year tree-ring chronology from Mongolia andmillennial-scaletree-ring data from northern Siberia which demonstrate that these three eventsmay have alsoimpacted conditions in these distant regions.     

Investigating the amount of zeroing in modern sediments of River Danube, Austria

Sediments attributed to flooding events of River Danube concerning the bleaching of the optical stimulated luminescence (OSL) signal were investigated. It is demonstrated that the OSL signal in both quartz and feldspar is not completely but differentially bleached in the sediment grains. Partial bleaching of the samples is clearly indicated by the scatter of equivalent dose determined for several individual single aliquots. It is also shown that residual ages in feldspars are significantly higher than those calculated for quartz. It is furthermore demonstrated that analysing measurement-time dependent equivalent dose estimates is not a suitable method to identify partial bleaching in the investigated sediment grains. However, the transport and deposition process of the investigated samples was probably disturbed by an artificial input of sediment, and this case study may thus not be representative of undisturbed high flood events in the past.     

Opportunities provided by geographic information systems and volunteered geographic information for a timely emergency response during flood events in Cologne,Germany

The occurrence of disasters such as extreme flooding in urban environments has severe consequences, not only on the human population but also on critical infrastructures such as the road networks, which are of vital importance for everyday living and particularly for emergency response. In this article, our main goal is to present-conceptually and in praxis-a model that could be used from the emergency responders for timely and efficient emergency management and response in an urban complex environment. For the city of Cologne in Germany, we aim to indicate possible ways to decrease the emergency response time during an extreme flood scenario through the development of an accessibility indicator, which consists of different components. Therefore, we will investigate the opportunities that occur, in a flood risk scenario, from the use of geographic information in different forms such as Volunteered Geographic Information (VGI) and open-source data in an ArcGIS environment, to increase urban resilience through the decreasing emergency response time. We will focus on network analysis for the fire brigades (first acting emergency responders) during a flood scenario to calculate their emergency response ranges and emergency response routes through flooded road networks, for the assistance of the possibly affected hospitals, refugee homes and fire brigades, which can be flooded. At the end of the paper, we suggest that the vulnerable community of the refugees could be taken into consideration as a new source of VGI, as an additional component that would lead to the decrease in the emergency response time. The geo-located information that could be provided by the refugee community can be very useful in emergency situations, such as those examined in this article where timely information can be forwarded to the proper authorities for a more focused and timely emergency response, increasing the resilience of the urban population and their community.     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Use of Pitzer's equations to determine the media effect on the formation of lead chloro complexes

The spectrophotometric measurements of chloro complexes of lead in aqueous HCl, NaCl, MgCl₂ and CaCl₂ solutions at 25°C have been analyzed using Pitzer's specific interaction equations. Parameters for activity coefficients of the complexes PbCl⁺, PbCl₂⁰ and PbCl₃^? have been determined for the various media. Values of $\text{K}{}_1\text{= 30.0 ± 0.6}$, $\text{K}{}_2\text{= 106.7 ± 2.1}$ and $\text{K}{}_3\text{= 73.0 ± 1.5}$ were obtained for the cumulative formation constants. [$\text{Pb}{}^{\mathrm{2+}}\text{+ nCl}{}^{\mathrm{?}}\text{→ PbCl}{}_{\mathrm{n}}{}^{\mathrm{2?n}}\text{)}$]. These values are in reasonable agreement with literature data. The Pitzer parameters for the PbCl ion pairs in various media were used to calculate the speciation of Pb²⁺ in an artificial seawater solution.     

A review of the metallogeny and tectonics of the Lachlan Orogen

Future mineral exploration within eastern Australia will be enhanced by resolving the tectonic evolution of the Lachlan Orogen to establish the spatial and temporal terrane distribution of the various mineral deposits. The Lachlan Orogen, from north-eastern Tasmania through to central and eastern New South Wales, is host to a number of major mineral deposit styles—including orogenic gold (e.g. Stawell, Ballarat, Bendigo), volcanic-hosted massive sulphide (e.g. Woodlawn, Currawong), sediment-hosted Cu–Au (e.g. Cobar Basin deposits), porphyry Au–Cu (e.g. Cadia, Parkes, Cowal) and granite-related Sn (e.g. Ardlethan, Beechworth). Each of these mineral deposit styles is a sensitive and diagnostic indicator of the prevalent tectonic environment during their formation. In this review, we briefly summarise the deposit- to large-scale factors that define the diverse metallogenic evolution of the Lachlan Orogen. This overview is intended to “set the scene” for subsequent specialist papers published in this thematic issue on the metallogeny and tectonics of the Lachlan Orogen in south-east Australia.     

An HWRF-based ensemble assessment of the land surface feedback on the post-landfall intensification of Tropical Storm Fay (2008)

While tropical cyclones (TCs) usually decay after landfall, Tropical Storm Fay (2008) initially developed a storm central eye over South Florida by anomalous intensification overland. Unique to the Florida peninsula are Lake Okeechobee and the Everglades, which may have provided a surface feedback as the TC tracked near these features around the time of peak intensity. Analysis is done with the use of an ensemble model-based approach with the Developmental Testbed Center (DTC) version of the Hurricane WRF (HWRF) model using an outer domain and a storm-centered moving nest with 27- and 9-km grid spacing, respectively. Choice of land surface parameterization and small-scale surface features may influence TC structure, dictate the rate of TC decay, and even the anomalous intensification after landfall in model experiments. Results indicate that the HWRF model track and intensity forecasts are sensitive to three features in the model framework: land surface parameterization, initial boundary conditions, and the choice of planetary boundary layer (PBL) scheme. Land surface parameterizations such as the Geophysical Fluid Dynamics Laboratory (GFDL) Slab and Noah land surface models (LSMs) dominate the changes in storm track, while initial conditions and PBL schemes cause the largest changes in the TC intensity overland. Land surface heterogeneity in Florida from removing surface features in model simulations shows a small role in the forecast intensity change with no substantial alterations to TC track.