The role of basalt replenishment in the generation of basaltic andesites of the ongoing activity at Arenal volcano,Costa Rica: evidence from clinopyroxene and spinel

Bulletin of Volcanology - The bulk composition of magma erupted from Volcán Arenal has remained nearly constant (SiO2 = 53.6–54.9&;nbsp;wt%; MgO = 5.0–4.5&;nbsp;wt%) during...     

Phase relations of a F-enriched peraluminous granite: an experimental study of the Kymi topaz granite stock,southern Finland

Phase relations of F-rich Kymi equigranular topaz granite have been investigated experimentally at 100–500 MPa as a function of water activity and F content. Fluorite and topaz can crystallize as liquidus phases in F-rich peraluminous systems, but the F content of the melt should exceed 2.5–3.0 wt% for the crystallization of topaz. In peraluminous F-bearing melts containing more than 1 wt% F, topaz and muscovite are expected to be the first F-bearing phases to crystallize at high pressure, whereas fluorite and topaz should crystallize first at low pressure. Following reaction models the saturation of fluorite and topaz: CaAl₂Si₂O₈ (plagioclase) + 2[AlF₃]_melt = CaF₂ (fluorite) + 2Al₂SiO₄F₂ (topaz). The obtained partition coefficient for F between biotite and glass D(F)^Bt/glass ranges from 1.89 to 0.80 (average value 1.29) and can be used as an empirical fluormeter to determine the F content of coexisting melts. Combined petrological and experimental studies of the Kymi equigranular topaz granite indicate that plagioclase was the liquidus phase at nearly water-saturated (fluid-saturated) conditions and that the F content of the melt was at least 2 wt%. The mean F content of natural biotite (3.92 wt%) suggests that the late-stage crystallization of biotite occurred in melts containing about 3 wt% F. The early crystallization of biotite and the presence of muscovite in our experiments at 200 MPa contrasts with the late-stage crystallization of biotite and the absence of muscovite in the natural assemblage, indicating that crystallization pressure may have been lower than 200 MPa for the granite. Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Sulfur partition coefficient between apatite and rhyolite: the role of bulk S content

Experimental studies have been performed to constrain sulfur behavior during apatite crystallization and to determine sulfur partition coefficient between apatite and melt (Kd_S^apatite/melt) at oxidizing conditions. Crystallization experiments have been conducted with a hydrous rhyolitic melt and different bulk sulfur contents (0.15 to 2 wt.% S) at 900 and 1,000°C, 200 MPa and Δlog =NNO+3.6. The sulfur content in the glass increases with increasing amount of added S. Anhydrite crystallizes for S added = 0.75 wt.% (0.10 and 0.13 wt.% SO₃ in glass at 900 and 1,000°C, respectively). The amount of anhydrite increases and the amount of apatite decreases with increasing amount of added sulfur. The sulfur exchange reaction in apatite is influenced by the bulk composition of the melt (e.g., P content). However, changing melt composition has only little effect on Kd_S^apatite/melt for the investigated rhyolitic composition. The Kd_S^apatite/melt does not depend directly on temperature, decreases from 14.2 to 2.7 with increasing S content in glass from SO₃=0.03 to 0.19 wt.%, respectively, and can be predicted from the following equation: ln Kd = −0.0025×S in melt (in ppm)+2.9178. The combination of experimental data obtained for rhyolitic and andesitic melts reveals that the sulfur partition coefficient tends toward a value of 2 for high-sulfur content in the glass (>0.2 wt.% SO₃). Using S in apatite as proxy for determining S content in melt is promising but additional experimental data are needed to clarify the individual effects of T, , and P and Ca content in the melt on S partitioning.     

板状绿柱石晶体的结构测定

自然界中绿柱石晶体多为柱状,具板状晶形的绿柱石非常少见。本文对产于四川雪宝顶云英岩晶洞中的无色透明板状绿柱石进行了精确的结构分析,并与产于阿尔泰山号伟晶岩脉中的柱状绿柱石进行了比较。与阿尔泰柱状绿柱石相比,雪面板状绿石富Ｌi、Ｎａ,ｃ／ａ值较高,为１．００１,属钠－锂绿柱石或“四面体”绿柱石。本文还对这种特殊形貌柱石的形成机制进行了初步讨论,成矿流体中Ｌi的浓度以及Ｓi的化学形态可能是影响柱石忻驳闹     

Water and the density of silicate glasses

A review of published and newly measured densities for 40 hydrous silicate glasses indicates that the room-temperature partial molar volume of water is 12.0 ± 0.5 cm³/mol. This value holds for simple or mineral compositions as well as for complex natural glasses, from rhyolite to tephrite compositions, prepared up to 10–20 kbar pressures and containing up to 7 wt% H₂O. This volume does not vary either with the molar volume of the water-free silicate phase, with its degree of polymerization or with water speciation. Over a wide range of compositions, this constant value implies that the volume change for the reaction between hydroxyl ions and molecular water is zero and that, at least in glasses, speciation does not depend on pressure. Consistent with data from Ochs and Lange (1997, 1999), systematics in volume expansion for SiO₂–M₂O systems (M=H, Li, Na, K) suggests that the partial molar thermal expansion coefficient of H₂O is about 4 × 10⁻⁵ K⁻¹ in silicate glasses. Received: 30 June 1999 / Accepted: 5 November 1999     

Chronic offshore loss of nourishment on Nice beach,French Riviera: A case of over-nourishment of a steep beach?

The 4.5 km-long gravel beach fronting the exclusive resort of the city of Nice, on the French Riviera, in southeastern France, was artificially nourished from 1976 to 2005 to the tune of 558,000 m³, making this long-term operation one of the most significant for gravel beaches in the world. Nourishment has ranged from nil in certain years (1979, 1980, 1983–85, and 2001–2002) to a peak of over 97,000 m³ in 2000. Analyses of 50 transects covering the beach highlight no significant change in net beach width over this 30-year period of massive gravel nourishment. A Principal Components Analysis and a Cluster Analysis used to detect patterns in the 87 beach-width measurement dataset show no clear spatial trends in transect groups that can be interpreted in terms of the morphology of the beach and the steep inner shoreface. Significant wave height off Nice shows no change over the period 1979–2005. Since there is no possibility for alongshore gravel leakage on the strongly embayed Nice beach, the relative stability in beach width clearly implies loss of recharged gravel offshore. Gravel loss following nourishment is favoured by: (1) the steep inner shoreface inherited from the geological context of Nice beach at the flanks of the southern Alps, and (2) the practise of artificial beach widening through flattening, in summer, of a narrow (5–15 m-wide) mobile zone of the profile in order to enhance the ‘carrying’ capacity of this highly touristic beach. Beach widening and flattening following nourishment bring close to the very steep inner shoreface zone several cubic metres of gravel for each metre of beach that may be permanently lost downslope during autumn and winter storms. Recharged gravel is redistributed alongshore and offshore leakage is probably enhanced where small narrow submarine canyon heads impinge on the beach, resulting in a very narrow shoreface. Mean beach width shows an oscillating alongshore pattern that may be due to the influence of these canyons as pathways of gravel loss offshore. However, there is no correlation between mean beach width and distance to the 10-m isobath, used as a surrogate for inner shoreface width. Storms are associated with plunging waves that are particularly effective and concentrated, on this almost tideless shore, over the narrow mobile zone of the beach profile where a series of steep reflective berms are built during storms. The high dynamic pressures associated with this narrow zone of concentrated wave breaking, and energy reflection from the steepened profile, are deemed to contribute to the permanent downslope loss of gravel. This situation of long-term gravel loss is probably accepted by the beach management authority because of the low cost of obtaining nourishment material and the advantages derived from a temporarily wider beach in terms of recreational space.     

Examining the impact of multiple climate forcings on simulated Southern Hemisphere climate variability

Climate Dynamics - The study examines the influence of external climate forcings, and atmosphere–ocean–sea–ice coupled interaction on the Southern Hemisphere (SH) atmospheric...     

A probabilistic permeability model and the pore size density function

Mathematical interpretation of the pore size disribution (PSD) data as measured by mercury intrusion porosimetry was revealed in detail. The PSD data were commonly presented as cumulative intruded volume per gram of specimen versus pore size. In this paper, however, they were expressed in a dimensionless term for convenient mathematical operations. The pore size density function was deduced from the PSD data using the finite difference approximation and curve-fitting technique. For the prediction of permeability, first the published correlations between permeability and pore geometry were critically reviewed. A probabilistic permeability model based on the pore size density function was then developed, which can be thought of as a generalization of Childs and Collis-George's model. Predictions of permeability of the compacted soils studied using the developed model were very good for a wide range of permeabilities.     

The Blacktail Creek Tuff: an analytical and experimental study of rhyolites from the Heise volcanic field,Yellowstone hotspot system

The magma storage conditions of the 6.62 Ma Blacktail Creek Tuff eruption, belonging to the Heise volcanic field (6.62–4.45 Ma old) of the Yellowstone hotspot system, have been investigated by combining thermobarometric and experimental approaches. The results from different geothermometers (e.g., Fe–Ti oxides, feldspar pairs, apatite and zircon solubility, and Ti in quartz) indicate a pre-eruptive temperature in the range 825–875 °C. The temperature estimated using two-pyroxene pairs varies in a range of 810–950 °C, but the pyroxenes are probably not in equilibrium with each other, and the analytical results of melt inclusion in pyroxenes indicate a complex history for clinopyroxene, which hosts two compositionally different inclusion types. One natural Blacktail Creek Tuff rock sample has been used to determine experimentally the equilibrium phase assemblages in the pressure range 100–500 MPa and a water activity range 0.1–1.0. The experiments have been performed at fluid-present conditions, with a fluid phase composed of H₂O and CO₂, as well as at fluid-absent conditions. The stability of the quartzo-feldspathic phases is similar in both types of experiments, but the presence of mafic minerals such as biotite and clinopyroxene is strongly dependent on the experimental approach. Possible explanations are given for this discrepancy which may have strong impacts on the choice of appropriate experimental approaches for the determination of magma storage conditions. The comparison of the composition of natural phases and of experimentally synthesized phases confirms magma storage temperatures of 845–875 °C. Melt water contents of 1.5–2.5 wt% H₂O are required to reproduce the natural Blacktail Creek Tuff mineral assemblage at these temperatures. Using the Ti-in-quartz barometer and the Qz–Ab–Or proportions of natural matrix glasses, coexisting with quartz, plagioclase and sanidine, the depth of magma storage is estimated to be in a pressure range between 130 and 250 MPa.