Decoupling of arsenic and iron release from ferrihydrite suspension under reducing conditions: a biogeochemical model

High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis. Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted. Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant, or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction revealed vivianite Fe(II)₃(PO₄)₂.8H₂O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results. The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully applied to recent experimental results on the release of arsenic from Bengal delta sediments.     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

The Ultimate CCD for Laser Guide Star Wavefront Sensing on Extremely Large Telescopes

All of the extremely large telescopes (ELTs) will utilize sodium laser guide star (LGS) adaptive optics (AO) systems. Most of these telescopes plan to use the Shack-Hartmann approach for wavefront sensing. In these AO systems, the laser spots in subapertures at the edge of the pupil will suffer from spot elongation due to the 10 km extent of the sodium layer and the large separation from the projection laser. This spot elongation will severely degrade the performance of standard geometry wavefront sensing systems. In this paper, we present a CCD with custom pixel morphology that aligns the pixels of each subaperture with the radial extension of the LGS spot. This CCD design will give better performance than a standard geometry CCDs for continuous wave lasers. In addition, this CCD design is optimal for a pulsed sodium laser. The pixel geometry enables each subaperture to follow a laser pulse traversing the sodium layer, providing optimal sampling of a limited number of detected photons. In addition to novel pixel layout, this CCD will also incorporate experimental JFET sense amplifiers and use CMOS design approaches to simplify the routing of biases, clocks and video output. This CCD will attain photon-noise limited performance at high frame rates, and is being incorporated in the plans for the Thirty Meter Telescope (TMT).     

Towards bridging the gap between climate change projections and maize producers in South Africa

Theoretical and Applied Climatology - Multi-decadal regional projections of future climate change are introduced into a linear statistical model in order to produce an ensemble of austral...     

Mobility of arsenic in West Bengal aquifers conducting low and high groundwater arsenic. Part I: Comparative hydrochemical and hydrogeological characteristics

The present study demonstrates the importance of hydrogeochemical characteristics (groundwater flow and recharge) of an aquifer in the release of As to groundwater. The study area (∼20 km²) is located in Chakdaha block, Nadia district, West Bengal, which hosts groundwaters of variable As content. The spatial distribution pattern of As is patchy with areas containing groundwater that is high in As (>200 μg L⁻¹) found in close vicinity to low As (<50 μg L⁻¹) groundwaters (within 100 m). The concentration of groundwater As is found to decrease with depth. In addition, the data shows that there is no conspicuous relationship between high groundwater As concentration and high groundwater abstraction, although the central cone of depression has enlarged over 2 a and is extending towards the SE of the study area. The river Hooghly, which forms the NW boundary of the study site, shows dual behaviour (effluent and influent during pre- and post-monsoon periods, respectively), complicating the site hydrogeology. The observed groundwater flow lines tend to be deflected away from the high As portion of the aquifer, indicating that groundwater movement is very sluggish in the As-rich area. This leads to a high residence time for this groundwater package, prolonging sediment–water interaction, and hence facilitating groundwater As release.     

High‐resolution evolution of terrigenous sediment yields in the Provence Basin during the last 6 Ma: relation with climate and tectonics

Basin‐wide correlation of Messinian units and Plio‐Quaternary chronostratigraphic markers (5.3 Ma, 2.6 Ma, 0.9 Ma and 0.45 Ma), the mapping of total sediment thickness and the determination of overall sedimentary volumes enabled us to provide a high‐resolution quantitative history of sediment volumes for the last 6 Ma along the Gulf of Lions margin. The results point to (i) a dramatic increase in terrigenous sediment input during the Messinian Salinity Crisis. This increased sedimentation reflects enhanced regional fluvial erosion related to the dramatic fall of Mediterranean base‐level. Stronger weathering due to a regional wetter climate probably also increased erosional fluxes. (ii) A sediment input three times higher during the Plio‐Quaternary compared to the Miocene seems in agreement with published measurements from World's ocean. However, the timing of this increase being uncertain, it implies that the trigger(s) also remain(s) uncertain. (iii) A decrease in detrital volume around 2.6 Ma is attributed to a regional change in the drainage pattern of rivers in the northwestern Alps. (iv) This study also highlights the Mid‐Pleistocene Revolution around 0.9 Ma, which resulted in an almost doubling of sediment input in the Provencal Basin.     

Study of inorganic ligand-chromium(III)-surface ternary complexes by ESR spectroscopy

Cr(III) sorbed at the solid/water interface of latex and hectorite was studied by ESR spectroscopy in the presence of different inorganic ligands. The ESR spectra of the surface obtained in the presence of selenite, phosphate and fluoride can be explained in terms of ternary surface complex formation. This is contrasted by the behaviour of sulfate and selenate ions which were found to have no effect on the ligand field of Cr(III), either in the adsorbed state or in solution.     

Quartz thermoluminescence (TL) in gold exploration; some applications

The possible uses of thermoluminescence in mineral exploration are summarised. The methodology is described and some applications for gold exploration are developed with regard to the district of St-Yrieix (Limousin, France), the district of Salsigne (Herault, France) and some occurrences in the Ardenne massif (Belgium). From these cases, different possibilities may be mentioned: the distinction of various types of mineralized structures (St-Yrieix); the evaluation of the potential of mineralized districts from samples collected in the old mining works or in the superficial formations, etc. (St-Yrieix; Ardenne massif), and the determination of a genetic affiliation between different types of mineralizations (e.g. between stratiform deposits and vein-type deposits: the comparison between the districts of St-Yrieix and Salsigne). Finally new possibilities using the TL sensitivity and the equation of the straight lines NTL (natural TL) and ATL (induced TL) are evaluated.     

The UV cameras on the High Energy Transient Experiment (HETE)

The High Energy Transient Experiment (HETE), scheduled for launch this year, is a small satellite dedicated to multiwavelength observations of -ray and X-ray bursts. The HETE spacecraft will be equipped with gamma-ray detectors, X-ray detectors with a coded mask, and ultraviolet-sensitive CCD cameras. The UV cameras on HETE are wide-field imagers which will a) provide UV images of the regions in which -ray or X-ray bursts are detected, before, duringand after the burst, b) detect UV transients, whether associated with a high-energy transient or not, c) monitor the brightnesses of field stars for variability over a wide range of timescales, and d) serve as star trackers for HETE. In this poster, we describe the HETE UV instrumentation, control software, and data products.     

Contextualizing vulnerability assessment: a support to geo-risk management in central Africa

European Union directives as well as national legislation are placing great emphasis on the inclusion of stakeholder perspectives in the governance of risks from natural hazards. This should help decision makers formulate better policies. However, to date, there is little information on stakeholders’ perspectives with respect to landslide risk governance. This paper addresses the gap by reporting on research in Nocera Inferiore, Italy. The research is based on a documentary analysis, 43 semi-structured interviews and a survey submitted to 373 residents. The political instability, the unfairness of national funding allocation across municipalities and the residents’ lack of knowledge about risk assessment and emergency planning are some of the main barriers to effective risk governance. Moreover, there are divergent, sometimes even opposite, stakeholders’ views on several issues, such as the relevance of illegal development in risky areas. The results highlight the importance of addressing these divergent views and including the plurality of voices as a prerequisite for inclusive risk governance. The research provided essential background information for a participatory process, which was designed to support decisions on landslide risk mitigation measures in Nocera Inferiore (Linnerooth-Bayer et al. this issue). The methodology will be of more general interest to researchers and policymakers intent upon including stakeholder perspectives in natural risk governance.