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31.
32.
Electron Probe Microanalysis of Bromine in Minerals and Glasses with Correction for Spectral Interference from Aluminium,and Comparison with Microbeam Synchrotron X‐Ray Fluorescence Spectrometry
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Chao Zhang Jinru Lin Yuanming Pan Renfei Feng Renat R. Almeev Francois Holtz 《Geostandards and Geoanalytical Research》2017,41(3):449-457
The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al2O3 content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses. 相似文献
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François Charlet Marc De Batist Emmanuel Chapron Sébastien Bertrand Mario Pino Roberto Urrutia 《Journal of Paleolimnology》2008,39(2):163-177
Prior to the collection of a series of sediment cores, a high- and very-high-resolution reflection seismic survey was carried
out on Lago Puyehue, Lake District, South-Central Chile. The data reveal a complex bathymetry and basin structure, with three
sub-basins separated by bathymetric ridges, bedrock islands and interconnected channels. The sedimentary infill reaches a
thickness of >200 m. It can be sub-divided into five seismic-stratigraphic units, which are interpreted as: moraine, ice-contact
or outwash deposits (Unit I), glacio-lacustrine sediments rapidly deposited in a proglacial or subglacial lake at the onset
of deglaciation (Unit II), lacustrine fan deposits fed by sediment-laden meltwater streams in a proglacial lake (Unit III),
distal deposits of fluvially derived sediment in an open, post-glacial lake (Unit IV) and authigenic lacustrine sediments,
predominantly of biogenic origin, that accumulated in an open, post-glacial lake (Unit V). This facies succession is very
similar to that observed in other glacial lakes, and minor differences are attributed to an overall higher depositional energy
and higher terrigenous input caused by the strong seismic and volcanic activity in the region combined with heavy precipitation.
A long sediment core (PU-II core) penetrates part of Unit V and its base is dated as 17,915 cal. yr. BP. Extrapolation of
average sedimentation rates yields an age of ca. 24,750 cal. yr. BP for the base of Unit V, and of ca. 28,000 cal. yr. BP
for the base of Unit IV or for the onset of open-water conditions. This is in contrast with previous glacial-history reconstructions
based on terrestrial records, which date the complete deglaciation of the basin as ca. 14,600 cal. yr. BP. This discrepancy
cannot be easily explained and highlights the need for more lacustrine records from this region.
This is the second in a series of eight papers published in this special issue dedicated to the 17,900 year multi-proxy lacustrine record of
Lago Puyehue, Chilean Lake District. The papers in this special issue were collected by M. De Batist, N. Fagel, M.-F. Loutre
and E. Chapron. 相似文献
36.
Marisa?Giuffrida Francois?Holtz Francesco?Vetere Marco?ViccaroEmail author 《Contributions to Mineralogy and Petrology》2017,172(11-12):90
Changes in magmatic assemblages and crystal stability as a response of CO2-flushing in basaltic systems have rarely been directly addressed experimentally, making the role of CO2 in magma dynamics still controversial and object of scientific debate. We conducted a series of experiments to understand the response of magmas from Etna volcano to CO2 flushing. We performed a first experiment at 300 MPa to synthesize a starting material composed of crystals of some hundreds of µm and melt pools. This material is representative of an initial magmatic assemblage composed of plagioclase, clinopyroxene and a water-undersaturated melt with 1.6 wt% H2O. In a second step, the initial assemblage was equilibrated at 300 and 100 MPa with fluids having different XCO 2 fl (CO2/(H2O + CO2)). At low XCO 2 fl (< 0.2 to 0.4), plagioclase is completely dissolved and clinopyroxene show dissolution textures. For relatively high XCO 2 fl (0.9 at 300 MPa), the flushing of a CO2-rich fluid phase leads to an increase of the amount of clinopyroxene and a decrease of the abundance of plagioclase at 300 MPa. This decrease of plagioclase proportion is associated with a change in An content. Our experiments demonstrate that flushing basaltic systems with fluids may drastically affect crystal textures and phase equilibria depending on proportions of H2O and CO2 in the fluid phase. Since texture and crystal proportions are among the most important parameters governing the rheology of magmas, fluid flushing will also influence magma ascent to the Earth’s surface. The experimental results open new perspectives to decipher the textural and compositional record of minerals observed in volcanic rocks from Mt. Etna, and at the same time offer the basis for interpreting the information preserved in minerals from other basaltic volcanoes erupting magmas enriched in CO2. 相似文献
37.
Hiroaki?SatoEmail author Francois?Holtz Roman?E.?Botcharnikov Setsuya?Nakada 《Contributions to Mineralogy and Petrology》2017,172(4):22
Mafic enclaves in the 1991–1995 dacite of Unzen volcano show chemical and textural variability, such as bulk SiO2 contents ranging from 52 to 62 wt% and fine- to coarse-grained microlite textures. In this paper, we investigated the mineral chemistry of plagioclase and hornblende microlites and distinguished three enclave types. Type-I mafic enclaves contain high-Mg plagioclase and low-Cl hornblende as microlites, whereas type-III enclaves include low-Mg plagioclase and high-Cl hornblende. Type-II enclaves have an intermediate mineral chemistry. Type-I mafic enclaves tend to show a finer-grained matrix, have slightly higher bulk rock SiO2 contents (56–60 wt%) when compared with the type-III mafic enclaves (SiO2?=?53–59 wt%), but the overall bulk enclave compositions are within the trend of the basalt–dacite eruptive products of Quaternary monogenetic volcanoes around Unzen volcano. The origin of the variation of mineral chemistry in mafic enclaves is interpreted to reflect different degree of diffusion-controlled re-equilibration of minerals in a low-temperature mushy dacitic magma reservoir. Mafic enclaves with a long residence time in the dacitic magma reservoir, whose constituent minerals were annealed at low-temperature to be in equililbrium with the rhyolitic melt, represent type-III enclaves. In contrast, type-I mafic enclaves result from recent mafic injections with a mineral assemblage that still retains the high-temperature mineral chemistry. Taking temperature, Ca/(Ca?+?Na) ratio of plagioclase, and water activity of the hydrous Unzen magma into account, the Mg contents of plagioclase indicate that plagioclase microlites in type-III enclaves initially crystallized at high temperature and were subsequently re-equilibrated at low-temperature conditions. Compositional profiles of Mg in plagioclase suggest that older mafic enclaves (Type-III) had a residence time of ~100 years at 800 °C in a stagnant magma reservoir before their incorporation into the mixed dacite of the 1991–1995 Unzen eruption. Presence of different types of mafic enclaves suggests that the 1991–1995 dacite of Unzen volcano tapped mushy magma reservoir intermittently replenished by high-temperature mafic magmas. 相似文献
38.
Brunet Morgane Moretti Laurent Le Friant Anne Mangeney Anne Fernández Nieto Enrique Domingo Bouchut Francois 《Natural Hazards》2017,85(2):1189-1208
Natural Hazards - In November 2015, China government announced that the national carbon emissions trading market is expected to start in 2017. Carbon emission trading system is a raising concern... 相似文献
39.
Maviza Auther Grab Stefan Engelbrecht Francois 《Theoretical and Applied Climatology》2022,149(1-2):309-325
Theoretical and Applied Climatology - This study evaluates precipitation trends in the upper Mzingwane sub-catchment (UMS) of Zimbabwe using ten World Meteorological Organization (WMO)’s... 相似文献
40.
Alexander Borisov Harald Behrens Francois Holtz 《Contributions to Mineralogy and Petrology》2013,166(6):1577-1591
The effect of TiO2 and P2O5 on the ferric/ferrous ratio in silicate melts was investigated in model silicate melts at air conditions in the temperature range 1,400–1,550 °C at 1-atm total pressure. The base composition of the anorthite–diopside eutectic composition was modified with 10 wt % Fe2O3 and variable amounts of TiO2 (up to 30 wt %) or P2O5 (up to 20 wt %). Some compositions also contained higher SiO2 concentrations to compare the role of SiO2, TiO2, and P2O5 on the Fe3+/Fe2+ ratio. The ferric/ferrous ratio in experimental glasses was analyzed using a wet chemical technique with colorimetric detection of ferrous iron. It is shown that at constant temperature, an increase in SiO2, TiO2, and P2O5 content results in a decrease in the ferric/ferrous ratio. The effects of TiO2 and SiO2 on the Fe3+/Fe2+ ratio was found to be almost identical. In contrast, adding P2O5 was found to decrease ferric/ferrous ratio much more effectively than adding silica. The results were compared with the predictions from the published empirical equations forecasting Fe3+/Fe2+ ratio. It was demonstrated that the effects of TiO2 are minor but that the effects of P2O5 should be included in models to better describe ferric/ferrous ratio in phosphorus-bearing silicate melts. Based on our observations, the determination of the prevailing fO2 in magmas from the Fe3+/Fe2+ ratio in natural glasses using empirical equations published so far is discussed critically. 相似文献