试论大火成岩省与成矿作用

根据组成大火成岩省的岩浆类型不同,大火成岩省可以分为两类,一是以基性火成岩为主的镁铁质大火成岩省（MLIPs）,二是以酸性火成岩为主的长英质大火成岩省（SLIPs）。它们都是由于在异常高的地幔热流参与下导致地幔或地壳大规模熔融形成的。大火成岩省独特的巨量岩浆活动是引起多层次物质和能量交换的重要场 所。成矿物质的聚集导致成矿作用和矿床的形成是必然的,因此大火成岩省本身就是一个大成矿系统。在这个成矿系统中,由于物源、成分、温度、压力、流体和氧逸度等条件的差异性,形成不同种类的矿化和矿床,并构成一定的成矿系列。镁铁质大火成岩省中形成的矿床类型有岩浆硫化物型Cr-Cu-Ni-PGE矿床和Ti-Fe 氧化物型V-Ti-Fe 矿床,热液型的Cu-Pb-Zn-Au-Ag矿床,以及远程低温热液矿床等。长英质大火成岩省形成的矿床类型为岩浆和交代型、热液型Cu-Pb-Zn-Au-Ag,W-Sn,U-Th-REE矿床,以及Sb-As矿床等。加强对大火成岩省及其成矿机理的研究,有望形成新的成矿理论和加速超大型矿床的发现。     

Low-pH waters discharging from submarine vents at Panarea Island (Aeolian Islands,southern Italy) after the 2002 gas blast: Origin of hydrothermal fluids and implications for volcanic surveillance

A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate (i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and (ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.     

Carbonate-hosted siliceous crust type mineralization of Carnic Alps (Italy-Austria)

A carbonate-hosted stratabound siliceous crust type (SCT) mineralization (base metal sulphides, barite, fluorite) occurs over large areas of Carnic Alps and Karawanken in the Eastern Alps. It concerns a pervasively silicified lithological unit, up to some tens of metres thick, which caps the unconformity landscapes developed on epicontinental Devonian–Dinantian carbonates. The SCT mineralization is directly overlaid by different transgressive siliciclastic sediments, which range from Lower Carboniferous to Lower Permian. The presence of fragments of the SCT mineralization in the transgressive siliciclastic sediment bounds its whole lithological evolution within a short stratigraphic interval of Lower Carboniferous age. Selected features of the regional and lithostratigraphic setting are discussed. The chemical characterisation is based on the statistical evaluation of compositional data of 581 selected samples. Three significant groups of elements have been distinguished: (1) the hydrological and metasomatically active elements (Si, Ba, F), which show a strong negative correlation amongst themselves and characterise the silica-saturated aqueous solutions; (2) the terrigenous elements (Al₂O₃, K₂O, Fe_tot, TiO₂, B, Be, Ce, La, Nb, V, Y, Zr), which suggest a continental margin environment for silica deposition; (3) the sulphide metals (Cu, Pb, Zn, Ni, Sb, As, Hg, Cd), which define the metalliferous signature of the SCT mineralization.Some consistent, but still debatable genetic aspects of the SCT mineralization are as follow: (1) silica may be supplied by illitization of clay-rich basinal sediments during their diagenesis. δ¹⁸O of microcrystalline quartz ranges from +18.5‰ and +24.6‰ and is very similar to δ¹⁸O of authigenic quartz deriving from diagenetic processes of illitization of clay-rich basinal sequences. (2) The diagenetic evolution of these sediments may trigger off the movement of silica-rich marine pore waters. δ³⁴S of barite ranges from +15.5‰ to +19.3‰ with an average of +17.7‰ and are in good agreement with δ³⁴S of sulphate in ocean waters of Upper Devonian–Lower Carboniferous age. (3) A convective hydrological system, connected with sinsedimentary transtensive tectonics, active in the Carnic Alps since the Frasnian, may be the transport mechanism of aqueous solutions. (4) A weak drop in pH in the dominant carbonate environment represents the conditions for silica precipitation.SCT mineralization, showing persistent, independent and distinct characters, occurs over large areas also in other sites of the Alpine belt and outside Italy and Austria. Therefore, it points to important markers for some sedimentary sequences as well as to a worldwide significant cyclic metallogenic event. It represents a new ore deposit-type within the carbonate-hosted mineralization.     

Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy

With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO₃.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO₃²⁻ ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE³⁺ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.     

Evolution of the Mesozoic Granites in the Xiong''ershan-Waifangshan Region,Western Henan Province,China,and Its Tectonic Implications

Based on the new data of isotopic ages and geochemical analyses, three types of Mesozoic granites have been identified for the Xiong'ershan-Waifangshan region in western Henan Province: high-Ba-SrⅠ-type granite emplaced in the early stage (～160 Ma),Ⅰ-type granite in the middle stage (～130 Ma) and anorogenic A-type granite in the late stage (～115 Ma). Geochemical characteristics of the high-Ba-SrⅠ-type granite suggest that it may have been generated from the thickened lower crust by partial melting with primary residues of amphibole and garnet. Gradual increase of negative Eu anomaly and Sr content variations reflect progressive shallowing of the source regions of these granites from the early to late stage. New 40Ar/39Ar plateau ages of the early-stage Wuzhangshan granite (156.0±1.1 Ma, amphibole) and middle-stage Heyu granite (131.8±0.7 Ma, biotite) are indistinguishable from their SHRIMP U-Pb ages previous published, indicating a rapid uplift and erosion in this region. The representative anorogenic A-type granite, Taishanmiao pluton, was emplaced at～115 Ma. The evolution of the granites in this region reveals a tectonic regime change from post-collisional to anorogenic between～160 Ma and～115 Ma. The genesis of the early- and middle-stageⅠ-type granites could be linked to delamination of subducted lithosphere of the Qiniing orogenic belt, while the late-stage A-type granites represent the onset of extension and the end of orogenic process. In fact, along the Qiniing -Dabie-Sulu belt, the Mesozoic granitoids in western Henan, Dabieshan and Jiaodong regions are comparable on the basis of these temporal evolutionary stages and their initial 87Sr/86Sr ratios, which may suggest a similar geodynamic process related to the collision between the North China and Yangtze cratons.     

河南铁炉坪银矿床的地质和D-O-C同位素体系及成因

铁炉坪银矿产于熊耳地体高级变质基底内的 NE向断裂带中 ,是最新发现的一个重要的中生代造山型 Ag- Pb和Au矿带的一部分。成矿过程包括早 (E)、中 (M)、晚 (L ) 3个阶段 ,分别形成石英 -黄铁矿组合 (E)、多金属硫化物组合(M)和碳酸盐脉 (L)。早阶段流体的 δD=- 90‰ ,δ1 3CCO     

Infiltration effects on a two-dimensional molecular dynamics model of landslides

We propose a two-dimensional computational model for deep landslides triggered by rainfall, based on interacting particles or grains. The model describes a vertical section of a fictitious granular material along a slope, in order to study the behavior of a wide-thickness landslide. The triggering of the landslide is caused by the exceeding of two conditions: a threshold speed and a condition on the static friction of the particles, the latter based on the Mohr–Coulomb failure criterion (Coulomb in Mem Acad R Div Sav 7:343–387, 1776; Mohr in Abhandlungen aus dem Gebiete der Technischen Mechanik. Ernst, Berlin, 1914). The interparticle interactions are represented as a potential that, in the absence of suitable experimental data and due to the arbitrariness of the grain dimension, is modeled similarly to the Lennard-Jones’ one (Lennard-Jones in Proc R Soc Lond A 106(738):463–477, 1924), i.e., with an attractive and a repulsive part. For the updating of the particle positions, we use a molecular dynamics method, which is quite suitable for this type of systems (Herrmann and Luding in Continuum Mech Thermodyn 10:189–231, 1998). An infiltration scheme is introduced for modeling the increasing pore pressure due to the rainfall. Finally, we also introduce the viscosity in the dynamical equations of motion. The statistical characterization and dynamical behavior of the results of simulations are quite satisfactory relative to real landslides: We obtain a power law distribution of landslide triggering times, and the velocity patterns are typical of real cases, including the acceleration progression. Therefore, we can claim that this type of modeling can represent a new method to simulate landslides triggered by rainfall.     

Distribution of trace elements in filtered and non filtered aqueous fractions: Insights from rivers and streams of Sardinia (Italy)

The distribution of several trace elements in different aqueous fractions has been studied in running waters from Sardinia (Italy). Trace elements and major components were determined in water samples collected at high- and low-discharge from rivers (90 samples) and streams (70 samples). At selected sites, total (non filtered samples) and dissolved (0.4 μm and 0.015 μm pore-size filtered samples) amounts of trace elements were determined, and the composition of the solid matter retained on the filters was investigated for estimating the eventual interrelationship. The elements B, Li, Rb, Sr, Ba, As, Sb, Mo, Tl and U in the studied waters showed small differences between total and dissolved amounts; dissolved concentrations were higher under low flow conditions, when the contribution of rainwater to the rivers was minimum; their concentrations were often correlated with total dissolved solids (TDS), and appeared to be related to the intensity of water-rock interaction processes. The elements Al, Fe, Mn, Pb, Zn, Cd, Cu, Co, Ni, Cs, Y, REE and Th were not related to TDS and/or major ions; they showed higher concentrations under high flow conditions; marked differences occurred between total and dissolved amounts; much lower concentrations were generally observed in the water filtered through 0.015 μm than in the water filtered through 0.4 μm, especially when sampling was carried out after heavy rain events that enhanced the load of solid matter in the water. These observations indicate an aqueous transport via sorption processes on very fine particles, such as Fe-oxide/hydroxide and clay mineral particles, which have been inferred by SEM-EDX analyses of the matter retained on the filters.     

New Ar–Ar age constraints on the deformation along the Machaoying fault zone: Implications for Early Cambrian tectonism in the North China Craton

The Machaoying fault zone extends along the southern margin of the North China Craton (NCC) and controlled the regional structures and hydrothermal mineral systems in this area. The fault underwent at least two major deformational phases, as revealed by macro- and micro-structural observations from a well-developed segment of the fault in the Hongzhuang–Baitu area, located south of the Xiong'er Mountains. Early ductile deformation is characterized by thrusting from north to south, which was subsequently overprinted by late brittle faulting. Syntectonic strain shadows of biotite are preserved around rotated porphyroclasts of quartz amygdales in mylonite. The biotite yields a ⁴⁰Ar–³⁹Ar plateau age of 524.9 ± 1.9 Ma, which is interpreted as the time of regional thrusting along the Machaoying fault zone. The thrusting may be temporally correlated with an Early Cambrian discontinuity in sedimentation observed in the rocks sequences of the NCC, suggesting a compressional regime in this area and a craton-wide tectonic event. Many 540–500 Ma tectonic events have been previously identified in the Qinling–Qilian–Kunlun Orogenic Belt of central China and in massifs in northeastern China, both of which surround the NCC, and some of these were interpreted to be associated with assembly of Gondwana. However, paleomagnetic data indicate that the NCC was unlikely to have been connected with Gondwana in the Early Cambrian and thus our new biotite date cannot record deformation along the Gondwanan margin. Dating of K-feldspar from a quartz–K-feldspar vein formed along one of the brittle faults of the Machaoying fault zone yields a much younger ⁴⁰Ar–³⁹Ar plateau age of 119.5 ± 0.7 Ma. This is a minimum age for the brittle deformation along the southern margin of the NCC, which also overlaps the age of widespread gold and molybdenum mineralization in the region.