High-resolution atmospheric forcing for regional oceanic model: the Iroise Sea

This study was aimed at modeling, as realistically as possible, the dynamics and thermodynamics of the Iroise Sea by using the Model for Applications at Regional Scale (MARS), a regional ocean 3D model. The horizontal resolution of the configuration in use is 2 km with 30 vertical levels. The 3D model of the Iroise Sea is embedded in a larger model providing open boundary conditions. As regards the atmospheric forcing, the originality of this study is to force the regional ocean model with the high-resolution (6 km) regional meteorological model, Weather Research and Forecasting (WRF). In addition, as the air surface temperature is highly sensitive to the sea surface temperature (SST), this regional meteorological model is improved by taking into account a regional climatologic SST to compute meteorological parameters. By allowing a better coherence between the SST and the temperature of the atmospheric boundary layer while giving a more realistic representation of heat fluxes exchanged at the air/sea interface, this forcing constitutes a noticeable improvement of the Iroise Sea modeling. The different sensitivity tests discussed here pinpoint the importance of entering, in WRF, SST data of sufficiently high quality before the computation of meteorological forcing when the aim is a study of dynamics and thermodynamics far away from the coast. On the other hand, when the target is the reproduction of coastal small-scale features in Iroise Sea modeling, the resolution of the meteorological forcing and the quality of SST are both paramount. The simulation of reference was carried out throughout the Summer and Autumn of year 2005 to allow comparisons with a campaign of surface current measurements by high-frequency radars conducted at the same period.     

Intertidal subsidence and collapse features on wave‐exposed,drift‐aligned sandy beaches subject to Amazon mud: Cayenne,French Guiana

Short‐lived collapse features affecting the intertidal sandy profile were observed on mud‐rich beaches in Cayenne. They were formed in packets of beach sand accumulating over thick (several metres) fluid to under‐consolidated foreshore mud, which adjusts to this sand loading by seaward and longshore migration of fluid mud and subsequent in situ mud dewatering, thus generating subsidence and deformation of the overlying sand sheet. These sandy collapse features required active longshore sand transport and were washed out by wave processes at each rising tide. They finally disappeared permanently as adjustment of the underlying mud enabled stabilization of the beach profile. Copyright © 2006 John Wiley & Sons, Ltd.     

Simulation of damage–permeability coupling for mortar under dynamic loads

The results reported in this paper deal with the simulation of damage in cohesive geomaterials such as rocks or concrete subjected to dynamic loads. The practical objective is to stimulate the production of tight gas reservoirs with a technique that is an alternative to hydraulic fracturing. The principle is that when subjected to dynamic loads, cohesive materials such as concrete, rocks or ceramics exhibit distributed micro‐cracking as opposed to localised cracking observed under static loads. Hence, a low permeability rock containing gas trapped into occluded pores can be fragmented with the help of dynamic loads, and gas can be extracted in a much more efficient way compared with hydraulic fracturing, where only large macro cracks are formed with very few connections between occluded pores. At the stage of laboratory development of this technique, compressive underwater shock waves have been used to increase the intrinsic permeability of concrete specimens. In a previous study, pressure waves generated by pulsed arc electrohydraulic discharges in water were used in order to induce micro‐cracking and an increase of average permeability of concrete hollow cylinders subjected to confinement stresses (equivalent to geostatic stresses). We discuss here a 3‐D anisotropic constitutive model aimed at describing the dynamic response of these specimens. It is based on rate‐dependent continuum damage constitutive relations. Crack closure effects and damage‐induced anisotropy are included in the model. The directional growth of damage is related to the directional growth of material intrinsic permeability. Numerical simulations of damage induced by shock waves show good agreement with the experiments for various confinement levels of the specimens. Copyright © 2013 John Wiley & Sons, Ltd.     

Experimental determination of synthetic NdPO4 monazite end-member solubility in water from 21°C to 300°C: implications for rare earth element mobility in crustal fluids

The solubility of synthetic NdPO₄ monazite end-member has been determined experimentally from 21 to 300°C in aqueous solutions at pH = 2, and at 21°C and pH = 2 for GdPO₄. Measurements were performed in batch reactors, with regular solution sampling for pH measurement, rare earths and phosphorous analysis by inductively coupled plasma mass spectrometry (ICP-MS) coupled with a desolvation system. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were employed to check that no reprecipitation of secondary phases occurred and that the mineral surfaces remained those of a monazite. Coupled with speciation calculations, measured solution compositions permitted the determination of NdPO₄ and GdPO₄ solubility products which are in general agreement with previous experimental determination on rhabdophane at 25°C, but showing that monazite is more than two orders of magnitude less soluble than inferred on the basis of previous thermodynamic estimates. The temperature evolution from 21 to 300°C of the equilibrium constant (K) of the NdPO₄ monazite end-member dissolution reaction given by:

     

Suitability of airborne laser scanning for the assessment of forest protection effect against rockfall

Rockfall simulation models are now able to quantify the protective effect of forest with the integration of rock impacts on trees. Those models require spatially explicit forest characteristics which are costly to acquire in operational conditions. The present study compares rockfall simulation results obtained with different forest input data sources: field data with different levels of spatial detail and two methods based on airborne Lidar data. Three different forest stands are tested with several virtual terrain configurations. When rockfall energies are below 200 kJ, the forest protection effect is significant. For higher energies, it also exists but it is minor compared to the effects of topography and rock volume. For all forest input data sources, the estimated rockfall intensity is within ?13 and 16 % of the reference value, whereas the frequency is generally overestimated. Both Lidar methods yield a satisfactory forest protection effect evaluation, but single tree detection tends to underestimate it. Improvements are possible regarding the spatial heterogeneity of stem density and the diameter distribution by tree species.     

Quantification of the ferric/ferrous iron ratio in silicates by scanning transmission X-ray microscopy at the Fe L2,3 edges

Estimation of Fe³⁺/ΣFe ratios in materials at the submicrometre scale has been a long-standing challenge in the Earth and environmental sciences because of the usefulness of this ratio in estimating redox conditions as well as for geothermometry. To date, few quantitative methods with submicrometric resolution have been developed for this purpose, and most of them have used electron energy-loss spectroscopy carried out in the ultra-high vacuum environment of a transmission electron microscope (TEM). Scanning transmission X-ray microscopy (STXM) is a relatively new technique complementary to TEM and is increasingly being used in the Earth sciences. Here, we detail an analytical procedure to quantify the Fe³⁺/ΣFe ratio in silicates using Fe L_2,3-edge X-ray absorption near edge structure (XANES) spectra obtained by STXM, and we discuss its advantages and limitations. Two different methods for retrieving Fe³⁺/ΣFe ratios from XANES spectra are calibrated using reference samples with known Fe³⁺ content by independent approaches. The first method uses the intensity ratio of the two major peaks at the L₃-edge. This method allows mapping of Fe³⁺/ΣFe ratios at a spatial scale better than 50 nm by the acquisition of 5 images only. The second method employs a 2-eV-wide integration window centred on the L₂ maximum for Fe³⁺, which is compared to the total integral intensity of the Fe L₂-edge. These two approaches are applied to metapelites from the Glarus massif (Switzerland), containing micrometre-sized chlorite and illite grains and prepared as ultrathin foils by focused ion beam milling. Nanometre-scale mapping of iron redox in these samples is presented and shows evidence of compositional zonation. The existence of such zonation has crucial implications for geothermometry and illustrates the importance of being able to measure Fe³⁺/ΣFe ratios at the submicrometre scale in geological samples.     

ASSESSMENT OF A SIMPLE METHOD FOR THE DETERMINATION OF NB AND TA AT THE SUB-μG/G LEVEL IN SILICATE ROCKS BY ICP-MS

We report Nb and Ta data for 15 international silicate rock standards, obtained by inductively coupled plasma-mass spectrometry (ICP-MS) measurement following decomposition with HF-HNOs-HCI.⁹⁵ Moand¹⁸⁵Re were used as internal standards, and calibration lines were constructed with artificial solutions. Typical relative standard deviations are better than 10% above 0.2 μg/g, and detection limits for Nb and Ta are 40 and 0.8 ng/g, respectively. The results are generally in good agreement with published data. Moreover, this study points out the Nb-Ta heterogeneity of some standard reference materials on the 100 mg scale.     

Why are climate policies of the present decade so crucial for keeping the 2 °C target credible?

Decision-makers have confirmed the long term objective of preventing a temperature increase greater than 2 °C. This paper aims at appraising by means of a cost-benefit analysis whether decision makers’ commitment to meet the 2 °C objective is credible or not. Within the framework of a cost-benefit type integrated assessment model, we consider that the economy faces climate damages with a threshold at 2 °C. We run the model for a broad set of scenarios accounting for the diversity of “worldviews” in the climate debate. For a significant share of scenarios we observe that it is considered optimal to exceed the threshold. Among those “non-compliers” we discriminate ”involuntary non-compliers” who cannot avoid the exceedance due to physical constraint from ”deliberate compliers” for whom the exceedance results from a deliberate costs-benefit analysis. A second result is that the later mitigation efforts begin, the more difficult it becomes to prevent the exceedance. In particular, the number of ”deliberate non-compliers” dramatically increases if mitigation efforts do not start by 2020, and the influx of involuntary non-compliers become overwhelming f efforts are delayed to 2040. In light of these results we argue that the window of opportunity for reaching the 2 °C objective with a credible chance of success is rapidly closing during the present decade. Further delay in finding a climate agreement critically undermines the credibility of the objective.     

A spectral comparison of (379) Huenna and its satellite

We present near-infrared spectral measurements of Themis family Asteroid (379) Huenna (D ∼ 98 km) and its 6 km satellite using SpeX on the NASA IRTF. The companion was farther than 1.5″ from the primary at the time of observations and was approximately 5 magnitudes dimmer. We describe a method for separating and extracting the signal of a companion asteroid when the signal is not entirely resolved from the primary. The spectrum of (379) Huenna has a broad, shallow feature near 1 μm and a low slope, characteristic of C-type asteroids. The secondary’s spectrum is consistent with the taxonomic classification of C-complex or X-complex. The quality of the data was not sufficient to identify any subtle feature in the secondary’s spectrum.     

Coupling eruption and tsunami records: the Krakatau 1883 case study,Indonesia

The well-documented 1883 eruption of Krakatau volcano (Indonesia) offers an opportunity to couple the eruption’s history with the tsunami record. The aim of this paper is not to re-analyse the scenario for the 1883 eruption but to demonstrate that the study of tsunami deposits provides information for reconstructing past eruptions. Indeed, though the characteristics of volcanogenic tsunami deposits are similar to those of other tsunami deposits, they may include juvenile material (e.g. fresh pumice) or be interbedded with distal pyroclastic deposits (ash fall, surges), due to their simultaneity with the eruption. Five kinds of sedimentary and volcanic facies related to the 1883 events were identified along the coasts of Java and Sumatra: (1) bioclastic tsunami sands and (2) pumiceous tsunami sands, deposited respectively before and during the Plinian phase (26–27 August); (3) rounded pumice lapilli reworked by tsunami; (4) pumiceous ash fall deposits and (5) pyroclastic surge deposits (only in Sumatra). The stratigraphic record on the coasts of Java and Sumatra, which agrees particularly well with observations of the 1883 events, is tentatively linked to the proximal stratigraphy of the eruption.