SHRIMP U–Pb dating of the Antucoya porphyry copper deposit: new evidence for an Early Cretaceous porphyry-related metallogenic epoch in the Coastal Cordillera of northern Chile

The Antucoya porphyry copper deposit (300 Mt at 0.45% total Cu) is one of the largest deposits of a poorly known Early Cretaceous porphyry belt in the Coastal Cordillera of northern Chile. It is related to a succession of granodioritic and tonalitic porphyritic stocks and dikes that were emplaced within Jurassic andesitic rocks of the La Negra Formation immediately west of the N–S trending sinistral strike-slip Atacama Fault Zone. New zircon SHRIMP U–Pb data indicate that the porphyries of Antucoya crystallized within the time span from 142.7 ± 1.6 to 140.6 ± 1.5 Ma (±2 σ), and late, unmineralized, NW–SE trending dacite dikes with potassic alteration and internal deformation crystallized at 141.9 ± 1.4 Ma. The Antucoya porphyry copper system appears to be formed after a change of stress conditions along the magmatic arc from extensional in the Late Jurassic to transpressive during the Early Cretaceous and provides support for an Early Cretaceous metallogenic episode of porphyry-type mineralization along the Coastal Cordillera of northern Chile.     

Factors affecting the performance of family planning workers: importance of geographical information systems in empirical analysis

Substantial variation in contraceptive prevalence rates (CPRs) and fertility rates (FRs) between community health workers (CHWs) has been documented since the inception of the Matlab family planning program in rural Bangladesh. The coefficients of variation of these indicators for Matlab CHWs were 7% and 26%, respectively, in 1995. To identify the reasons for these performance variations, geographical information system (GIS) approaches were applied to longitudinal and cross-sectional data on 80 CHWs for the period 1980-95. Each observation in the data-set included catchment area-specific characteristics, measures of CHW efficiency in service delivery, and CHW-specific characteristics for one specific year. A one-unit increase in the average age of target women in the catchment area increases the CPR by 9.2%. The CPR increases by 0.2% for each 1% increase in women's literacy and decreases by 0.1% for each 1% increase in the number of Muslim households in the catchment area. An increase of 1 sq. km in the size of the catchment area reduces the CPR by 3%. CHW performance increases with age up to 45 years and then decreases. Similarly, a 1-year increase in the average age of target women reduces the FR by 2%. A 10% increase in the size of the catchment area reduces program performance by increasing the FR by 1.4%. A single geographic barrier to movement increases the FR by 1%. This analysis indicates that CHW performance can be improved significantly by defining catchment areas through use of GIS techniques. Without knowledge of the spatial distribution of population and the physical barriers to movement, allocating a fixed number of clients per CHW may not be the most efficient approach.     

Site effect evaluation at Mexico City: Dominant period and relative amplification from strong motion and microtremor records

Site effects in Mexico City are discussed in terms of simple 1D, one-layer, linear models. The analysis is focussed on two parameters: dominant period and maximum amplification relative to a firm site within the city. The data used is a compilation of strong motion data and microtremor measurements. Strong motion data consist of digital acceleration records for nine events recorded by the Accelerographic Network of Mexico City. The authors analyzed spectral ratios of horizontal components of soft soil sites relative to an average of firm site observations for this data set. Dominant period, maximum relative amplification and an estimate of material damping were computed from the empirical transfer functions thus obtained. Microtremor data were compiled from measurement of different groups during the period 1985–1992. In all, 409 measurement points were analyzed. Values of dominant period obtained from microtremor measurements are in excellent agreement with those obtained from empirical transfer functions for strong motion data. The synthesis of results allows us to draw a detailed and robust map of dominant period for Mexico City. Based on this map, the authors propose some modifications to the current microzonation of Mexico City and evaluate a proposed model to account for site effects in this city.     

Hydrogeology and groundwater management in a coastal granitic area with steep slopes in Galicia (Spain)

Groundwater availability, management and protection are great challenges for the sustainability of groundwater resources in the scattered rural areas of the Atlantic regions of Europe where groundwater is the only option for water supply. This report presents a hydrogeological study of the coastal granitic area of Oia in northwestern Spain, which has unique geomorphological and hydrogeological features with steep slopes favoring the erosion of the weathered granite. The hydrogeological conceptual model of the study area includes: (1) the regolith layer, which is present only in the flat summit of the mountains; (2) the slope debris and the colluvial deposits, which are present in the intermediate and lowest parts of the hillside; (3) the marine terrace; and (4) the underlying fractured granite. Groundwater recharge from rainfall infiltration varies spatially due to variations in terrain slope, geology and land use. The mean annual recharge estimated with a hydrological water balance model ranges from 75 mm in the steepest zone to 135 mm in the lowest flat areas. Groundwater flows mostly through the regolith and the detrital formations, which have the largest hydraulic conductivities. Groundwater discharges in seepage areas, springs, along the main creeks and into the sea. The conceptual hydrogeological model has been implemented in a groundwater flow model, which later has been used to select the best pumping scenario. Model results show that the future water needs for domestic and tourist water supply can be safely provided with eight pumping wells with a maximum pumping rate of 700 m³/day.

     

Geochemical Characterization of Magnetite and Geological Setting of the Iron Oxide ± Iron Silicate ± Iron Carbonate Rich Pb–Zn Sulfides from the La Unión and Mazarrón Stratabound Deposits (SE Spain)

From a mineralogical point of view the La Unión ore field (SE Spain) can be regarded as an oddity as some of its hydrothermal, stratabound type deposits display an extremely unusual paragenesis comprising magnetite ± greenalite ± minnesotaite ± siderite and galena ± sphalerite (IOSC – LZS). Recent mineralogical studies have shown that this paragenesis is also present at the neighboring Mazarrón ore field. These ore fields share a similar geologic setting, involving metamorphic and sedimentary rocks (Paleozoic s.l. to Permian) hosting late Miocene high‐K calc‐alkaline volcanic and subvolcanic rocks. The latter have andesitic to dacitic composition, and triggered hydrothermal activity and ore deposition. This study discusses the detailed mineral chemistry of magnetite samples from Mazarrón and La Unión and provides some hints for the origin of the IOSC – LZS paragenesis. We performed electron microprobe (EPMA) analyses in magnetite samples from La Unión and Mazarrón to determine the contents of minor and trace elements (Zn, Ni, Mn, Cr, V, K, Ca, Ti, Al, Si, Mg). Given that some results fell below the detection limit for the EPMA instrumental conditions we used robust regression on order statistics (robust ROS), with the NADA package in R to deal with these data sets. The Ca + Al + Mn contents in magnetites from San Cristóbal and Emilia are equivalent to the mean contents of those of IOCG, Kiruna, BIF, Cu porphyry, skarn, VMS, hydrothermal and clastic Pb–Zn deposits, but they are low in Ti + V and Ni + Cr. The principal components analysis indicates that Zn, Ni, Cr, V, K, Ca, Ti, and Mg are roughly collinear, therefore correlated, being also independent from Fe. Besides, the function discriminant analysis of data shows that the magnetites from Emilia and San Cristóbal cluster in differentiated groups, thus probably reflecting some differences related to the distance to the magmatic source that triggered the hydrothermal system: proximal in the case of San Cristóbal and distal in Emilia.     

Use of discrete element modeling to study the stress and strain distribution in cyclic torsional shear tests

In this research, a torsional cyclic shear test was modeled using the 3D discrete element method (DEM). The results are compared against experimental data and micro-mechanical aspects of the soil during the loading are discussed. The aim of the work is to study the homogeneity of strains during this laboratory test and to compare the micro-mechanical behavior of the soil sample for different strain levels. The experimental investigation was performed using a synthetic soil material made of glass beads, which simplifies the modeling and calibration since normal interaction forces do not induce rotation of the particles. Both the model and experimental tests used the same grading distribution and particle size. We showed that the hysteresis cycles can be properly reproduced in terms of shape and magnitude. Thus, we obtained a robust estimation for the secant shear modulus and damping ratio at different strain levels. With this, it was possible to build stiffness degradation and damping increase curve to compare it with experimental data obtained from torsional shear tests. Based on this validation of the DEM model, we discuss the micro-mechanical behavior of the soil and its relation with the macroscopic parameters obtained. It is shown that shear strain distribution on the sample is not uniform and that large values of strains concentrate close to the top of the sample as top rotation increases, which differs from the standard assumption of a constant value across the height of the sample. Additionally, it is observed that at 0.8 times radius, the cumulative torque reaches approximately 90% of the total torque applied to sample.     

Asbestiform and non-asbestiform morphologies in a talc and vermiculite mine from the province of Córdoba (Argentina): a case study

In this work, a talc and vermiculite mine from the province of Córdoba (Argentina) was investigated with special emphasis on the occurrence of asbestiform and non-asbestiform phases. The meta-ultramafic rock was studied by a multimethodological approach, complementing field studies with petrographic-mineralogical, compositional and morphological analyses. Samples were examined by stereomicroscopy, polarizing light microscopy, SEM–EDS, XRD, DSC-TGA and FTIR. Complementary, compositional and textural analyses were performed with FE-SEM–EDS and EPMA. Talc-rich veins with a laminar and fibrous appearance were at first recognized. However, the fibrous morphology observed both in the field and by microscopy is due to an apparent habit because of the sample orientation. To avoid erroneous interpretations, studies by secondary electron images (SEM) are fundamental to carrying out this type of analysis. Tremolite was identified in different zones of the outcrop; however, only ~40% of the crystals located in the vermiculite zone have dimensions to be considered as asbestiform fibres in the range of respirable particles. In these types of complex deposits affected by superimposed metamorphic, igneous and deformational events, multimethodological approaches are necessary to develop models of occurrence of asbestiform morphologies that may be applicable to other with similar characteristics.