WSO and the winds of massive stars: the gate to the metal-poor Local Universe

The spectrographs on-board the World Space Observatory (WSO) will provide access to the 1020–1800 Å wavelength range with unprecedented sensitivity. Previous observatories operating in the 1150–2000 Å range (such as IUE and HST-STIS) have proved extremely useful to study the winds of OB type stars, which leave their most prominent imprints in the far ultraviolet range. The addition of the λ < 1200 Å wavelengths is critical as it contains important diagnostic lines for mass loss and shocks in the wind, as found by FUSE-based analyses.WSO will enable quantitative spectroscopic analyses of blue massive stars in the Local Group beyond the Magellanic Clouds. The results will lead to the characterization of their winds as a function of metallicity, and shed new light on current urging questions regarding radiation driven winds.     

Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.     

Using ichnofossils to characterize chert tools: A preliminary study from Southern Iberia

Characterizing raw material of stone tools used by Late Neolithic and Copper Age communities is important for interpreting access to available sources and establishing regional routes of distribution. Ichnological analysis may be used to help characterize lithic material and determine the source of artifacts. Here we report for the first time the existence of trace fossils in artifacts from the Late Neolithic and Copper Age of southern Spain. Ichnological analysis indicates a trace fossil assemblage consisting of relatively scarce small‐sized Chondrites and abundant Phycosiphon. A regional survey of natural outcrops and chert quarries indicates the presence of discrete trace fossils only in the samples from geological formations that are part of the Campo de Gibraltar Complex. Ichnological composition in these samples is similar to that discerned in the artifacts and suggests that this was the probable source of the chert used in tool manufacture. © 2010 Wiley Periodicals, Inc.     

Geochemical processes in a Mediterranean Lake: a high-resolution study of the last 4,000 years in Zoñar Lake,southern Spain

High-resolution geochemical analysis of a 6-m-long sediment core from Zoñar Lake, southern Spain, provides a detailed characterization of major changes in lake and watershed processes during the last 4,000 years. Geochemical variables were used as paleolimnological indicators and complement Zoñar Lakes’s paleoenvironmental reconstruction based on sedimentological and biological proxies, which define periods of increasing allochthonous input to the lake and periods of dominant autochthonous sedimentation. Chemical ratios identify periods of endogenic carbonate formation (higher Ca/Al, Sr/Al and Ba/Al ratios), evaporite precipitation (higher S/Al, Sr/Al ratios), and anoxic conditions (higher Mo/Al, U/Th ratios and Eu anomaly). Higher productivity is marked by elevated organic carbon content and carbonate precipitation (Mg/Ca). Hydrological reconstruction for Zoñar Lake was based on sedimentological, mineralogical and biological proxies, and shows that lower lake levels are characterized by Sr-rich sediments (a brackish lake with aragonite) and S-rich sediments (a saline lake with gypsum), while higher lake levels are characterized by sediments enriched in elements associated with alumino-silicates (Al, K, Ti, Fe, trace and rare earth elements), reflecting fresher conditions. Geochemical indicators also mark periods of higher detrital input to the lake related to human activity in the watershed: (1) during the Iberian Roman Humid Period (650 BC–AD 300), around the onset of the Little Ice Age (AD 1400), during the relatively drier Post-Roman and Middle Ages (AD 800–1400), and over the last 50 years, due to mechanized farming practices. Heavy metal enrichment in the sediments (Cu and Ni) suggests intensification of human activities during the Iberian Roman Period, and the use of fertilizers during the last 50 years.     

Palaeoceanographic changes in the North Atlantic during the Mid‐Pleistocene Transition (MIS 31–19) as inferred from planktonic foraminiferal and calcium carbonate records

Marine sediments from the Integrated Ocean Drilling Project (IODP) Site U1314 (56.36°N, 27.88°W), in the subpolar North Atlantic, were studied for their planktonic foraminifera, calcium carbonate content, and Neogloboqudrina pachyderma sinistral (sin.) δ¹³C records in order to reconstruct surface and intermediate conditions in this region during the Mid‐Pleistocene Transition (MPT). Variations in the palaeoceanography and regional dynamics of the Arctic Front were estimated by comparing CaCO₃ content, planktonic foraminiferal species abundances, carbon isotopes and ice‐rafted debris (IRD) data from Site U1314 with published data from other North Atlantic sites. Site U1314 exhibited high abundances of the polar planktonic foraminifera N. pachyderma sin. and low CaCO₃ content until Marine Isotope Stage (MIS) 26, indicating a relatively southeastward position of the Arctic Front (AF) and penetration of colder and low‐salinity surface arctic water‐masses. Changing conditions after MIS 25, with oscillations in the position of the AF, caused an increase in the northward export of the warmer North Atlantic Current (NAC), indicated by greater abundances of non‐polar planktonic foraminifera and higher CaCO₃. The N. pachyderma sin. δ¹³C data indicate good ventilation of the upper part of the intermediate water layer in the eastern North Atlantic during both glacial and interglacial stages, except during Terminations 24/23, 22/21 and 20/1. In addition, for N. pachyderma (sin.) we distinguished two morphotypes: non‐encrusted and heavily encrusted test. Results indicate that increases in the encrusted morphotype and lower planktonic foraminiferal diversity are related to the intensification of glacial conditions (lower sea‐surface temperatures, sea‐ice formation) during MIS 22 and 20.     

Modelling mechanical behaviour of limestone under reservoir conditions

High porosity and low permeability limestone has presented pore collapse. As fluid is withdrawn from these reservoirs, the effective stresses acting on the rock increase. If the strength of the rock is overcome, pore collapse may occur, leading to irreversible compaction of porous media with permeability and porosity reduction. It impacts on fluid withdrawal. Most of reservoirs have been discovered in weak formations, which are susceptible to this phenomenon. This work presents a study on the mechanical behaviour of a porous limestone from a reservoir located in Campos Basin, offshore Brazil. An experimental program was undergone in order to define its elastic plastic behaviour. The tests reproduced the loading path conditions expected in a reservoir under production. Parameters of the cap model were fitted to these tests and numerical simulations were run. The numerical simulations presented a good agreement with the experimental tests. Copyright © 2006 John Wiley & Sons, Ltd.     

Surface changes on crystalline stones due to salt crystallisation

This study assesses the changes on the surface of crystalline stones due to salt crystallisation. Efflorescence was forced to grow on the surface of granite and marbles through 60 cycles of salt crystallisation with sodium sulphate. Changes on surface roughness, gloss and colour were measured every 15 cycles and the specimens were examined with naked eye and SEM. Sodium sulphate produces damage which depends on mineral composition. Results show that granites experience a mechanical decay with an increase in roughness. Peaks of mica can be observed on the surface and cracks widen and grow deeper. Colour and gloss do not show any significant change, although gloss decreases with an increase in surface roughness. In marbles, the decay is mainly chemical. Surface roughness increases due to dissolution of the calcite. White marbles exhibit yellowing. Gloss decreases during the first cycles—as grain boundaries become more visible—but tends to regain almost its initial value as the number of cycles increases. In this case, gloss does not show any relation with surface roughness.