Alteration of platinum-group minerals and dispersion of platinum-group elements during progressive weathering of the Aguablanca Ni–Cu deposit, SW Spain

The distribution, mineralogy and mobility of the platinum-group elements (PGE) in the surface environment are poorly understood. This study of the lower, less altered and upper, more altered gossan, overlying the Aguablanca Ni–Cu-(PGE) magmatic deposit (Spain), has shown that the platinum-group minerals (PGM) are progressively oxidised and dispersed into iron oxides that form the gossan. A combination of the characterization of PGE in host PGM, using a scanning electron microscope, and measurement of PGE at lower concentrations in host iron oxides, using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), has for the first time allowed the total distribution of the PGE within a gossan to be documented. This study has revealed a complete in situ alteration and dispersion sequence of the PGM including (1) breakdown of both the more stable Pt-arsenides, Pt/Pd-tellurides and the less stable bismuthotellurides, (2) formation of partially oxidised PGM, (3) development of a wide range of oxidised Pt- and Pd-bearing phases, (4) subsequent formation of Fe–PGE-oxides and PGE-hydroxides, (5) incorporation of PGE into ferruginous supergene products and lastly (6) concentration of PGE at the edges of veins and iron oxides. Dispersion of Pd is greater than for the other PGE with Pd being widely distributed throughout the iron oxides. This oxidising environment produced PGE-oxides rather than PGE-alloys, also commonly found in the surface environment, especially in placers. These results provide critical evidence for the stages of mineralogical change from PGE host mineralogy in magmatic ores to surface weathering producing PGE-oxides.     

Assessment of CHADFDM satellite-based input dataset for the groundwater recharge estimation in arid and data scarce regions

Aquifer natural recharge estimations are a prerequisite for understanding hydrologic systems and sustainable water resources management. As meteorological data series collection is difficult in arid and semiarid areas, satellite products have recently become an alternative for water resources studies. A daily groundwater recharge estimation in the NW part of the Lake Chad Basin, using a soil–plant-atmosphere model (VisualBALAN), from ground- and satellite-based meteorological input dataset for non-irrigated and irrigated land and for the 2005–2014 period is presented. Average annual values were 284 mm and 30°C for precipitation and temperature in ground-based gauge stations. For the satellite-model-based Lake Chad Basin Flood and Drought Monitor System platform (CHADFDM), average annual precipitation and temperature were 417 mm and 29°C, respectively. Uncertainties derived from satellite data measurement could account for the rainfall difference. The estimated mean annual aquifer recharge was always higher from satellite- than ground-based data, with differences up to 46% for dryland and 23% in irrigated areas. Recharge response to rainfall events was very variable and results were very sensitive to: wilting point, field capacity and curve number for runoff estimation. Obtained results provide plausible recharge values beyond the uncertainty related to data input and modelling approach. This work prevents on the important deviations in recharge estimation from weighted-ensemble satellite-based data, informing in decision making to both stakeholders and policy makers.     

Holocene environmental change in southern Spain deduced from the isotopic record of a high-elevation wetland in Sierra Nevada

Small lakes and wetlands from high elevation within the Sierra Nevada Range (southern Spain) preserve a complete post-glacial Holocene record. Isotopic, TOC and C/N analyses, carried out on a sediment core, show various stages in the evolution of the Borreguiles de la Virgen, which today constitute a small bog at about 2,950?m above sea level. Glacial erosion generated a cirque depression, which became a small lake during the first phase of infilling (from?8,200 to 5,100?cal?yr BP), as suggested by sedimentary evidence, including an atomic C/N ratio generally below 20, low TOC values and the highest ??¹³C and ??¹⁵N values of the record. These results imply significant algal productivity, which is confirmed by the microscopic algal remains. Drier conditions became established progressively in this area from?5,100 to 3,700?cal?yr BP. Subsequently, the lake evolved into a bog as shown by geochemical evidence (C/N ratios above 20, high TOC content and low ??¹³C values). Unstable conditions prevailed from?3,600 to 700?cal?yr BP; an extremely low sedimentation rate and scarcity of data from this period do not allow us to make a coherent interpretation. Fluctuating conditions were recorded during the last?~700?cal?yr BP, with wetter conditions prevailing during the first part of the interval (with C/N rate below 20) up to 350?years ago. In general, a gradual trend toward more arid conditions occurred since?~6,900?cal?yr BP, with a further increase in aridity since?~5,100?cal?yr BP. This evidence is consistent with other contemporaneous peri-Mediterranean records.     

First record of mosquitofish,Gambusia holbrooki,in Tasmania,Australia: Stock structure and reproductive biology

The first population of mosquitofish, Gambusia holbrooki, was discovered in a wetland area of the upper Tamar Estuary, northern Tasmania, Australia, in November 2000. We report aspects of the structure and reproductive biology of this population, based on 1567 fish collected between August 2001 and January 2002. Females dominated most catches. Maximum lengths were 48.9 and 23.6 mm standard length (SL) for females and males, respectively. Growth of the over‐wintered cohort was evident from October, when temperatures reached >19°C; growth rates in the young‐of‐season cohort from length frequency plots were 0.38 mm/ day for females and 0.19 mm/day for males. Estimated SL at 50% maturity for females (25.0 mm) and males (17.4 mm) were attained within 7 weeks of birth. Developing embryos were present from mid October and offspring from mid November; average number of stage III embryos was 55.5 (3–144). Given their rapid reproductive turnover (c. 34‐day gestation period) and resilience to broad environmental conditions, it is likely that this exotic pest will spread to other Tasmanian localities, as it has already been discovered in areas near the wetlands since the completion of this study.     

Nematode diversity in different microhabitats in a mangrove region

Mangroves are highly productive environments that play important ecological and socioeconomic roles; however, they have been impacted to different degrees in most countries worldwide. The knowledge of which organisms inhabit this environment and their ecological interactions is the first step towards its conservation. The natural variability of environmental factors in mangroves provides numerous niches available to different species. Meiofauna have patchy patterns of distribution that are related to the availability of resources. Hence, meiofauna are expected to present a high diversity of different taxa occupying the different microhabitats offered by mangroves. This work aims to test the hypothesis that the assemblage structure of Nematoda varies significantly among mangrove microhabitats and to contribute knowledge on the meiofauna diversity in mangrove environments. This work was carried out in a mangrove region at Pernambuco state, Northeastern Brazil. Qualitative samples were collected in nine microhabitats which show different characteristics mainly in terms of presence of vegetation or another organism and sediment grain size. Univariate and multivariate analysis were applied to Nematoda genera abundance data. Our results demonstrate the existence of significant differences among microhabitats regarding nematode assemblage structure corroborating the hypothesis. Different Nematoda assemblages are present in at least seven microhabitats. These assemblages are composed of nematode genera with different trophic and morphological features, demonstrating a strong relationship between morphological diversity and ecological plasticity. Furthermore, this study also demonstrates the importance of the conservation of this ecosystem and its attributes.     

Magnetic field modulated dust streams from Jupiter in interplanetary space

High speed dust streams emanating from near Jupiter were first discovered by the Ulysses spacecraft in 1992. Since then the phenomenon has been re-observed by Galileo in 1995, Cassini in 2000, and Ulysses in 2004. The dust grains are expected to be charged to a potential of , which is sufficient to allow the planet's magnetic field to accelerate them away from the planet, where they are subsequently influenced by the interplanetary magnetic field (IMF). A similar phenomenon was observed near Saturn by Cassini. Here, we report and analyze simultaneous dust, IMF and solar wind data for all dust streams from the two Ulysses Jupiter flybys. We find that compression regions (CRs) in the IMF – regions of enhanced magnetic field – precede most dust streams. Furthermore, the duration of a dust stream is roughly comparable with that of the precedent CR, and the occurrence of a dust stream and the occurrence of the previous CR are separated by a time interval that depends on the distance to Jupiter. The intensity of the dust streams and their precedent CRs are also correlated, but this correlation is only evident at distances from the planet no greater than 2 AU. Combining these observations, we argue that CRs strongly affect dust streams, probably by deflecting dust grain trajectories, so that they can reach the spacecraft and be detected by its dust sensor.     

On the Impact of Anthropogenic Heat Fluxes on the Urban Boundary Layer: A Two-Dimensional Numerical Study

The heat generated in buildings and the manner in which this heat is exchanged with the ambient environment can play an important role in urban climate. Recent studies have shown that anthropogenic heat from air-conditioning facilities can increase the exterior ambient temperature and should be taken into account for a more complete urban heat island (UHI) mitigation study. For this purpose, the first part of the present work is focused on the coupling of a new building energy model (BEM) and an urban canopy parameterisation (UCP). The new scheme is implemented in a finite volume mesoscale model (MM) and tested in a two-dimensional (2D) configuration of a city over flat terrain. A sensitivity study is performed with respect to different parameters in order to test the simulation system and enhance the understanding of the possible impacts of the BEM on the exterior microclimate.     

Plant community patterns in a gypsum area of NE Spain. II. Effects of ion washing on topographic distribution of vegetation

A model, based on the physico-chemical properties of gypsum, is postulated in order to interpret the regular distribution of plant communities associated with the topography and the main environmental stresses to which each vegetation type is subjected in a landscape unit.The leaf chemical composition of 28 representative plant species supports the main predictions of the model: species from low areas present large concentrations of Na, N and ash but low contents of Ca. It is demonstrated that the strong nutrient and salt downwashing in the hilly terrain is an important cause of the vegetation segregation observed on a large spatial scale.     

A new Building Energy Model coupled with an Urban Canopy Parameterization for urban climate simulations—part II. Validation with one dimension off-line simulations

Recent studies show that the fluxes exchanged between buildings and the atmosphere play an important role in the urban climate. These fluxes are taken into account in mesoscale models considering new and more complex Urban Canopy Parameterizations (UCP). A standard methodology to test an UCP is to use one-dimensional (1D) off-line simulations. In this contribution, an UCP with and without a Building Energy Model (BEM) is run 1D off-line and the results are compared against the experimental data obtained in the BUBBLE measuring campaign over Basel (Switzerland) in 2002. The advantage of BEM is that it computes the evolution of the indoor building temperature as a function of energy production and consumption in the building, the radiation coming through the windows, and the fluxes of heat exchanged through the walls and roofs as well as the impact of the air conditioning system. This evaluation exercise is particularly significant since, for the period simulated, indoor temperatures were recorded. Different statistical parameters have been calculated over the entire simulated episode in order to compare the two versions of the UCP against measurements. In conclusion, with this work, we want to study the effect of BEM on the different turbulent fluxes and exploit the new possibilities that the UCP–BEM offers us, like the impact of the air conditioning systems and the evaluation of their energy consumption.