Clinopyroxene of spinel-peridotite mantle xenoliths from Lake Nji (Cameroon Volcanic Line, W Africa): crystal chemistry and petrological implications

The crystal chemistry of six clinopyroxenes enclosed in protogranular spinel-peridotite mantle xenoliths from Lake Nji (Cameroon, W Africa) was studied by means of single-crystal X-ray diffraction and electron microprobe. These spinel-peridotite xenoliths are characterised by clinopyroxene contents distinctly higher than those reported by Lee et al. (1996) for spinel-peridotite xenoliths of the same region (19–11% and 15–8% respectively) and by high clinopyroxene/orthopyroxene ratios: 0.7–2.7 (present study) and about 0.4 (Lee et al. 1996). The clinopyroxene crystal chemistry indicates that the xenoliths show the compositional features of a mantle source contaminated by small-volume melts, responsible for the high clinopyroxene content. The protogranular texture of the Cameroon xenoliths (upper portion of lithospheric mantle) testifies that the spinel peridotite and the associated small-volume melts completely re-equilibrated at the spinel-peridotite facies. This is also supported by the petrological and geochemical data of Lee et al. (1996) on the Etinde–Biu Plateau spinel-peridotite xenoliths, which underwent Late Proterozoic–Early Paleozoic enrichment in incompatible trace elements. Received: 6 October 1999 / Accepted: 27 March 2000     

Large scale climate and rainfall seasonality in a Mediterranean Area: Insights from a non‐homogeneous Markov model applied to the Agro‐Pontino plain

In the context of climate change and variability, there is considerable interest in how large scale climate indicators influence regional precipitation occurrence and its seasonality. Seasonal and longer climate projections from coupled ocean–atmosphere models need to be downscaled to regional levels for hydrologic applications, and the identification of appropriate state variables from such models that can best inform this process is also of direct interest. Here, a Non‐Homogeneous Hidden Markov Model (NHMM) for downscaling daily rainfall is developed for the Agro‐Pontino Plain, a coastal reclamation region very vulnerable to changes of hydrological cycle. The NHMM, through a set of atmospheric predictors, provides the link between large scale meteorological features and local rainfall patterns. Atmospheric data from the NCEP/NCAR archive and 56‐years record (1951–2004) of daily rainfall measurements from 7 stations in Agro‐Pontino Plain are analyzed. A number of validation tests are carried out, in order to: 1) identify the best set of atmospheric predictors to model local rainfall; 2) evaluate the model performance to capture realistically relevant rainfall attributes as the inter‐annual and seasonal variability, as well as average and extreme rainfall patterns. Validation tests show that the best set of atmospheric predictors are the following: mean sea level pressure, temperature at 1000 hPa, meridional and zonal wind at 850 hPa and precipitable water, from 20°N to 80°N of latitude and from 80°W to 60°E of longitude. Furthermore, the validation tests show that the rainfall attributes are simulated realistically and accurately. The capability of the NHMM to be used as a forecasting tool to quantify changes of rainfall patterns forced by alteration of atmospheric circulation under climate change and variability scenarios is discussed.     

The effect of low‐permeability fault zones on groundwater flow in a compartmentalized system. Experimental evidence from a carbonate aquifer (Southern Italy)

The hydrogeological behaviour of fault zones in carbonate aquifers is often neglected in conceptual and numerical models. Furthermore, no information is available regarding the relationships between piezometric levels when significant compartmentalization occurs due to the occurrence of low‐flow fault zones. The aim of this study was to refine the conceptualization of subsurface flow in faulted carbonate aquifers and to analyse relationships between sub‐basins within a compartmentalized aquifer system in Southern Italy. The interactions between compartments that straddle low‐flow faults were investigated over four hydrologic years using a statistical approach to compare (i) the hydraulic heads within two wells located up‐ and down‐gradient of tectonic discontinuities as well as (ii) the rainfall and piezometric levels. The results of this study suggest that a set of barriers exists between the wells, and, therefore, the total head loss observed between the wells (approximately 80 m) should be distributed across several aquitards, with one aquitard exhibiting a relatively high permeability or low degree of integrity. Due to slight differences in permeability, transient conditions in aquitards can occur over relatively short periods, which is in agreement with the results of the statistical data analysis. Consequently, rather than being caused by pure aquitards, aquifer system compartmentalization likely results from slight differences in the permeability between lower‐permeability fault zones and adjacent higher‐permeability protoliths. Copyright © 2014 John Wiley & Sons, Ltd.     

Limestone Provenance in Roman Lime‐Volcanic Ash Mortars from the Villa dei Quintili,Rome

Roman mortars were collected from the Villa dei Quintili in Rome, an archaeological site consisting of numerous edifices from nine construction phases dating from the 2nd century A.D. to modern times. A multianalytical approach was used on 34 mortar samples to infer the evolution of production techniques over time and to identify the source area of calcareous raw materials used in the preparation of the lime. Optical microscopy, scanning electron microscopy coupled with an energy‐dispersive system, and laser ablation inductively coupled plasma mass spectrometry were used to study the samples. The major and trace element data were compared with the compositions of two types of limestone samples (Calcare Massiccio and Calcare Maiolica) collected from the Cornicolani Mountains. The results suggest that the technological practices and the calcareous raw materials used for lime production remained unchanged over the time period considered (2nd century A.D. to 3rd century A.D.). The compositions of lime‐related particles in the mortars match those of Calcare Maiolica, which suggests its use as raw material for lime production. On the whole, the results are in agreement with data from existing literature regarding both the use by Roman builders of specific raw materials for the mortars’ production and the relative supply area.     

A procedure to estimate the seismic hazard in an urban area: an application to Acireale (Eastern Sicily)

A “standard procedure” to characterize the seismic hazard of a given area was proposed. It is based on a multidisciplinary approach implying: (1) the knowledge of the seismic history of the area; (2) detailed geological surveys; (3)seismic noise measurements; (4) simulations of earthquake scenarios. The downtown of Acireale, a typical baroque town located on Eastern Sicily, was chosen as the “test area”. A catalog of the local seismogenic faults (able to generate earthquakes in historical times) has been compiled, as well as a seismic catalog for the effects of both local and regional earthquakes. The analysis of both catalogs allowed us to make the following conclusions: (1) the most important seismogenic faults affecting the Acireale municipality do not affect the downtown, while the related local earthquakes attenuate their energy (and intensity) in short (few km) distances; (2) the highest seismic intensity (degree X) experienced in Acireale downtown was caused by the 1693 regional earthquake; (3) over the last 140 years, the downtown has experienced the highest intensity value of VII only once, while six times the intensity was VI. On the whole, this implies a moderate seismic hazard. The estimation of the seismic hazard has been also approached by the experimental method of recording seismic noise. Measurements have been performed at seven different sites, where drills gave detailed information on the shallow subsurface geology to obtain HV (horizontal/vertical) spectral ratios. On the whole, the highest site amplification factor was moderate (about 7). A further investigation based on synthetic seismograms (and spectra) produced by simulating two given earthquake scenarios was also performed. The two scenarios are, respectively, representative of the largest expected earthquake in the area (the 1693 shock) and of a moderate (magnitude ca. 5.5) local earthquake (as the 1818 one). Moderate to strong locally expected accelerations were evidenced.     

Morphology, distribution and origin of recent submarine landslides of the Ligurian Margin (North-western Mediterranean): some insights into geohazard assessment

Based on new multibeam bathymetric data, seismic-reflection profiles and side-scan sonar images, a great number of submarine failures of various types and sizes was identified along the northern margin of the Ligurian Basin and characterized with 3 distinct end-members concerning their location on the margin, sedimentary processes and possible triggering mechanisms. They include superficial landslides mainly located in the vicinity of the main mountain-supplied rivers and on the inner walls of canyons (typically smaller that 10⁸ m³ in volume: Type 1), deep scars 100?C500 m high along the base of the continental slope (Type 2), and large-scale scars and Mass Transport Deposits (MTDs) affecting the upper part of the slope (Type 3 failures). The MTDs are located in different environmental contexts of the margin, including the deep Var Sedimentary Ridge (VSR) and the upper part of the continental slope in the Gulf of Genova (Finale Slide and Portofino Slide), with volumes of missing sediment reaching up to 1.5 × 10⁹ m³. High sedimentation rates related to hyperpycnal flows, faults and earthquake activity, together with sea-level fluctuations are the main factors invoked to explain the distribution and sizes of these different failure types.     

Contourites offshore Pantelleria Island (Sicily Channel, Mediterranean Sea): depositional, erosional and biogenic elements

High-resolution seismic reflection profiles and multibeam bathymetry data collected in 2006 and 2008 around Pantelleria Island show the widespread occurrence of contourite drifts and erosional elements ~30?km from the narrowest part (~145?km) of the Sicily Channel, where water masses from the Eastern Mediterranean flow towards the Western Mediterranean. The contourite drifts are rather small (up to 10?km long and 3.3?km wide), at water depths of ~250?C750?m. Most are elongated separated drifts with quite well-developed moats and crests, aligned roughly parallel to the regional bathymetric contours. Erosional elements include abraded surfaces, moats, scours and sub-circular depressions. In addition, a wide sector of the seafloor adjacent to a seamount located SW of Pantelleria Island is characterized by numerous biogenic build-ups colonized by deep-water corals (Madrepora oculata). The spatial distribution of sediment drifts, erosional features and biogenic build-ups suggests an origin from a north-westward-flowing bottom current, in this case the outflow of Levantine Intermediate Water and transitional Eastern Mediterranean Deep Water via the Sicily Channel. These findings for the Pantelleria offshore sector demonstrate that contourite processes are able to concentrate a high variety of closely spaced depositional and erosional features even in small areas (in this case, about 2,000?km²). This Pantelleria focusing can plausibly be related to a particular configuration of the prevailing bottom-current regime in complex interaction with an uneven bathymetry shaped mainly by tectonic and volcanic activity. The distribution of bottom currents seems to be strongly influenced by morphological features ranging from major seabed obstacles, such as the Pantelleria volcanic complex and the so-called southwest seamount, to smaller-scale escarpments and banks. This is consistent with previous findings for Mediterranean and other settings characterized by neotectonics and large topographic features.     

Warming permafrost in European mountains

Here we present the first systematic measurements of European mountain permafrost temperatures from a latitudinal transect of six boreholes extending from the Alps, through Scandinavia to Svalbard. Boreholes were drilled in bedrock to depths of at least 100 m between May 1998 and September 2000. Geothermal profiles provide evidence for regional-scale secular warming, since all are nonlinear, with near-surface warm-side temperature deviations from the deeper thermal gradient. Topographic effects lead to variability between Alpine sites. First approximation estimates, based on curvature within the borehole thermal profiles, indicate a maximum ground surface warming of +1 °C in Svalbard, considered to relate to thermal changes in the last 100 years. In addition, a 15-year time series of thermal data from the 58-m-deep Murtèl–Corvatsch permafrost borehole in Switzerland, drilled in creeping frozen ice-rich rock debris, shows an overall warming trend, but with high-amplitude interannual fluctuations that reflect early winter snow cover more strongly than air temperatures. Thus interpretation of the deeper borehole thermal histories must clearly take account of the potential effects of changing snow cover in addition to atmospheric temperatures.