Impact of ancient metal smelting on arsenic pollution in the Pecora River Valley,Southern Tuscany,Italy

A significant As anomaly has been reported in the literature for stream sediments and unlithified Quaternary deposits of the Pecora River valley in Southern Tuscany, extending from the “Colline Metallifere” pyrite-base metals district to the Tyrrhenian Sea. The As anomaly spreads over several square kilometers around a core that exceeds 500 ppm. Several source contributions (from natural to anthropogenic) have been invoked to explain the observed As distribution in the Pecora Valley, including the metal-working industry which was active in this area, particularly in Etrusco-Roman times and in the Middle Ages. In order to evaluate the contribution of ancient mining and metallurgical activities in the Pecora Valley to elevated As concentrations in the environment, a detailed mineralogical and geochemical survey of metallurgical slags and smelted ore minerals was undertaken from six different sites through the Pecora Valley: Poggio Butelli (Etrusco-Roman iron slags); Sata Creek, Arialla, Marsiliana, Forra and Cascata sites (all Medieval base metals slags). The As content of Etrusco-Roman slags is relatively low (few tens of ppm), whereas Medieval slags show variable, but higher amounts of base metals (±Ag) (ranging from tens to tens of thousands ppm) and As (up to 267 ppm, with average contents of about 40 ppm). Arsenic is mostly partitioned in sulfides disseminated through the glassy groundmass rather than in solid solution with the glassy matrix. Remnants of the ore used for base metal and Ag smelting during the Middle Ages had the highest As contents (up to about 1000 ppm).     

Morphological effects of local scouring in step–pool streams

Step–pool morphology characterizes many high‐gradient streams in a variety of natural settings, but formative processes and evolutionary dynamics are still poorly understood. In this paper, natural step–pool geometry is compared with steep alluvial channels where grade‐control structures such as check‐dams and bed sills make the stream profile resemble a natural stepped stream. Along these channels, local scouring due to falling jets forms plunge pools under each structure, analogous to natural steps determining the formation of pools. In order to test the hypothesis that natural pools are analogous to pools formed below grade‐control works with respect to their dimensions, shape and formative dynamics, 37 natural pools and 73 artificial pools were surveyed in 10 mountain streams of the eastern Italian Alps. Pools below grade‐control works featured a transitional zone between the scour hole and the downstream sloping bed, marked by a depositional berm. When geometric parameters such as maximum pool depth, length and step–berm distances are normalized to the jet virtual energy, no statistically significant differences were detected between natural and artificial systems. These results lend support to an upstream‐forced cascade model for step–pool formation, where the energy of falling jets controls the geometry of the pools, and is therefore regarded as the most important scaling‐independent variable. Copyright © 2005 John Wiley & Sons, Ltd.     

Site effects in the Aterno River Valley (L’Aquila,Italy): comparison between empirical and 2D numerical modelling starting from April 6th 2009 Mw 6.3 earthquake

In this paper, we focused our attention on a cross-section of the Aterno River Valley where a good quality geological and geophysical dataset allowed to reconstruct accurately the geometry and the Vs profiles along all the plane of the section. Its trace is deliberately aligned close to the strong motion stations that recorded the Mw 6.3 (April 6th 2009) L’Aquila earthquake. We analysed strong and weak motion data available at these latter stations as well as at one of the temporary stations installed during the Microzonation activities and located on outcropping bedrock, in proximity of the cross-section. We used the H/V technique to select a reliable reference site and once we found it, we applied the SSR technique to compute amplification functions in correspondence of two strong motion stations. In turn, for both sites we performed a site response numerical modelling with two different 2D codes and we compared simulated versus experimental transfer functions. We found that the cross-section is well constrained based on the very reasonable agreement between results of numerical modelling and earthquake data analysis. We pointed out also a strong amplification of the deposit at the centre of the valley due to the constructive interference of S and surface waves, not predictable by means of 1D numerical modelling. We also compared the H/V as well as the SSR obtained from strong motion data with the ones computed from weak motion finding evidences of non-linearity in soil behaviour.     

A flume experiment on wood storage and remobilization in braided river systems

This work investigates wood dynamics in braided streams through physical modelling in a mobile bed laboratory flume, with the specific objective to characterize wood storage and turnover as a function of wood input rate and of wood element type. Three parallel channels (1.7 m wide, 10 m long) filled with uniform sand were used to reproduce braided networks with constant water discharge and sediment feeding. Wood dowels with and without simplified root wads were regularly added at the upstream end of each flume at different input rates, with a 1:2:3 ratio between the three flumes. Temporal evolution of wood deposition patterns and remobilization rates were monitored by a series of vertical images that permitted the recognition of individual logs. Results show that wood tends to disperse in generally small accumulations (< 5 logs), with higher spatial density on top of sediment bars, and is frequently remobilized due to the intense morphological changes. The amount of wood stored in the channel depends on log input rate through a non‐linear relationship, and input rates exceeding approximately 100 logs/hour determine a sharp change in wood dynamics, with higher storage volume and augmented formation of large jams (> 10 elements) that are less prone to remobilization. Presence of root wads seems to play a minor role in wood deposition, but it reduces the average travel distance of logs. Turnover rates of logs were similar in the three flumes, independently of wood input rate and largely resembling the turnover rate of exposed bars. For the simulated conditions, significant effects of wood on bed morphology were not observed, suggesting that interactions with fine sediments and living vegetation are crucial to form large, stable wood jams able to bring about relevant morphological changes. Copyright © 2014 John Wiley & Sons, Ltd.     

A physically-based method for removing pits in digital elevation models

Spurious pits in digital elevation models (DEMs) are traditionally removed by filling depressions, often creating flat regions that lead to inaccurate estimation of landscape flow directions. In this study, a physical approach based on a simple landscape evolution model is proposed for DEM pit removal. This method, an alternative to traditional geometrical procedures, enforces more realistic slopes and flow directions on topography. The procedure is compared with the method most commonly used in the literature and distributed with commercial GIS software where, generally, elevations of a depression are increased up to the lowest value among neighbouring cells. Several tests are performed and parameters sensitivity is carried out in order to demonstrate the performance of the proposed model as compared to traditional methods.     

A coquinoid tsunamite from the Pliocene of Salento (SE Italy)

A Pliocene composite shell concentration from a shallow-marine carbonate succession located in the small, slowly subsiding Novoli graben (Salento peninsula, Puglia, S-Italy) is interpreted as a tsunamite. This interpretation is based on taphonomic, palaeoecological and sedimentologic features. The deposit appears to drape the previous substrate, with thinning on the topographic highs and thickening in the lows, and consists of up to six sub-layers showing repeated grading (normal and reverse), suggesting that deposition occurred during up to six surges. The shell assemblage results from a chaotic mixing of taxa spanning a large spectrum of environments and taphonomic features. Although a fraction of broken shells is present, most shells are integral, suggesting a transport mechanism preventing strong impacts. On the other hand, the high comminution of skeletal remains occurring in the matrix of the deposit is thought to reflect the composition of sea-floor sediment before the inferred high-energy event.The predominance of displaced, but still articulated valves indicates that bivalves were mostly transported while still alive, after having been lifted from the sea bed. Exhumation, displacement, and large-scale transport of large-sized, deep-infaunal organisms (such as Panopea) implies that across relatively large areas the upper few decimetres of the middle–inner shelf floor were eroded by highly turbulent flows of exceptional intensity. A transport as turbulent suspension, very rapid deposition and immediate and permanent burial are strongly suggested by the general integrity of the shells indicating limited effects of physical damage and lack of biological alteration. The variable faunal characteristics of the unit lying below the inferred tsunamite suggest that deposition of the latter took place in settings ranging from a somewhat restricted, relatively low-energy bay, to a more open inner-shelf environment.     

High-temperature rapid pyrometamorphism induced by a charcoal pit burning: The case of Ricetto,central Italy

Bulk chemistry and mineralogy of the peculiar rock of Ricetto (Carseolani Mts., Central Apennines, Italy) was studied to resolve its controversial origin: igneous dyke or anthropic product. This hybrid rock consists of a colorless, felsic component made up of glass plus quartz, and a brown, femic component made up of fans and spherulites of diopside, calcic plagioclase, wollastonite, and melilite. Textural relationships indicate very rapid cooling and immiscibility phenomena. The bulk chemistry of the rock is the same as that of the surrounding siliciclastic sandstone. The ¹⁴C analysis of a coal fragment from bottom of the body yields the conventional age of 227(±50) years. The Ricetto occurrence is an example of pyrometamorphism of a siliceous limestone induced by a charcoal pit burning. The small size of the heat source at Ricetto caused an intense but short-lived melting of the country rock. Prograde metamorphism caused a temperature increase up to 1,000–1,100 °C when melilite crystallization conditions were reached at appreciable P(CO₂) and high f(O₂). Melting occurred in a close system represented by the simplified equation: 3Cal+16.5Qtz+Ms+BtMel+Melt+2H₂O+3CO₂+0.5O₂. Diopside+calcic plagioclase+wollastonite formed by melilite breakdown during rapid cooling, through the reaction: 6Mel+6Qtz+0.5O₂3Di+2An+7Wo. Liquid immiscibility caused the separation between the felsic melt component and the femic melilite-bearing component. Immiscibility was characterized by different fractionation of alumina and alkalies between these two phases. Differences in bulk, glass, and mineral chemistry between the Ricetto and other melilite-bearing pyrometamorphic rocks can be attributed mainly to different protoliths.An erratum to this article can be found at