Weathering characterization for landslides modeling in granitoid rock masses of the Capo Vaticano promontory (Calabria,Italy)

This work focuses on developing multidisciplinary researches concerning weathering profiles related to landscape evolution of the Capo Vaticano promontory on the Calabria Tyrrhenian side (southern Italy). In this area, the tectonic uplift, occurred at least since Pleistocene, together with the Mediterranean climatic conditions, is the main cause of deep weathering and denudation processes. The latter occurred on the outcropping rocks of the crystalline-metamorphic basement, made up of weathered granitoids, in turn belonging to the Monte Poro granitoid complex (intermediate to felsic plutonic rocks covered by Cenozoic sedimentary successions). Field observations coupled to borehole explorations, geophysical surveys, and minero-petrographical analyses allowed the characterization of the granitoid outcrops typical of the studied area in terms of kind and degree of slope instability. This characterization was based on suitable correlations verified between several factors as weathering degree, elastic properties of rocks, and discontinuity features. Weathering profiles are mainly composed by rock masses varying from completely weathered rock with corestones of highly weathered rock (classes IV–V) to slightly weathered rocks (class II). The weathered rocks are involved in several landslide typologies such as debris flow (frequency 48.5%), translational slide (frequency 33.3%), and minor rock fall and rotational slide (frequency 9%). The achieved data allowed the establishment of a general correlation between weathering degree and type of slope instability. Debris flow-type instabilities are predominant on the steeper slopes, involving very poor rock masses ascribed to the shallowest portions of the weathering class IV. Translational slides are less widespread than the previous ones and often involve a mixture of soil and highly weathered rocks. Rotational slides are more frequently close to the top of the slopes, where the thicknesses of more weathered rocks increase, and involve mainly rock masses belonging to the weathering classes IV and V. Rock falls mostly occur on the vertical escarpments of the road cuts and are controlled by the characteristics of the main discontinuities. The assessment of rock mass rating and slope mass rating, based on the application of the discontinuity data, allowed respectively an evaluation of the quality of rock masses and of the susceptibility of rock slopes to failure. The comparison between the last one and the real stability conditions along the cut slopes shows a good correspondence. Finally, the geological strength index system was also applied for the estimation of rock mass properties. The achieved results give a worthy support for a better understanding of the relationship between the distribution of landslides and the geological features related to different weathering degrees. Therefore, they can provide a reliable tool to evaluate the potential stability conditions of the rock slopes in the studied area and a general reference framework for the study of weathering processes in other regions with similar geological features.     

Nouvelles données sur le Messinien de Méditerranée occidentale : les gisements à Aphanius crassicaudus (Agassiz poissons téléostéens,cyprinodontiformes) des Marches (Italie)

Résumén

La découverte, dans le Nord des Marches (Italie), de nouveaux gisements de Poissons Cyprinodontidae appartenant à l’espèce Aphanius crassicaudus (AGASSIZ), conduit à réexaminer, à la lumière des données lithostratigraphiques, la signification géodynamique des ichthyofaunes messiniennes de ce secteur de l’Apennin. Après avoir précisé la position stratigraphique et la répartition paléogéographique des gisements étudiés, les auteurs montrent que le développement des faunes à Aphanius crassicaudus (AGASSIZ) dans les eaux saumâtres du domaine continental n’implique pas la disparition corrélative du milieu marin. En effet, certains genres marins sont parfois présents à côté de cette espèce, comme c’est le cas dans le gisement de Pésaro. Les auteurs contestent en outre l’interprétation selon laquelle le fait qu’aucune ichthyofaune marine ne soit connue dans le Messinien supérieur d’Italie puisse suffire à conclure que la Méditerranée était asséchée pendant le dépôt de la « Formation à colombacci »     

Macroseismic effects highlight site response in Rome and its geological signature

A detailed analysis of the earthquake effects on the urban area of Rome has been conducted for the L??Aquila sequence, which occurred in April 2009, by using an online macroseismic questionnaire. Intensity residuals calculated using the mainshock and four aftershocks are analyzed in light of a very accurate and original geological reconstruction of the subsoil of Rome based on a large amount of wells. The aim of this work is to highlight ground motion amplification areas and to find a correlation with the geological settings at a subregional scale, putting in evidence the extreme complexity of the phenomenon and the difficulty of making a simplified model. Correlations between amplification areas and both near-surface and deep geology were found. Moreover, the detailed scale of investigation has permitted us to find a correlation between seismic amplification in recent alluvial settings and subsiding zones, and between heard seismic sound and Tiber alluvial sediments.     

A Fe K-edge XAS study of amethyst

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.     

La nuova carta magnetica d'Italia (Isogone al 1° gennaio 1940) dell'Istituto Geografico Militare

Riassunto L'Autore, accennato alla carta del Palazzo del 1892 e dimostrata la necessità di una più precisa carta rispondente alle accresciute esigenze civili e militari, tratta del nuovo rilievo magnetico d'Italia basato su ben 1529 stazioni eseguite dall'Istituto Geografico Militare dal 1932 al 1937 e quindi della nuova carta magnetica con le isogone al 1° gennaio 1940 testé pubblicata dallo stesso Istituto.

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Zusammenfassung Der Verf., nach Erwähnung der erdmagnetischen Karte von Palazzo des Jahres 1892 hervorhebt die Notwendigkeit einer genaueren den vermehrten zivilen und militärischen Ansprüchen entsprechender Aufnahme; eine solche neue erdmagnetische Aufnahme Italiens ist vom Istituto Geografico Militare in den Jahren 1932–1937 durchgeführt worden und zwar mit zusammen 1529 Stationen. Diese Arbeit wird beschrieben und erörtet besonders in Zusammenhang mit der hier vorgestellten neuen Isogonen-Kart, bezogen auf dem 1. Januar 1940.

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Résumé L'Auteur, après avoir mentionné la carte magnétique du Prof. Palazzo (1892) et démontré la nécessité d'une carte plus précise et plus correspondante à l'accroissement des exigences civiles et militaires, s'entretient sur le nouveau levé magnétique d'Italie, qui se base sur les observations de 1529 stations, esecutées par l'Istituto Geografico Militare entre 1932 et 1937; ensuite il illustre la nouvelle carte magnétique des isogones, au l.er Janiver 1940, qui vient d'être publiée par le même Institut et qui est jointe au présent mémoire.

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Quest'articolo è in parte un riassunto di quanto io stesso ebbi a scrivere in alcune memorie precedenti edite dall'Istituto Geografico Militare e dalla Società Italiana per il Progresso delle Scienze.     

Thermal decay of carbonate dimension stones: fabric,physical and mechanical changes

This paper deals with the effects of thermal stresses on selected carbonate rocks used as dimension stones. They are Mesozoic calcareous and dolomitic rocks cropping out in Apulia (southern Italy) that, for their physico-mechanical and aesthetic properties, have always been finding a large application both as ornamental stones and as simple construction materials; their use is attested not only in Italy, in works of archaeological, historical and artistic interest too. The cause–effect relationships of thermal degradation were studied by means of an artificial accelerated ageing test, in order to provide a perspective about the decay of carbonate stones due to diurnal and seasonal temperature fluctuations, as well as thermal shocks during events of fire development. The stone samples were subjected to thermal cycles in a muffle furnace, ranging from 100 to 700 °C; after each cycle, several non-destructive and semi-destructive tests were carried out: mass and volume measurements, mercury intrusion porosimetry, sclerometer tests, ultrasonic tests, thin-section observations and determination of chromatic alterations through image analysis and Munsell charts method. In this way, the qualitative and quantitative modifications induced in fabric, physical and mechanical properties were discussed. The results highlight the fundamental role of depositional and diagenetic fabric that, together with mineralogical composition, represents the most significant discriminating factor in the response of the stone to thermal stresses.     

Carbon dioxide degassing and thermal energy release in the Monte Amiata volcanic-geothermal area (Italy)

The quaternary volcanic complex of Mount Amiata is located in southern Tuscany (Italy) and represents the most recent manifestation of the Tuscan Magmatic Province. The region is characterised by a large thermal anomaly and by the presence of numerous CO₂-rich gas emissions and geothermal features, mainly located at the periphery of the volcanic complex. Two geothermal systems are located, at increasing depths, in the carbonate and metamorphic formations beneath the volcanic complex. The shallow volcanic aquifer is separated from the deep geothermal systems by a low permeability unit (Ligurian Unit). A measured CO₂ discharge through soils of 1.8 × 10⁹ mol a⁻¹ shows that large amounts of CO₂ move from the deep reservoir to the surface. A large range in δ¹³C_TDIC (−21.07 to +3.65) characterises the waters circulating in the aquifers of the region and the mass and isotopic balance of TDIC allows distinguishing a discharge of 0.3 × 10⁹ mol a⁻¹ of deeply sourced CO₂ in spring waters. The total natural CO₂ discharge (2.1 × 10⁹ mol a⁻¹) is slightly less than minimum CO₂ output estimated by an indirect method (2.8 × 10⁹ mol a⁻¹), but present-day release of 5.8 × 10⁹ mol a⁻¹ CO₂ from deep geothermal wells may have reduced natural CO₂ discharge. The heat transported by groundwater, computed considering the increase in temperature from the infiltration area to the discharge from springs, is of the same order of magnitude, or higher, than the regional conductive heat flow (>200 mW m⁻²) and reaches extremely high values (up to 2700 mW m⁻²) in the north-eastern part of the study area. Heat transfer occurs mainly by conductive heating in the volcanic aquifer and by uprising gas and vapor along fault zones and in those areas where low permeability cover is lacking. The comparison of CO₂ flux, heat flow and geological setting shows that near surface geology and hydrogeological setting play a central role in determining CO₂ degassing and heat transfer patterns.     

Structural control over equilibrium silicon and oxygen isotopic fractionation: A first-principles density-functional theory study

Isotopic fractionation factors for oxygen and silicon in selected silicates (quartz, enstatite, forsterite, lizardite, kaolinite) are calculated using first-principles methods based on density-functional theory. Good agreement between theory and experiment is found in the case of oxygen. In the case of silicon, agreement and differences with existing estimates of equilibrium fractionation factors are discussed. The relationship between silicon and oxygen fractionation factors, silicate polymerization degree and chemical composition is studied and compared with previous semi-empirical models.     

A low plain between arcadia and agronomy: Ippolito Nievo and the Friulan landscape

An analysis of the historical and cultural context of a large number of literary works illuminates the concept of landscape, a recurrent theme in contemporary humanistic geography. In this context, the works of Ippolito Nievo present an opportunity to look closer at the socio-economic circumstances of his time while also offering suggestive interpretative elements about the attitudes held concerning the wetlands of the lower Friulan plain.