Biogeochemical processes involving dissolved CO2 and CH4 at Albano, Averno, and Monticchio meromictic volcanic lakes (Central–Southern Italy)

This paper focuses on the chemical and isotopic features of dissolved gases (CH₄ and CO₂) from four meromictic lakes hosted in volcanic systems of Central–Southern Italy: Lake Albano (Alban Hills), Lake Averno (Phlegrean Fields), and Monticchio Grande and Piccolo lakes (Mt. Vulture). Deep waters in these lakes are characterized by the presence of a significant reservoir of extra-atmospheric dissolved gases mainly consisting of CH₄ and CO₂. The δ¹³C-CH₄ and δD-CH₄ values of dissolved gas samples from the maximum depths of the investigated lakes (from ?66.8 to ?55.6?‰ V-PDB and from ?279 to ?195?‰ V-SMOW, respectively) suggest that CH₄ is mainly produced by microbial activity. The δ¹³C-CO₂ values of Lake Grande, Lake Piccolo, and Lake Albano (ranging from ?5.8 to ?0.4?‰ V-PDB) indicate a significant CO₂ contribution from sublacustrine vents originating from (1) mantle degassing and (2) thermometamorphic reactions involving limestone, i.e., the same CO₂ source feeding the regional thermal and cold CO₂-rich fluid emissions. In contrast, the relatively low δ¹³C-CO₂ values (from ?13.4 to ?8.2?‰ V-PDB) of Lake Averno indicate a prevalent organic CO₂. Chemical and isotopic compositions of dissolved CO₂ and CH₄ at different depths are mainly depending on (1) CO₂ inputs from external sources (hydrothermal and/or anthropogenic); (2) CO₂–CH₄ isotopic exchange; and (3) methanogenic and methanotrophic activity. In the epilimnion, vertical water mixing, free oxygen availability, and photosynthesis cause the dramatic decrease of both CO₂ and CH₄ concentrations. In the hypolimnion, where the δ¹³C-CO₂ values progressively increase with depth and the δ¹³C-CH₄ values show an opposite trend, biogenic CO₂ production from CH₄ using different electron donor species, such as sulfate, tend to counteract the methanogenesis process whose efficiency achieves its climax at the water–bottom sediment interface. Theoretical values, calculated on the basis of δ¹³C-CO₂ values, and measured δ¹³C_TDIC values are not consistent, indicating that CO₂ and the main carbon-bearing ion species (HCO₃ ^?) are not in isotopic equilibrium, likely due to the fast kinetics of biochemical processes involving both CO₂ and CH₄. This study demonstrates that the vertical patterns of the CO₂/CH₄ ratio and of δ¹³C-CO₂ and δ¹³C-CH₄ are to be regarded as promising tools to detect perturbations, related to different causes, such as changes in the CO₂ input from sublacustrine springs, that may affect aerobic and anaerobic layers of meromictic volcanic lakes.     

Dielectric constant estimation of the uppermost Basal Unit layer in the martian Boreales Scopuli region

An electromagnetic inversion model has been applied to echoes from the subsurface sounding Shallow Radar (SHARAD) to retrieve the dielectric properties of the uppermost Basal Unit (BU) beneath the North Polar Layered Deposits of Mars. SHARAD data have been carefully selected to satisfy the assumption of the inversion model which requires a stratigraphy consisting of mostly plane parallel layers. The resulting values of the dielectric constant have been interpreted in terms of a variable percentage of dust in an ice–dust mixture through the use of a mixing model for dielectric properties. The resulting dust content exceeds 65%, reaching perhaps 95%, depending on the permittivity values assumed for the dust. Such a concentration is higher than that obtained by Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003). This discrepancy could be justified considering that our observations refer to the uppermost BU layer, whereas Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003) probed the BU full thickness. Moreover, if the BU is considered spatially inhomogeneous, with very different dust content and thickness (Tanaka, K.L., Skinner, J.A., Fortezzo, C.M., Herkenhoff, K.E., Rodriguez, J.A.P., Bourke, M.C., Kolb, E.J., Okubo, C.H. [2008]. Icarus, 196, 318–358), the discrepancy could be furtherly reconciled.     

The Ricker Hills Tillite provides evidence of Oligocene warm-based glaciation in Victoria Land, Antarctica

The relationship between the Ricker Hills Tillite (RHT), which represents the northernmost outcrop of lithified continental glacial deposits in Victoria Land, is discussed with respect to the glacial landscape assemblage of the Ricker Hills, a nunatak at the internal border of the Transantarctic Mountains. A warm-based ice sheet deposited the tillite and induced syn- to post-depositional glacial deformation under wet conditions both of the tillite and of the bedrock. The thickness of the ice sheet on the nunatak is estimated to have been 600 m, at most. The area had been deeply eroded before deposition of the RHT as documented by the low elevation of tillite outcrops located in overdeepened depressions of the nunatak. Micropaleontological analysis evidences only the presence of Permian to Jurassic palynomorphs. X-ray diffraction and SEM–EDS analyses of clay minerals in the RHT indicate continental chemical weathering under wet conditions after the RHT deposition. As documented by clay mineral assemblage variation in CRP drillholes, the progressive cooling of the Antarctic continent allowed chemical weathering in “warm” conditions until the Late Oligocene period in southern Victoria Land, leading to a chronological constrain for RHT deposition. Conservatively estimating the sea level to have been between the tillite outcrops and the erosional trimline limiting horns in the Ricker Hills, at the time of RHT deposition, we suggest that the maximum uplift of the area would not have exceeded 900–1500 m since at least Late Oligocene.     

Nuovo contributo alla bioclimatologia di Venezia

Prof.Francesco Saverio Zanon, Direttore dell' Osservatorio Geofisico del Seminario Patriarcale di Venezia e della stazione meteo rologica dell' Ospedale al Mare del Lido.     

Comparison between Eulerian diagnostics and finite-size Lyapunov exponents computed from altimetry in the Algerian basin

Transport and mixing properties of surface currents can be detected from altimetric data by both Eulerian and Lagrangian diagnostics. In contrast with Eulerian diagnostics, Lagrangian tools like the local Lyapunov exponents have the advantage of exploiting both spatial and temporal variability of the velocity field and are in principle able to unveil subgrid filaments generated by chaotic stirring. However, one may wonder whether this theoretical advantage is of practical interest in real-data, mesoscale and sub-mesoscale analysis, because of the uncertainties and resolution of altimetric products, and the non-passive nature of biogeochemical tracers. Here we compare the ability of standard Eulerian diagnostics and the finite-size Lyapunov exponent in detecting instantaneous and climatological transport and mixing properties in the south-western Mediterranean. By comparing with sea-surface temperature patterns, we find that the two approaches provide similar results for slowly evolving eddies like the first Alboran gyre. However, the Lyapunov exponent is also able to predict the (sub-)mesoscale filamentary processes occurring along the Algerian current and above the Balearic Abyssal Plain. Such filaments are also observed, with some mismatch, in sea-surface temperature patterns. Climatologies of Lyapunov exponents do not show any compact relation with other Eulerian diagnostics, unveiling a different structure even at the basin scale. We conclude that filamentation dynamics can be detected by reprocessing available altimetric data with Lagrangian tools, giving insight into (sub-)mesoscale stirring processes relevant to tracer observations and complementing traditional Eulerian diagnostics.