Influence of physiology and climate on δD of leaf wax n-alkanes from C3 and C4 grasses

We measured hydrogen isotope compositions (δD) of high-molecular-weight n-alkanes (C₂₇-C₃₃) from grasses grown in greenhouses and collected from the US Great Plains. In both cases, n-alkanes from C₄ grasses are enriched in D by more than 20‰ relative to those from C₃ grasses. The apparent enrichment factor (ε_C29-GW) between C₂₉n-alkane and greenhouse water is −165 ± 12‰ for C₃ grasses and −140 ± 15‰ for C₄ grasses. For samples from the Great Plains, δD values of C₂₉n-alkanes range from −280 to −136‰, with values for C₄ grasses ca. 21‰ more positive than those for C₃ grasses from the same site. Differences in C₃ and C₄ grass n-alkane δD values are consistent with the shorter interveinal distance in C₄ grass leaves, and greater back-diffusion of enriched water from stomata to veins, than in C₃ grass leaves. Great Plains’ grass n-alkane isotopic ratios largely reflect precipitation δD values. However, the offset or apparent fractionation between n-alkanes and precipitation is not uniform and varies with annual precipitation and relative humidity, suggesting climatic controls on lipid δD values. The dryer sites exhibit smaller absolute apparent fractionation indicative of D-enrichment of source waters through transpiration and/or soil evaporation. To explore the relationship between climate and n-alkane δD values, we develop three models. (1) The ‘direct analog’ model estimates δD_C29 values simply by applying the apparent enrichment factors, ε_C29-GW, observed in greenhouse grasses to precipitation δD values from the Great Plains. (2) The ‘leaf-water’ model uses a Craig-Gordon model to estimate transpirational D-enrichment for both greenhouse and field sites. The transpiration-corrected enrichment factors between C₂₉ and bulk leaf-water, ε_C29-GW, calculated from the greenhouse samples (−181‰ for C₃ and −157‰ for C₄) are applied to estimate δD_C29 values relative to modeled bulk leaf-water δD values. (3) The ‘soil- and leaf-water’ model estimates the combined effects of soil evaporation, modeled by analogy with a flow-through lake, and transpiration on δD_C29 values. Predictions improve with the addition of the explicit consideration of transpiration and soil evaporation, indicating that they are both important processes in determining plant lipid δD values. D-enrichment caused by these evaporative processes is controlled by relative humidity, suggesting that important climatic information is recorded in leaf wax n-alkane δD values. Calibration studies such as this one provide a baseline for future studies of plant-water-deuterium systematics and form the foundation for interpretation of plant wax hydrogen isotope ratios as a paleo-aridity proxy.     

Analysis of climatic trends in data from the agrometeorological station of Bologna-Cadriano, Italy (1952–2007)

Agriculture is highly exposed to climate change, as farming activities directly depend on climatic conditions. Knowledge of the extent of such change and of related phenomena will help to answer the questions posed by society about adaptation strategies. The global situation is well described by the Fourth IPCC assessment report (IPCC 2007), but local studies are important to understand the impact and the priorities to adopt in adaptation strategies. In this study a historical set of meteorological data, collected during the period 1952–2007 at the University of Bologna (Italy) agrometeorological station, was analysed. Several indexes, such as Frost Severity Index, number of hot days, number of rainy days, etc., were calculated, and their trends in time were analysed. The results show a scenario of increasing temperatures and evapotranspiration, a decrease in rainy days and a deepening of the watertable. The effect of these changes on agriculture will be a decrease in water availability, an increase in heat stress in plants and an increase in drought risk.     

The role of bathymetry and directional wave conditions on observed crescentic bar dynamics

Nearshore sandbars are important features in the surf zone of many beaches because they strongly influence the mean circulation and evolving morphology. Due to variations in wave conditions, sandbars can experience cross-shore migration and vary in shape from alongshore uniform (shore-parallel) to alongshore rhythmic (crescentic). Sandbar dynamics have been studied extensively, but existing observational studies usually do not quantify the processes leading to crescentic bar formation and straightening. This study analyses the dynamics of crescentic bar events at the fetch-limited beach of Castelldefels (northwestern Mediterranean Sea, Spain) using 7.5 years of hourly time-exposure video images and detailed wave conditions. The results show that, despite the generally calm wave conditions, the sandbars were very dynamic in the cross-shore and longshore directions. They often migrated rapidly offshore during storms (up to 70 m in one day) and more slowly onshore during post-storm conditions. Crescentic bars were often present at the study site (48% of the time), but only when the sandbar was at least 10 m from the shoreline. They displayed a large variability in wavelengths (100–700 m), alongshore migration speeds (0–50 m/day) and cross-shore amplitudes (5–20 m). Wavelengths increased for larger bar–shoreline distances and the alongshore migration speeds were strongly correlated with the alongshore component of the radiation stresses. Crescentic patterns typically developed during low–medium energetic waves with limited obliquity ( $\theta \lesssim 20$° at 10 m depth), while bar straightening occurred during medium–high energetic waves with strong oblique angles of incidence ( $\theta \gtrsim 15$°). Overall, this study provides further proof for the important role of wave direction in crescentic bar dynamics and highlights the strong dependence of crescentic bar development on the initial bathymetric configuration.     

Paleomagnetic dating of the most recent silicic eruptive activity at Pantelleria (Strait of Sicily)

We report on the paleomagnetism of ten sites in the products of the most recent silicic eruptive cycle of Pantelleria, Strait of Sicily. Previously radiometrically dated at 5–10 ka, our comparison with proxies for geomagnetic field directions allows us to narrow considerably the time window during which these eruptions occurred. The strongly peralkaline composition causes the magmas to have low viscosities, locally resulting in strong agglutination of proximal fall deposits. This allows successful extraction of paleomagnetic directions from the explosive phases of eruptions. One of our sites was located in the Serra della Fastuca fall deposit, produced by the first explosive event of the eruptive cycle. The other nine sites were located in the most recent explosive (pumice fall and agglutinate from Cuddia del Gallo and Cuddia Randazzo) and effusive (Khaggiar lava) products. The (very similar) paleomagnetic directions gathered from eight internally consistent sites were compared to reference geomagnetic field directions of the last 5–10 ka. Directions from Cuddia del Gallo agglutinate and Khaggiar flows translate into 5.9- to 6.2-ka ages, whereas the Fastuca pumices yield a slightly older age of 6.2–6.8 ka. Hence, the most recent silicic eruptive cycle lasted at most a millennium and as little as a few centuries around 6.0 ka. Paleomagnetically inferred ages are in good agreement with published (and calibrated by us) ¹⁴C dates from paleosols/charcoals sampled below the studied volcanic units, whereas K/Ar data are more scattered and yield ∼30% older ages. Our data show that the time elapsed since the most recent silicic eruptions at Pantelleria is comparable to the quiescence period separating the two latest volcanic cycles.     

Engineering ground motion record selection in the ITalian ACcelerometric Archive

This paper introduces REXELite, an internet version of REXEL, a software for automatic selection of ground motion suites for nonlinear dynamic analysis of structures. REXELite was developed with the aim of integrating an advanced earthquake records’ repository, such as the ITalian ACcelerometric Archive (ITACA), with a tool to define seismic input for engineering seismic analysis according to international standards (with priority to Europe). In fact, REXELite allows to define target design spectra according either to Eurocode 8 or to the Italian building code, and to search ITACA for suitable sets of seven records (comprised of one or two horizontal ground motion components) matching such target spectra: on average, in a user-specified period range, and with the desired tolerance. The records in the set also have, individually and according to some criteria, the most similar spectral shape with respect to that of the code. Selection options include magnitude, source-to-site distance, soil conditions and, if desired, linear scaling of records to reduce further record-to-record variability of the selected suite.     

Estimation of load reduction factors for clay masonry walls

The in‐plane cyclic behaviour of three types of unreinforced clay masonry was characterized by means of laboratory tests on full‐scale specimens. The masonry walls were assembled with various bonding arrangements (head joints made with mortar pockets, dry head joints with mechanical interlocking, thin‐layer mortar bed joints), which are not yet inserted in seismic codes. Experimental behaviour was modelled with an analytical hysteretic model able to predict lateral load–displacement curves in case of shear failure of the unreinforced walls. According to the experimental results and those of the selected analytical model, parametric study to evaluate the reduction in lateral strength demand produced by non‐linear behaviour in masonry walls, i.e. the load reduction factor was carried out by non‐linear dynamic analyses. The calculated values of the load reduction factor were modest. The differences in values found for the three masonry types, although consistent with them, were not great. This may indicate that, in the ultimate limit state, the type of masonry cannot significantly affect the behaviour of an entire building. Copyright © 2009 John Wiley & Sons, Ltd.     

Landslide HotSpot Mapping by means of Persistent Scatterer Interferometry

Landslide detection and mapping represent fundamental requirements for every hazard and risk evaluation and consequent improvement of the management strategies for such natural hazards. Optical and radar remote sensing can be used to observe landslide-induced ground deformation, ranging from regional to local scales. This work presents a methodology called Landslide HotSpot Mapping; this approach integrates cartographic, thematic and optical data with Persistent Scatterer Interferometry for the identification of extremely slow to very slow moving landslides, and for the evaluation of their state of activity and intensity. This methodology scans wide areas to detect hotspots, which are narrow unstable zones characterized by higher landslide hazard. To these hotspots, priority has to be given when planning field surveys and in situ validation campaigns, so that field work time and effort can be optimized and significantly reduced. The approach is tested in Central Calabria, over a 4,470?km² area located in southern Italy. ENVISAT ascending images acquired between 2003 and 2009 and processed with the Persistent Scatterer Pairs (PSP) technique are used to analyse deformation patterns. Combining conventional photo-interpretation with the analysis of PSP data, 64 new landslides are identified and the spatial (boundaries) and temporal (activity) information of 980 pre-mapped phenomena (23.6% of updated inventory) are updated. 1,012 active (continuous or reactivated) landslides are identified and 4 hotspot areas selected: San Fili, Rende, Lago, Catanzaro. Urgent field checks have to be organized for these hotspots to validate the satellite-based observations and to design appropriate mitigation measures to reduce impacts on the elements at risk.