Carbon dioxide dynamics in rivers and coastal waters of the “big island” of Hawaii,USA, during baseline and heavy rain conditions

The distributions of the partial pressure of carbon dioxide (pCO₂) and total alkalinity (TA) were examined for a 6-month period in the Wailuku and Wailoa rivers and coastal waters of Hilo Bay on the west coast of the Island of Hawaii, USA. Main results for the largest and turbulent Wailuku River show in the watershed an oversaturation in CO₂ with respect to atmospheric equilibrium and a CO₂ undersaturation in the estuary. In the Wailoa river-estuary system, extremely high pCO₂ values ranging from 1500 to 10500 ppm were measured with significant shifts in pCO₂ from drought to flood period. In the two rivers, water residence time, groundwater inputs and occasional flood events are the predominant drivers of the spatial and temporal patterns in the distribution of pCO₂. In Hilo Bay, CO₂ oversaturation dominates and the bay was a source of CO₂ to the atmosphere during the study period. TA is conservative along the salinity gradient, indicating calcification in the bay is not a significant source of CO₂ to the atmosphere.     

The December 26th 2004 Tsunami Recorded along the Southeastern Coast of Brazil

Sea level measurements along the southeastern Brazilian coast, between 20° S and 30° S, show the effect of the Sumatra Tsunami of December 26, 2004. Two records from stations, one located inside an estuary and other inside a bay, shows oscillations of about 0.20 m range; one additional record from a station facing the open sea shows up to 1.2 m range oscillations. These oscillations have around 45 min period, starting 20–22 h after the Sumatra earthquake in the Indian Ocean (00:59 UTC) and lasting for 2 days. A computer modelling of the event reproduces the time of arrival of long shallow-water tsunami waves at the southeastern Brazilian coast but with slight longer period and amplitudes smaller than observed at the coast, probably due to its coarse resolution (1/4 of a degree). The high amplitudes observed at the coast suggest a mechanism of amplification of these waves over the southeastern Brazilian shelf.     

Sulfur partition coefficient between apatite and rhyolite: the role of bulk S content

Experimental studies have been performed to constrain sulfur behavior during apatite crystallization and to determine sulfur partition coefficient between apatite and melt (Kd_S^apatite/melt) at oxidizing conditions. Crystallization experiments have been conducted with a hydrous rhyolitic melt and different bulk sulfur contents (0.15 to 2 wt.% S) at 900 and 1,000°C, 200 MPa and Δlog =NNO+3.6. The sulfur content in the glass increases with increasing amount of added S. Anhydrite crystallizes for S added = 0.75 wt.% (0.10 and 0.13 wt.% SO₃ in glass at 900 and 1,000°C, respectively). The amount of anhydrite increases and the amount of apatite decreases with increasing amount of added sulfur. The sulfur exchange reaction in apatite is influenced by the bulk composition of the melt (e.g., P content). However, changing melt composition has only little effect on Kd_S^apatite/melt for the investigated rhyolitic composition. The Kd_S^apatite/melt does not depend directly on temperature, decreases from 14.2 to 2.7 with increasing S content in glass from SO₃=0.03 to 0.19 wt.%, respectively, and can be predicted from the following equation: ln Kd = −0.0025×S in melt (in ppm)+2.9178. The combination of experimental data obtained for rhyolitic and andesitic melts reveals that the sulfur partition coefficient tends toward a value of 2 for high-sulfur content in the glass (>0.2 wt.% SO₃). Using S in apatite as proxy for determining S content in melt is promising but additional experimental data are needed to clarify the individual effects of T, , and P and Ca content in the melt on S partitioning.     

Fluoride pollution in French rivers and estuaries

Fluoride concentrations have been determined in major French rivers and estuaries. The unpolluted estuary in the Loire has been compared with the Seine, Gironde and Charente where important discharges occur. Natural dissolved concentration can be multiplied by a factor of 30. Particulate fluorine concentration reach almost 2000 ppm in the Seine estuary. The percentage between free and complexed dissolved fluoride is not affected by the anthropic discharge. The present French rivers discharge of fluoride is 700% higher than the pristine value. At a global scale, dissolved fluoride has probably increased by 25% compared with the natural situation.     

A site effect study in the Verchiano valley during the 1997 Umbria-Marche (Central Italy) earthquakes

Strong site effects were observed during the two M _W 5.7 and M _W 6.0 main shocks of the Colfiorito seismic crisis which occured on September 26, 1997 in Umbria-Marche (Central Italy).The most obvious indications of these effects are the dramatic differences in damage shown by buildings of similar construction in neighboring villages.Such observations were specifically made in the Verchiano valley in the fault area, 15 km south of Colfiorito where the Verchiano village and the Colle and Camino hamlets were heavily damaged (MCS intensity IX-X) since the first main shock of 1997/09/26,while in contrast, the Curasci village located 2 km eastwards remains almost intact.In order to study the anomalous ground motion amplifications in this area, an array of 11, 3-components seismo- and accelero-meters was set up during the 1997/10/20-24 period, extending from the western side of the valley, up to the top of Mount San Salvatore, going accross the Colle and Curasci hamlets.During the experiment, 67 aftershocks enlightened the valley from the Colfiorito (10 km north) and the Sellano (6 km south) active swarms.Seismic refraction experiments were conducted at the same time in the 500 m wide, 1500 m long Verchiano valley in order to determine the thickness and main characteristics of the alluvial infilling.The main results are: (i) compared to the valley side ground motion, and for all the events, recordings in the central part of the valley (piana di Verchiano) show relative amplification of 10 with a clear lengthening of the seismogram duration by a factor of 2 – (ii) broad band relative amplification of 6–8 is also clearly identified at the top of the Mount San Salvatore overhanging the valley – (iii) any of the site effect measurements done explains by itself the strongly contrasted damage observed at Colle and Curasci: i.e. the modification of the near-field radiation pattern by interaction with the free heterogeneous surface may have induced local shadow zones that saved Curasci.     

Robotic telescopes and networks: New tools for education and science

Nowadays many telescopes around the world are automated and some networks of robotic telescopes are active or planned. Such equipment could be used for thetraining of students and for science in the Universities of DCs and of newastronomical countries, by sending them observational data via Internetor through remotely controlled telescope. It seems that it is thetime to open up for discussion with UN and ESA organizations and also withIAU, how to implement links between robotic telescopes and suchUniversities applying for collaborations. Many scientific fields couldthus be accessible to them, for example on stellar variability, near-earthobject follow-up, -ray burst counterpart tracking, and so on.     

Water and the density of silicate glasses

A review of published and newly measured densities for 40 hydrous silicate glasses indicates that the room-temperature partial molar volume of water is 12.0 ± 0.5 cm³/mol. This value holds for simple or mineral compositions as well as for complex natural glasses, from rhyolite to tephrite compositions, prepared up to 10–20 kbar pressures and containing up to 7 wt% H₂O. This volume does not vary either with the molar volume of the water-free silicate phase, with its degree of polymerization or with water speciation. Over a wide range of compositions, this constant value implies that the volume change for the reaction between hydroxyl ions and molecular water is zero and that, at least in glasses, speciation does not depend on pressure. Consistent with data from Ochs and Lange (1997, 1999), systematics in volume expansion for SiO₂–M₂O systems (M=H, Li, Na, K) suggests that the partial molar thermal expansion coefficient of H₂O is about 4 × 10⁻⁵ K⁻¹ in silicate glasses. Received: 30 June 1999 / Accepted: 5 November 1999     

Thermal and mechanical behaviour of the orogenic middle crust during the syn‐ to late‐orogenic evolution of the Variscan root zone,Bohemian Massif

We combine structural observations, petrological data and ⁴⁰Ar–³⁹Ar ages for a stack of amphibolite facies metasedimentary units that rims high‐P (HP) granulite facies felsic bodies exposed in the southern Bohemian Massif. The partly migmatitic Varied and Monotonous units, and the underlying Kaplice unit, show a continuity of structures that are also observed in the adjacent Blanský les HP granulite body. They all exhibit an earlier NE?SW striking and steeply NW‐dipping foliation (S3), which is transposed into a moderately NW‐dipping foliation (S4). In both the Varied and Monotonous units, the S3 and S4 foliations are characterized by a Sil–Bt–Pl–Kfs–Qtz–Ilm±Grt assemblage, with occurrences of post‐D4 andalusite, cordierite and muscovite. In the Monotonous unit, minute inclusions of garnet, kyanite, sillimanite and biotite are additionally found in plagioclase from a probable leucosome parallel to S3. The Kaplice unit shows rare staurolite and kyanite relicts, a Sil–Ms–Bt–Pl–Qtz±Grt assemblage associated with S3, retrogressed garnet?staurolite aggregates during the development of S4, and post‐D4 andalusite, cordierite and secondary muscovite. Mineral equilibria modelling for representative samples indicates that the Varied unit records conditions higher than ~7 kbar at 725 °C during the transition from S3 to S4, followed by a P?T decrease from ~5.5 kbar/750 °C to ~4.5 kbar/700 °C. The Monotonous unit shows evidence of partial melting in the S3 fabric at P?T above ~8 kbar at 740–830 °C and a subsequent P?T decrease to 4.5–5 kbar/700 °C. The Kaplice unit preserves an initial medium‐P prograde path associated with the development of S3 reaching peak P?T of ~6.5 kbar/640 °C. The subsequent retrograde path records 4.5 kbar/660 °C during the development of S4. ⁴⁰Ar–³⁹Ar geochronology shows that amphibole and biotite ages cluster at c. 340 Ma close to the HP granulite, whereas adjacent metasedimentary rocks preserve c. 340 Ma amphibole ages, but biotite and muscovite ages range between c. 318 and c. 300 Ma. The P?T conditions associated with S3 imply an overturned section of the orogenic middle crust. The shared structural evolution indicates that all mid‐crustal units are involved in the large‐scale folding cored by HP granulites. The retrograde P–T paths associated with S4 are interpreted as a result of a ductile thinning of the orogenic crust at a mid‐crustal level. The ⁴⁰Ar–³⁹Ar ages overlap with U–Pb zircon ages in and around the HP granulite bodies, suggesting a short duration for the ductile thinning event. The post‐ductile thinning late‐orogenic emplacement of the South Bohemian plutonic complex is responsible for a re‐heating of the stacked units, reopening of argon system in mica and a tilting of the S4 foliation to its present‐day orientation.