Time and space matter: How urban transitions create inequality

An increase in transportation costs impacts the welfare of households living on the outskirts of the city more than the other inhabitants and, in the short term, limited housing supply stops them from moving toward the center. Over a longer period, however, urban adjustments cancel out this inequality: (1) in the center, rent level rises because of higher demand, inducing investment in additional housing and increasing city density; (2) on the outskirts, housing demand decreases until rent level decreases and compensates for higher transportation expenditures. Inertia in housing supply and household re-locations leads, therefore, to the development of spatial inequalities.To investigate this issue, we built a dynamic model that reproduces urban transitions in monocentric cities, and enables quantifying in continuous time their spatialized consequences. Applied to the implementation of a transportation tax, the model suggests that a rapid implementation would induce (i) higher welfare losses than can be inferred from traditional models and (ii) major redistributive effects throughout the city. Finally, the model suggests that an early and progressive implementation is to be preferred to late and aggressive action.These results challenge current assessment methods of climate change stabilization strategies and show that it is essential to take into account urban dynamics and inequalities in the design of climate policy.     

Solubility measurements of synthetic neodymium monazite as a function of temperature at 2 kbars, and aqueous neodymium speciation in equilibrium with monazite

The solubility of synthetic NdPO₄ monazite end-member was experimentally determined from 300 up to 800 °C, at 2000 bars in pure water, and in aqueous chloride or phosphate solutions. Both the classical weight-loss method and a new method based on isotope dilution coupled with thermal ionization mass spectrometer were used. In the range of temperature studied monazite showed a prograde solubility from 10^−5.4 m at 300 °C up to 10^−2.57 m at 800 °C. Experiments in H₂O-H₃PO₄-NaCl-HCl solutions suggested Nd(OH)₃⁰ was the major species that was formed at high temperature and pressure. The equilibrium constants (log K) for the reaction:

     

A two‐step process for the reflooding of the Mediterranean after the Messinian Salinity Crisis

The Messinian Salinity Crisis is well known to have resulted from a significant drop of the Mediterranean sea level. Considering both onshore and offshore observations, the subsequent reflooding is generally thought to have been very sudden. We present here offshore seismic evidence from the Gulf of Lions and re‐visited onshore data from Italy and Turkey that lead to a new concept of a two‐step reflooding of the Mediterranean Basin after the Messinian Salinity Crisis. The refilling was first moderate and relatively slow accompanied by transgressive ravinement, and later on very rapid, preserving the subaerial Messinian Erosional Surface. The amplitude of these two successive rises of sea level has been estimated at ≤500 m for the first rise and 600–900 m for the second rise. Evaporites from the central Mediterranean basins appear to have been deposited principally at the beginning of the first step of reflooding. After the second step, which preceeded the Zanclean Global Stratotype Section and Point, successive connections with the Paratethyan Dacic Basin, then the Adriatic foredeep, and finally the Euxinian Basin occurred, as a consequence of the continued global rise in sea level. A complex morphology with sills and sub‐basins led to diachronous events such as the so‐called ‘Lago Mare’.This study helps to distinguish events that were synchronous over the entire Mediterranean realm, such as the two‐step reflooding, from those that were more local and diachronous. In addition, the shoreline that marks the transition between these two steps of reflooding in the Provence Basin provides a remarkable palaeogeographical marker for subsidence studies.     

1750?years of large rainfall events inferred from particle size at East Lake, Cape Bounty, Melville Island, Canada

Annual grain-size variation was measured on the varved (annually laminated) lacustrine sediment from Cape Bounty East Lake using an innovative image analysis system. About 7100 images were acquired using a scanning electron microscope and processed to obtain measurement of particles from 2845 varves. Several particle-size distributions indices were calculated and can be linked to high-energy sedimentary facies. Moreover, the coarse grain size (98th percentile) of these high-energy facies is strongly correlated with summer rainfall (and also summer temperature) of instrumental data from nearby stations. Particle-size distributions show a similar trend through time, especially for the standard deviation and the 98th percentile. Climatic reconstruction suggests that Cape Bounty recently experienced an unprecedented increase of rainfall events since ~AD 1920. On the other hand, changes in varve thickness are weakly correlated with the particle-size distribution. Altogether, these results highlight the need to obtain annual grain-size data to identify a meteorological signal.     

Formation and evolution of the chaotic terrains by subsidence and magmatism: Hydraotes Chaos, Mars

The origin of the martian chaotic terrains is still uncertain; and a variety of geologic scenarios have been proposed. We provide topographic profiles of different chaos landscapes, notably Aureum and Hydraotes Chaos, showing that an initial shallow ground subsidence occurred at the first step of the chaos formation. We infer that the subsidence was caused by intrusion of a volcanic sill; which could have produced consequent melting as well as release of ground water from disrupted aquifer. Signs of a volcanic activity are observed on the floor of Hydraotes Chaos, a complex and deep depression located at the junction of three channels. The volcanic activity is represented by small, 0.5 to 1.5 km diameter, rounded cones with summit pits. The cone's size and morphology, as well as the presence of possible surrounding lava flows, suggest that they are primary volcanic cones similar to terrestrial cinder cones. The identification of volcanic activity on the deepest chaos, where the lower crustal thickness and the faults/fractures system contributed to the magma rising, reveals that magmatic activity, proved by the cones, and possibly help by structural activity, has been a major factor in the formation of chaotic terrains.     

New experimental constraints on the composition and structure of tholins

Powdered samples of carbon-nitrogen-hydrogen “tholins” that mimic Titan's atmosphere aerosols were produced under levitation conditions in the laboratory with a dusty plasma (PAMPRE experiment) using different initial N₂:CH₄ gas mixtures and studied using UV Raman and infrared spectroscopy, X-ray diffraction and high resolution transmission electron microscopy (HRTEM). Comparison between the tholins produced in the PAMPRE experiments and samples prepared by other techniques reveal that they form a fairly homogeneous family of hydrogenated carbon nitride materials. Wall effects during the PAMPRE deposition experiments and other were found to have little effect on the chemical structure of tholins. The first-order UV Raman bands of the disordered carbonaceous materials point to a large contribution of sp² clusters present compared with olefinic CN or CC groupings, whereas features at 690 and 980 cm⁻¹ suggest C₃N₃ rings are present as a species inserted in the macromolecular network. Diffraction techniques do not indicate the presence of large polyaromatic species in any of the tholins studied, whatever their nitrogen concentration, in disagreement with certain previous observations. This precludes the idea that the nature and degree of absorption in the visible range is controlled by the size of polyaromatic species, as has been observed in series of carbon-based materials obtained via thermal processing. Infrared spectroscopy analysis of the tholins has confirmed earlier identifications of chemical groups present including primary amines, nitriles, and alkyl moieties such as CH₂/CH₃, but has ruled out CH₂/CH₃ branches appearing on secondary or tertiary amines. Similar analyses were also performed on a polymeric (HCN)_x material, which was found to present several similarities with the tholins, hence suggesting similar polymerization processes.     

Long term high frequency sediment observatory in an alpine catchment: The Arc-Isère rivers,France

We present a dataset on to the Arc-Isère long-term environmental research observatory, which is part of the Rhône Basin Long Term Environmental Research Observatory. This alpine catchment located in the French Alps is characterized by high Suspended Particulate Matter (SPM) in anthropogenized valleys. Suspended Sediment Concentrations (SSC) naturally observed in the river are very high, ranging from a few tens of milligrams per litre at low flow to tens of grams per litre during major natural hydrological events (floods, debris flows) or river dam hydraulic flushes. One research objective related to this site is to better understanding the SSC dynamics along the river using a system of nested catchments (Arvan, Arc, and Isère) in order to assess both temporal and spatial dynamics. The data allow the quantification of fine sediment yields and also the evaluation of possible morphological changes due to fine sediment deposition or resuspension. Additionally, the observatory database support studies on contaminants (either dissolved or particulate contaminants). Our monitoring includes six stations with high frequency (2–30 min) streamflow, SSC measurement using turbidity sensors, and associated automatic sampling. Discharge is measured via water level measurements and a rating curve. The oldest station (Grenoble-campus) started recording discharge and concentration data from April 2006 while others stations were built between 2009 and 2011. Data are available in an online data website called ‘Base de Données des Observatoires en Hydrologie’ (Hydrological observatory database, https://bdoh.irstea.fr/ARC-ISERE/ ) with a DOI reference for the dataset. The hydrological and sediment transport time series are stored, managed and made available to a wide community with unfettered access in order to be used at their full extent. This database is used as a data exchange tool for both scientists and operational end-users and there is an associated online tool to compute integrated fluxes.