Proxies for land plant biomass: closed system pyrolysis of some methoxyphenols

Methoxyphenols can be used as proxies for terrestrial biomass when investigating the chemical changes in lignin during hydrothermal alteration. The closed system microscale pyrolysis of 2-methoxyphenol (2-MOP) and 2,6-dimethoxyphenol (2,6-DMP), in the presence of water vapour, has been studied in borosilicate glass vessels. 2-MOP was heated isothermally at temperatures of 330°C for 96 h and 2,6-DMP was heated isothermally at 300°C for 118 h. Pyrolysis of the model compound 2-MOP gave a simple product distribution which was composed mainly of 1,2-dihydroxybenzene with lower amounts of 2-methylphenol and phenol. The prominent reaction products from heating 2,6-DMP were 1,2-dihydroxy-6-methoxybenzene and 2-methoxy-6-methylphenol, with minor amounts of 2-MOP, 1,2-dihydroxybenzene and 2-methylphenol. The decreasing amounts of 2,6-DMP with heating time and the concomitant increase in the amounts of 1,2-dihydroxy-6-methoxybenzene suggested that demethylation had occurred.     

Are Cosmic Rays Influencing Oceanic Cloud Coverage – Or Is It Only El Niño?

The monthly average (C2) cloudcoverage data produced by the International SatelliteCloud Climatology Project (ISCCP) for the period ofJuly 1986–June 1991 show strong global and regionalcloud coverage variations associated with the ElNiño of 1986–1987. The Pacific Ocean, inparticular, shows strong regional variations in cloudcoverage. These agree well with contemporaneoussatellite observations of broadband shortwave infraredcloud forcing measured by the Earth Radiation BudgetExperiment. Svensmark and Friis-Christensen (1997)noted a similarity between the shape of the timeseries curve of average cloud coverage fraction formid- to low-latitude ocean-areas and the time seriescurve of cosmic ray flux intensity. They proposed acausal relationship – a `missing link' for solarcycle influence on Earth climate. Further spatial andtemporal analysis of the same ISCCP C2 data in thispaper indicates that the cloud coverage variationpatterns are those to be expected for the atmosphericcirculation changes characteristic of El Niño,weakening the case for cosmic rays as a climaticforcing factor.     

Compton Scattering in Plane Media: Polarization of Radiation and Azimuth Independence. I. Theory

Astrophysics - Compton scattering of polarized radiation by a nondegenerate and unpolarized electron gas is examined. Two polarization bases are introduced for pulses of photons: external,...     

Reconstruction of the harmonic component of the magnetic field modulus anomalies

An algorithm is proposed for calculating a harmonic function equal to the projection of the anomalous magnetic field vector onto the normal field direction from in situ measurements of the anomalous magnetic field modulus (the scalar magnetic anomaly) ΔT, which is a nonharmonic function and is nonlinearly related to the magnetization of anomaly sources. It is shown that the inferred estimates tend to the desired harmonic function if the iterative algorithm converges. The convergence conditions and stability of the process are studied numerically in a wide range of amplitudes of the anomalous field. The results of the modeling simulation demonstrate the efficiency of the proposed algorithm in solving magnetic field interpretation problems often encountered in practice.     

Contaminant concentrations in sport fish from San Francisco Bay, 1997

In 1997, seven sport fish species were sampled from seven popular fishing areas in San Francisco Bay. Mercury exceeded a human health screening value in 44 of 84 (52%) samples. All collected samples of leopard shark and striped bass exceeded the mercury screening value of 0.23 microg/g wet weight. PCBs exceeded the screening value in 51 of 72 (71%) samples. DDT, chlordane, and dieldrin, had lower numbers of samples above screening values: 16 of 72 (22%) for DDT, 11 of 72 (15%) for chlordanes, and 27 of 72 (37%) for dieldrin. Concentrations of PCBs and other trace organics were highest in white croaker and shiner surfperch, the two species with the highest fat content in their muscle tissue. Fish from one location, Oakland Harbor, had significantly elevated wet weight concentrations of mercury, PCBs, DDTs, and chlordanes compared to other locations. Removal of skin from white croaker fillets reduced lipid concentrations by 27-49% and concentrations of trace organics by 33-40%.     

Sedimentary Basins and the Blockage of Lg Wave Propagation in the Continents

v--vThe phenomenon of "Lg blockage," where Lg is strongly attenuated by crustal heterogeneities, poses a serious problem to CTBT monitoring because Lg is an important seismic phase for discrimination. This paper examines blockage in three continental regions where the Lg blockages may be caused by large, enclosed sedimentary basins along the propagation path. The Barents Sea Basin blocks Lg propagation across the Barents Sea from the Russian nuclear test sites at Novaya Zemlya to Scandinavian stations. Also, "early Lg" waves are observed in Sn codas on NORSAR, NORESS, and ARCESS recordings of Novaya Zemlya explosions where direct Lg is blocked. Early Lg waves may have resulted from Sn-to-Lg mode conversion at the contact between the Barents Basin and the Kola Peninsula. The Northern and Southern Caspian Sea Basins also block Lg waves from PNEs and earthquakes, perhaps due to thick, low-velocity, low-Q sediments replacing the granitic layer rocks in the crust. Lg blockage has also been observed in the Western Mediterranean/Levantine Basin due to low-Q sediments and crustal thinning. A "basin capture" model is proposed to explain Lg blockage in sedimentary basins. In this model, shear waves that reverberate in the crust and constitute the Lg wave train are captured, delayed, and attenuated by thick, low-velocity sediments that replace the "granitic" layer rocks of the upper crust along part of the propagation path. Sn waves, which propagate below the basin, would not be blocked and in fact, the blocked Lg waves may be diverted downward into Sn waves by the low velocity sediments in the basin.     

New U-Pb ages of zircons in the Owk Shale (Kurnool Group) with reflections on proterozoic porcellanites in India

Felsic tuff beds with some presumed sedimentary components were reported from the Owk Shale (Kurnool Group; bearing Neoproterozoic fossils) in the upper part of the sedimentary succession in the Cuddapah basin in India by Saha and Tripathy (2012a). Our optical and SEM petrographic study of three thin sections, however, indicates that the parent samples are sandy mudstones with variable amounts of a felsic volcaniclastic component. New highquality U-Pb (SHRIMP and LA-MC-ICPMS) ages of 133 detrital zircon grains from a sample show that one grain is ca. 1880 Ma, one grain is ca. 3300 Ma, and the ages of the remaining 131 grains fall between 2690 Ma and 2429 Ma, the population averaging 2522 ± 36 Ma. The data indicate that the zircons are detrital grains derived from the ca. 2.5 Ga granitic/gneissic/greenstone basement of the Dharwar cratons that also host minor older Archean enclaves. The single 1880 Ma grain could have come from a ca. 1.9 Ga LIP. In the absence of any younger magmatic zircon, the absolute age of the Owk Shale remains elusive.