Climatic variability in the Late Copper Age: stable isotope fluctuation of prehistoric Unio pictorum (Unionidae) shells from Lake Balaton (Hungary)

Geochemical records of bivalve shells have been increasingly studied in the last decade to obtain information on climate conditions. In this paper we present stable isotope compositions of living and prehistoric shells of freshwater mussels (Unionidae) and their relationships with climate conditions in a shallow lake environment of Lake Balaton, West-Central Hungary. Physical conditions and stable oxygen isotope compositions of lake water samples were monitored where living bivalves were collected. Comparisons between seasonal variations in ambient temperature, water composition and within-shell isotopic variations indicate that the shells of Unio pictorum do reflect local changes at high resolution and thus can be used to study past conditions. Additionally, shells covering the last two decades were gathered at several locations along the lake in order to determine spatial and temporal variations in the shells’ isotopic compositions as a function of weather conditions. As an application, prehistoric shells collected in archaeological excavations were analysed in order to study past environmental variations. Climate variations during the Late Copper Age (5460–4870 cal. yr BP) have been assumed on the basis of geomorphological and archaeozoological observations at the site Balatonkeresztúr-Réti-dűlő (south of Lake Balaton), that suggested increasing humidity as a cause of changes in settlement location and domestic livestock husbandry. Stable carbon and oxygen isotope compositions of prehistoric bivalve shells were analyzed from excavations representing five archaeological subphases (Boleráz subphase, 5460–5310 cal. yr BP; two transitional subphases around 5310 cal. yr BP; Early Classic subphase, 5310–5060 cal. yr BP; Late Classic subphase, 5040–4870 cal. yr BP). The analyses revealed significant negative C and O isotope shifts in the transitional subphases relative to the earlier and later subphases. The isotopic variations indicate that the local climate became relatively wet and possibly cold around 5310 cal. yr BP, then it returned to drier (and likely warmer) conditions during the Classic subphases. This interpretation is in agreement with previous studies on climate changes related to the “5.3 ky event” in the European continental area and the North Atlantic Region, indicating an Atlantic influence in the Carpathian Basin.     

Social networks and healthy cities: spreading good practices based on a spanish case study

The city of Vitoria‐Gasteiz in Spain is considered a “healthy city” and has implemented sustainable actions to increase the mobility of its healthcare professionals. The objectives of this study are firstly to account for the use of bicycles at work as a strategy for a healthy city and secondly to propose a conceptual framework for analyzing this network and its capacity to spread their practices The paradigm proposed is that of social networks, within which sharing between contacts is explained by means of two models: the “threshold model” and “opinion leaders”.     

222Rn as Natural Tracer for LNAPL Recovery in a Crude Oil‐Contaminated Aquifer

The objective of this study was to investigate whether ²²²Rn in groundwater can be used as a tracer for light non‐aqueous phase liquid (LNAPL) quantification at a field site treated by dual‐phase LNAPL removal. After the break of a pipeline, 5 ha of soil in the nature reserve Coussouls de Crau in southern France was contaminated by 5100 m³ of crude oil. Part of this oil seeped into the underlying gravel aquifer and formed a floating oil body of about 3.9 ha. The remediation consists of plume management by hydraulic groundwater barriers and LNAPL extraction in the source zone. ²²²Rn measurements were performed in 21 wells in and outside the source zone during 15 months. In uncontaminated groundwater, the radon activity was relatively constant and remained always >11 Bq/L. The variability of radon activity measurements in wells affected by the pump‐and‐skim system was consistent with the measurements in wells that were not impacted by the system. The mean activities in wells in the source zone were, in general, significantly lower than in wells upgradient of the source zone, owing to partitioning of ²²²Rn into the oil phase. The lowest activities were found in zones with high non‐aqueous phase liquid (NAPL) recovery. LNAPL saturations around each recovery well were furthermore calculated during a period of high groundwater level, using a laboratory‐determined crude oil–water partitioning coefficient of 38.5 ± 2.9. This yielded an estimated volume of residual crude oil of 309 ± 93 m³ below the capillary fringe. We find that ²²²Rn is a useful and cheap groundwater tracer for finding zones of good LNAPL recovery in an aquifer treated by dual‐phase LNAPL removal, but that quantification of NAPL saturation using Rn is highly uncertain.     

Damages observed in locations of Oaxaca due to the Tehuantepec Mw8.2 earthquake,Mexico

On September 7, 2017, at 23:49 h (local time), a Mw8.2 intermediate-depth normal-fault earthquake occurred in the Gulf of Tehuantepec, 133 km away from Pijijiapan, Chiapas, and about 700 km away from Mexico City. This event caused 95 fatalities and severe damage to different types of structures located close to the epicenter. The main objective of this work is to present observed damages caused in the state of Oaxaca by this earthquake, which were mainly concentrated in self-built houses and historical and ancient buildings. The locations visited by the reconnaissance team of the Institute of Engineering from UNAM in Oaxaca included Salina Cruz, Tehuantepec, Ixtaltepec, Juchitán, Huatulco and La Ventosa.

     

Budgets of Mn,Cd and Cu in the macrotidal Gironde estuary (SW France)

The behavior and budget of Mn, Cd and Cu in the Gironde estuary were investigated through data from both the water column (WC) and sediment depth profiles. In the estuarine freshwater reaches, Mn and Cd removal from and Cu addition to the dissolved phase occurs with a magnitude equivalent to 10%, 30% and 25% of their respective annual fluvial gross dissolved input, respectively. In the saline estuary, diffusive benthic outflow is the main source of dissolved Mn (74% of the total gross dissolved input within the estuary) to the WC. In contrast, Cd (96%) and Cu (89%) are mainly released into the dissolved phase of the WC from fluvial, estuarine and dredging-related particles through complexation (Cd) and organic carbon mineralization (Cu). Anthropogenic activities (sediment dredging) induce pore water inputs, particulate sulfide oxidation and sediment resuspension, significantly contributing to the metal budget of the WC. The related amounts of metals released could be equivalent to 20–50% (Cd) and up to 70% (Cu) of their respective net dissolved addition. Mass balances suggest that a large part of the metals previously released into the dissolved phase from processes within the estuary are removed by suspended particles due to (co-)precipitation of Fe/Mn (oxy)hydroxides and scavenging on autochthonous organic matter. On an annual basis, the Gironde estuary acts as a net sink of dissolved Mn, removing 60% of the dissolved fluvial inputs, and as a net source of dissolved Cd and Cu, contributing ∼ 85% and 20–45% to the dissolved Cd and Cu fluxes to the ocean.     

Wavelet analysis of the standard map: Structure and scaling

Wavelet analysis is applied to distributions of points generated by iterating the standard map. The initial condition is chosen so that the points fill the largest chaotic region. When the standard map parameterk=1.3, the distribution of points contains many voids corresponding to islands in the chaotic region. The wavelet transform is dominated by contributions from these islands. Fork=10 the chaos fills phase space and no structure is apparent; the wavelet transform reveals statistical fluctuations in the distribution of points.     

The glacial inception as recorded in the NorthGRIP Greenland ice core: timing, structure and associated abrupt temperature changes

The mechanisms involved in the glacial inception are still poorly constrained due to a lack of high resolution and cross-dated climate records at various locations. Using air isotopic measurements in the recently drilled NorthGRIP ice core, we show that no evidence exists for stratigraphic disturbance of the climate record of the last glacial inception (∼123–100 kyears BP) encompassing Dansgaard–Oeschger events (DO) 25, 24 and 23, even if we lack sufficient resolution to completely rule out disturbance over DO 25. We quantify the rapid surface temperature variability over DO 23 and 24 with associated warmings of 10±2.5 and 16±2.5°C, amplitudes which mimic those observed in full glacial conditions. We use records of δ¹⁸O of O₂ to propose a common timescale for the NorthGRIP and the Antarctic Vostok ice cores, with a maximum uncertainty of 2,500 years, and to examine the interhemispheric sequence of events over this period. After a synchronous North–South temperature decrease, the onset of rapid events is triggered in the North through DO 25. As for later events, DO 24 and 23 have a clear Antarctic counterpart which does not seem to be the case for the very first abrupt warming (DO 25). This information, when added to intermediate levels of CO₂ and to the absence of clear ice rafting associated with DO 25, highlights the uniqueness of this first event, while DO 24 and 23 appear similar to typical full glacial DO events.     

60Fe–60Ni systematics in the eucrite parent body: A case study of Bouvante and Juvinas

Eucrites are basaltic meteorites that cooled rapidly but are in many instances thermally metamorphosed and impact brecciated. The exact timing of these events remains unclear. In this study, Ni isotopic compositions and Fe/Ni elemental ratios are presented for two non-cumulate eucrites, Bouvante and Juvinas, including mineral separates from the latter. The samples are characterized by variable, well-resolved ⁶⁰Ni-excesses consistent with the former presence of live ⁶⁰Fe (t_1/2 = 2.62 Ma) at the time of eucrite crystallization. A significant fraction of Ni with a terrestrial-like composition appears to be surface correlated. This Ni may be the product of terrestrial contamination or was introduced by a chondritic impactor during brecciation. Altogether, the data provide evidence for a complex and probably multi-stage history of Fe and/or Ni redistribution, which impedes the interpretation of the chronological data.