Long-wave radiative analysis of cloudy scattering atmospheres using a net exchange formulation

The Net Exchange Formulation (NEF) is an alternative to the usual radiative transfer equation. It was proposed in 1967 by Green [Q. J. R. Meteorol. Soc. 93 (1967) 371] for atmospheric sciences and by Hottel [H.C. Hottel, A.F. Sarofim. Radiative Transfer McGraw Hill, New York, 1967] for engineering sciences. Until now, the NEF has been used only in a very few cases for atmospheric studies. Recently we have developed a long-wave radiative code based on this formulation for a GCM of the Mars planet. Here, we will present results for the Earth atmosphere, obtained with a Monte Carlo Method based on the NEF. In this method, fluxes are not addressed any more. The basic variables are the net exchange rates (NER) between each pair of atmospheric layer (i, j), i.e. the radiative power emitted by i and absorbed by j minus the radiative power emitted by j and absorbed by i. The graphical representation of the NER matrix highlights the radiative exchanges that dominate the radiative budget of the atmosphere and allows one to have a very good insight of the radiative exchanges. Results will be presented for clear sky atmospheres with Mid-Latitude Summer and Sub-Arctic Winter temperature profiles, and for the same atmospheres with three different types of clouds. The effect of scattering on long-wave radiative exchanges will also be analysed.     

Disappearance of a crater lake: implications for potential explosivity at Soufrière volcano,St Vincent,Lesser Antilles

Soufrière volcano in St Vincent, West Indies, is one of the most active volcanoes in the Eastern Caribbean with at least six eruptions since 1718 AD, the latest of which occurred in 1979. Prior to the 1979 eruption, the active crater hosted deep-water lakes during periods of repose, which were always replenished within a few years after the eruptions. In 1979, the crater was filled with 10⁸ m³ of fragmental material and, despite constant precipitation, has remained virtually dry ever since, with the exception of a small shallow pond. A resistivity survey was conducted in July 2006 to investigate groundwater occurrence in the crater. Results from the resistivity data inversion on several 2-D profiles show a shallow horizontal conductor across the crater floor, consistent with a water-saturated aquifer. They also show that the post-1979 pond, currently present in the crater lake is in fact an outcropping part of the groundwater water reservoir. The reservoir water table is ∼28 m above the pre-1979 lake level and reflects mass equilibrium in the system where constant seepage underground balances the meteoric recharge. We suggest that the groundwater body extends at depth to the bottom of the pre-1979 crater lake, either due to a significant structural discontinuity or because of a reduction of permeability at depth. The estimated maximum volume of water stored underground is 10–30 × 10⁶ m³ and energy considerations indicate that 2.4–7.3 × 10¹⁰ kg of magma would potentially be sufficient to vaporise the whole groundwater body. This amount of magma represents only 13–41% of the mass erupted during the last eruption in 1979 which was the smallest of the past 3 eruptions (1902, 1971–72, 1979). Since explosive phreatic or phreatomagmatic eruptions at Soufrière seem to be linked to magma-water interaction within confined space, the results from this survey suggests that phreatic or phreatomagmatic activity is a distinct possibility during future magma intrusion in the summit area, despite the apparent disappearance of water in the summit crater.     

Calculation of amorphous silica solubilities at 25° to 300°C and apparent cation hydration numbers in aqueous salt solutions using the concept of effective density of water

The solubility of amorphous silica in aqueous salt solutions at 25° to 300°C can be calculated using information on its solubility in pure water and a model in which the activity of water in the salt solution is defined to equal the effective density. p_e, of “free” water in that solution. At temperatures of 100°C and above, p_e closely equals the product of the density of the solution times the weight fraction of water in the solution. At 25°C, a correction parameter must be applied to p_e that incorporates a term called the apparent cation hydration number, h. Because of the many assumptions and other uncertainties involved in determining values of h, by the model used here, the reported numbers are not necessarily real hydration numbers even though they do agree with some published values determined by activity and diffusion methods. Whether or not h is a real hydration number, it would appear to be useful in its inclusion within a more extensive activity coefficient term that describes the departure of silica solubilities in concentrated salt solutions from expected behavior according to the model presented here. Values of h can be calculated from measured amorphous silica solubilities in salt solutions at 25°C provided there is no complexing of dissolved silica with the dissolved salt, or if the degree of complexing is known. The previously postulated aqueous silica-sulfate complexing in aqueous Na₂SO₄ solutions is supported by results of the present effective density of water model.     

Slow cooling versus episodic fluid injections: Deciphering the Caledonian orogeny in Vestvågøy,Lofoten islands,Norway

The determination of the thermal (temperature–time) histories of high‐P metamorphic terranes has been commonly based on the concepts of slow cooling and closure temperatures. In this paper, we find that this approach cannot reconcile a geochronological data set obtained from the amphibolite‐facies allochthonous Leknes Group of the Lofoten islands, Norway, which reveals an extremely complex thermal history. Using detailed results from several different geochronometers such as ⁴⁰Ar/³⁹Ar, Rb–Sr and U–Pb, we show that a model invoking multiple, short‐lived thermal pulses related to hot‐fluid infiltration channelized by shear zones can reconcile this complicated data set. This model suggests that hot fluids infiltrated throughout basement shear zones and affected the overlying cold allochthon, partially resetting U/Pb rutile and titanite ages, crystallizing new zircon and produced identical ⁴⁰Ar/³⁹Ar and Rb/Sr ages in muscovite, biotite and amphibole in various rocks throughout the region. This paper shows the enormous potential of coupling laser Ar‐spot data with thermal modelling to identify and constrain the duration of short‐lived events. An optimal P–T–t history has been derived by modelling the age data from a previously dated large muscovite crystal (Hames & Andresen, 1996, Geology, 24 :1005) and using Zr‐in‐rutile thermometry which is consistent with all geochronological data and geological constraints from the basement zones and allochthon cover. This tectonothermal model history suggests that there have been three episodic hot‐fluid and ⁴⁰Ar‐free infiltration events, resulting in the total resetting of Ar ages during the Scandian (425 Ma) for 1 Ma at 650°C and two reheating events at 415 Ma for 400 ka at 650°C and at 365 Ma for 50 ka at 600°C, which are modelled as thermal spikes above an ambient temperature of 300°C. Independent confirmation of these parameters was provided by Pb‐diffusion modelling in rutile and titanite. The model suggests that the amphibolite facies rocks of the Leknes Group probably remained cold before being exhumed for at least 60 Ma (425–365 Ma) and successfully explains the presence of different minerals that crystallized or were totally/partially reset in the allochthon and in the basement. The migration of hot fluids for short periods of times within conduits extending through the basement and allochthon rock units is likely associated with episodic seismic activity during the Caledonian orogeny.     

Application of evidential reasoning to improve the mapping of regenerating forest stands

This study confirmed the ability of the Dempster–Shafer theory (DST) and the Dezert–Smarandache (Free DSm model) theory to significantly improve the quality of maps of regenerating forest stands in southern Quebec, Canada compared to a classical Maximum Likelihood Algorithm (MLA). The proposed approach uses data fusion methods that allow the integration of remotely sensed imagery with conventional maps of ecophysiographic features. While the MLA provided an overall accuracy of 82.75%, the DST and Free DSm models had overall accuracies of 90.14% and 91.13% respectively. In addition, this study showed that the data fusion methods can model the influence of biophysical parameters (e.g., surface deposits and drainage) on the growth potential of regenerating forest stands. This study illustrates the importance of the mass function allocation for each ancillary data source. We found that a Bayesian belief configuration provided results equivalent to those obtained when representing data uncertainty. This demonstrates the difficulty in modelling uncertainty associated with each ancillary source.     

Physical and chemical control of the phytoplankton of Ahe lagoon, French Polynesia

The environmental characteristics of Ahe deep lagoon (Tuamotu Archipelago, French Polynesia) were studied over 3 years with the aim of explaining the spatial and temporal variability of the natural food available for pearl oysters with a special focus on phytoplankton biomass and global photosynthesis/respiration ratio of the lagoon. Chlorophyll averaged 0.34±0.01 μg L(-1) and our findings did not confirm increased phytoplankton biomass in deep lagoonal waters. Phytoplankton production appears to be limited firstly by nitrogen and respiratory processes overpass photosynthetic processes at least in the north-eastern edge of the atoll. Grazing by pearl oysters in culture seems to decrease the POC concentration but not the phytoplankton biomass. Oysters graze mainly on non chlorophyllian particles.     

Investigation of Transport Processes inside Karst Aquifer by Means of STATIS

Environmental data sets are often multidimensional and consequently display complex structure. This article shows the limitations of principal component analysis (PCA) for the study of such three-dimensional (3D) data sets. These limitations can be resolved by the use of the statistical tool STATIS. The inlet (a swallow hole) and the outlet (a spring) of a karst system of the Western Paris basin were sampled during three rain events of various intensities. These 3D geochemical data sets (variables × sites × dates) for a karst system were analyzed by STATIS method to identify hydrological processes. STATIS proceeds in three steps (interstructure, compromise, and intrastructure), which allows us to focus the analysis of hydrologic systems at different temporal and spatial scales. Compromise plane shows that suspended matter and flood are not simultaneous and highlights a rapid flow, characterized by turbidity and phosphate, which represents a point source contamination, and a ground water flow contaminated by nitrate. Intrastructure plane allows us to compare hydrochemical variations between the swallow hole and the spring lead. By this way, hydrological processes such as direct transfer and resuspension of intrakarstic sediments before and after the flood were identified what cannot be realized by comparison of inlet and outlet breakthrough curves. Finally, results obtained from the same data set by STATIS and a coupled study using PCA and normalized hysteresis curves were compared. This comparison shows the efficiency of STATIS at the identification of transport processes and vulnerability of karst system and its potential for hydrological applications.     

Pearl oysters Pinctada margaritifera grazing on natural plankton in Ahe atoll lagoon (Tuamotu archipelago, French Polynesia)

In atoll lagoons of French Polynesia, growth and reproduction of pearl oysters are mainly driven by plankton concentration. However, the actual diet of black-lip pearl oysters Pinctada margaritifera in these lagoons is poorly known. To fill this gap, we used the flow through chamber method to measure clearance rates of P. margaritifera in Ahe atoll lagoon (Tuamotu Archipelago, French Polynesia). We found: (i) that pearl oysters cleared plankton at a rate that was positively related to plankton biovolume, (ii) that nanoflagellates were the main source of carbon for the pearl oysters, and (iii) that the quantity and origin of carbon filtrated by pearl oysters was highly dependent on the concentration and composition of plankton. These results provide essential elements for the comprehension of growth and reproduction variability of pearl oysters in atoll lagoons of French Polynesia.     

Recent work in magnetotelluric soundings of the lower crust and uppermost mantle

The technique of magnetotelluric sounding has been used for 25 years and a wealth of information has been obtained from regional studies. A table of results and an accompanying extensive bibliography was presented to the Murnau Workshop and this review discusses some aspects derived from the accumulated literature. In particular, the deep conducting layer (CCU) is considered.     

Magnesium correction to the NaKCa chemical geothermometer

Equations and graphs have been devised to correct for the adverse effects of magnesium upon the Na-K-Ca chemical geothermometer. Either the equations or graphs can be used to determine appropriate temperature corrections for given waters with calculated NaKCa temperatures > 70°C and R < 50, where $\text{R = {}\text{Mg}\text{(Mg + Ca + K)}\text{} × 100}$ with cation concentrations expressed in equivalents. Waters with R > 50 are probably derived from relatively cool aquifers with temperatures approximately equal to the measured spring temperature, irrespective of much higher calculated Na-K-Ca temperatures.