New formulae for estimating lava flow volumes at Mt. Etna Volcano, Sicily

 A new data set of Etna lava flows erupted since 1868 has been compiled from eight topographic maps of the volcano published at intervals since then. Volumes of 59 flows or groups of flows were measured from topographic difference maps. Most of these volumes are likely to be considerably more accurate than those published previously. We cut the number of flow volumes down to 25 by selecting those examples for which the volume of an individual eruption could be derived with the highest accuracy. This refined data set was searched for high correlations between flow volume and more directly measurable parameters. Only two parameters showed a correlation coefficient of 70% or greater: planimetric flow area A (70%) and duration of the eruption D (79%). If only short duration (<18 days) flows were used, flow length cubed, L³, had a correlation coefficient of 98%. Using combinations of measured parameters, much more significant correlations with volume were found. Dh had a correlation coefficient of 90% (h is the hydrostatic head of magma above the vent), and  , 92% (where W is mean width and E is the degree of topographic enclosure), and a combination of the two , 97%. These latter formulae were used to derive volumes of all eruptions back to 1868 to compare with those from the complete data set. Values determined from the formulae were, on average, lower by 16% (Dh), 7% (, and 19% . Received: 30 November 1998 / Accepted: 20 June 1999     

Digital Rectification Techniques for Architectural and Archaeological Presentation

Some exciting developments have been made recently, in the field of digital image rectification, which are of interest to both the photogrammetric specialist and non-specialist. This paper outlines the technical processes involved in generating digitally rectified images, as well as raising some of the issues that are becoming apparent when applying this modern technology to archaeological and architectural presentation.     

Thermodynamic properties,low-temperature heat-capacity anomalies,and single-crystal X-ray refinement of hydronium jarosite, (H<Subscript>3</Subscript>O)Fe<Subscript>3</Subscript>(SO<Subscript>4</Subscript>)<Subscript>2</Subscript>(OH)<Subscript>6</Subscript>

Crystals of hydronium jarosite were synthesized by hydrothermal treatment of Fe(III)–SO₄ solutions. Single-crystal XRD refinement with R₁=0.0232 for the unique observed reflections (|F_o| > 4_F) and wR₂=0.0451 for all data gave a=7.3559(8) Å, c=17.019(3) Å, V^o=160.11(4) cm³, and fractional positions for all atoms except the H in the H₃O groups. The chemical composition of this sample is described by the formula (H₃O)_0.91Fe_2.91(SO₄)₂[(OH)_5.64(H₂O)_0.18]. The enthalpy of formation (H^o_f) is –3694.5 ± 4.6 kJ mol^–1, calculated from acid (5.0 N HCl) solution calorimetry data for hydronium jarosite, -FeOOH, MgO, H₂O, and -MgSO₄. The entropy at standard temperature and pressure (S^o) is 438.9±0.7 J mol^–1 K^–1, calculated from adiabatic and semi-adiabatic calorimetry data. The heat capacity (C_p) data between 273 and 400 K were fitted to a Maier-Kelley polynomial C_p(T in K)=280.6 + 0.6149T–3199700T^–2. The Gibbs free energy of formation is –3162.2 ± 4.6 kJ mol^–1. Speciation and activity calculations for Fe(III)–SO₄ solutions show that these new thermodynamic data reproduce the results of solubility experiments with hydronium jarosite. A spin-glass freezing transition was manifested as a broad anomaly in the C_p data, and as a broad maximum in the zero-field-cooled magnetic susceptibility data at 16.5 K. Another anomaly in C_p, below 0.7 K, has been tentatively attributed to spin cluster tunneling. A set of thermodynamic values for an ideal composition end member (H₃O)Fe₃(SO₄)₂(OH)₆ was estimated: G^o_f= –3226.4 ± 4.6 kJ mol^–1, H^o_f=–3770.2 ± 4.6 kJ mol^–1, S^o=448.2 ± 0.7 J mol^–1 K^–1, C_p (T in K)=287.2 + 0.6281T–3286000T^–2 (between 273 and 400 K).     

Hydroclimatic variations over the last two glacial/interglacial cycles at Lake Urmia,Iran

A coarse-resolution, absolutely dated isotope record spanning the last 180 ka was constructed from aragonite-rich fecal pellets in a sediment core from Lake Urmia, Iran. The isotope record is not continuous as a consequence of detrital calcite that contaminates the pellets at certain depths. An isotopic correction was applied to samples > 50% aragonite, using the δ¹⁸O values of calcite-only pellets. Absolute dates were derived from U-Th analyses on pellets > 80% aragonite. The resultant δ¹⁸O record and sediment lithofacies confirm that the Penultimate Glacial was cold and dry, with pronounced interstadials at ca. 150 and >175 ka. Deglaciation began at ca. 130 ka, but climate was unstable and supported a probable no-analog vegetation assemblage. The onset of true interglacial conditions occurred at ca. 126 ka. Peak moisture conditions lasted for 5–6 ka before the climate became drier, with the loss of some tree taxa towards the end of the Last Interglacial. A period of greater moisture occurred between 116 and 108 ka, overlapping in timing with interstadial conditions recorded in the Soreq Cave speleothem record. In general, stadial to interstadial transitions (OIS 5d-5c, 5b-5a) are marked by decreasing δ¹⁸O values and rising lake levels. The nature of the OIS 5 to OIS 4 transition cannot be resolved in this study because of the loss of 5 m of core and imprecise dates. According to the present chronology, δ¹⁸O values, and inferred lake levels, arid conditions began at 60 ka and persisted until Termination I. Episodic increases in moisture, characterized by layers of aragonite-rich pellets, ostracodes, and the pollen of trees and/or aquatic plants, occurred during the Last Glacial. Deglaciation associated with the Late-glacial Interstadial began at 14 ka but was interrupted by a marked Younger Dryas event that resulted in renewed aridity. The Holocene began at approximately 10 ka. Despite large errors in the chronology, the overall timing and pattern of effective moisture matches the record from Soreq Cave, Israel, suggesting that the two regions were climatically in-phase.     

Fire and vegetation history during the last 3800 years in northwestern Montana

Foy Lake in northwestern Montana provides a record of annual-to-decadal-scale landscape change. Sedimentary charcoal and pollen analyses were used to document fire and vegetation changes over the last 3800 years, which were then compared to similar records from AD 1880 to 2000. The long-term record at Foy Lake suggests shifts between forest and steppe as well as changes in fire regime that are likely the result of climate change. Fire activity (inferred from the frequency of charcoal peaks) averaged 18 fire episodes/1000 years from 3800 to 2125 cal year BP, and increased from 16 fire episodes/1000 years at 2125 cal year BP to 22 episodes/1000 years at 750 cal year BP, a period when the pollen data suggest that steppe vegetation yielded to increasing patches of forest cover. Between 2125 and 750 cal year BP, increased forest cover produced more background charcoal than before and after this period, when vegetation was dominated by steppe. Between 750 and 75 cal year BP steppe has expanded and fire episode frequency averaged 33 episodes/1000 years, increasing to a maximum of 40 episodes/1000 years at ca. 300 cal year BP and then decreasing to present levels. Since AD 1880, the pollen record indicates an increase in shrubs and grasses from AD 1895 to 1960 as a result of vegetation changes associated with timber harvesting and livestock grazing. No fires have been documented in the Foy Lake watershed since AD 1880. Charcoal from the extralocal fires of AD 1910, burning over 4,111,249 ha in Idaho, Montana, and Wyoming, however, is present in Foy Lake. Between AD 1970 and 2000, increased arboreal pollen in the record is consistent with observations that the forest has become more closed. The activities of Euro–Americans have led to a decline in forest cover between AD 1880 and 1970, followed by a recent increase as trees are now growing in areas previously occupied by steppe. Euro–Americans are likely the cause of a reduction in fire activity in watershed since AD 1880.     

Seasonal controls on sediment transport and deposition in Lake Ohau,South Island,New Zealand: Implications for a high‐resolution Holocene palaeoclimate reconstruction

Laminated sediments in Lake Ohau, Mackenzie Basin, New Zealand, offer a potential high‐resolution climate record for the past 17 kyr. Such records are particularly important due to the relative paucity of detailed palaeoclimate data from the Southern Hemisphere mid‐latitudes. This paper presents outcomes of a study of the sedimentation processes of this temperate lake setting. Hydrometeorological, limnological and sedimentological data were collected over a 14 month period between 2011 and 2013. These data indicate that seasonality in the hydrometeorological system in combination with internal lake dynamics drives a distinct seasonal pattern of sediment dispersal and deposition on a basin‐wide scale. Sedimentary layers that accumulate proximal to the lake inflow at the northern end of the lake form in response to discrete inflow events throughout the year and display an event stratigraphy. In contrast, seasonal change in the lake system controls accumulation of light (winter) and dark (summer) laminations at the distal end of the lake, resulting in the preservation of varves. This study documents the key processes influencing sediment deposition throughout Lake Ohau and provides fundamental data for generating a high‐resolution palaeoclimate record from this temperate lake.     

Coordinated monitoring of the eccentric O-star binary Iota Orionis: optical spectroscopy and photometry

With the objective of investigating the windwind collision phenomenon and supporting contemporaneous X-ray observations, we have organized a large-scale, coordinated optical monitoring campaign of the massive, highly eccentric O9 III+B1 III binary Iota Orionis. Successfully separating the spectra of the components, we refine the orbital elements and confirm the rapid apsidal motion in the system. We also see strong interaction between the components during periastron passage and detect phase-locked variability in the spectrum of the secondary star. However, we find no unambiguous signs of the bow shock crashing on the surface of the secondary, despite the predictions of hydrodynamic simulations. Combining all available photometric data, we find rapid, phase-locked variations and model them numerically, thus restricting the orbital inclination to 50° i 70°.     

Interpretation of SOFIE PMC measurements: Cloud identification and derivation of mass density,particle shape,and particle size

The Solar Occultation For Ice Experiment (SOFIE) was launched onboard the Aeronomy of Ice in the Mesosphere (AIM) spacecraft to measure polar mesospheric clouds (PMCs) and their environment. This work describes methods for identifying PMCs in SOFIE observations and determining mass density, particle shape, particle effective radius, and the parameters of a Gaussian size distribution. Results using SOFIE measurements from the northern summer of 2007 are compared with concurrent observations by the ALOMAR lidar in northern Norway. Ice particle properties determined from SOFIE are in good agreement with the lidar results, considering the differences in instrument characteristics.     

A high‐resolution local RBF collocation method for steady‐state poroelasticity and hydromechanical damage analysis

In this work, we describe a meshless numerical method based on local collocation with RBFs for the solution of the poroelasticity equation. The RBF finite collocation approach forms a series of overlapping nodal stencils, over which an RBF collocation is performed. These local collocation systems enforce the governing PDE operator throughout their interior, with the intersystem communication occurring via the collocation of field variables at the stencil periphery. The method does not rely on a generalised finite differencing approach, whereby the governing partial differential operator is reconstructed at the global level to drive the solution of the PDE. Instead, the PDE governing and boundary operators are enforced directly within the local RBF collocation systems, and the sparse global assembly is formed by reconstructing the value of the field variables at the centrepoint of the local stencils. In this way, the solution of the PDE is driven entirely by the local RBF collocation, and the method more closely resembles the approach of the full‐domain RBF collocation method. By formulating the problem in this fashion, high rates of convergence may be attained without the computational cost and numerical ill‐conditioning issues that are associated with the full‐domain RBF collocation approach. An analytical solution is formulated for a 2D poroelastic fluid injection scenario and is used to verify the proposed implementation of the method. Highly accurate solutions are produced, and convergence rates in excess of sixth order are observed for each field variable (i.e. pressure and displacement) and field‐variable derivative (i.e. pressure gradients and stresses). The stress and displacement fields resulting from the solution of the poroelasticity equation are then used to describe the formation and propagation of microfractures and microfissures, which may form in the presence of large shear strain, in terms of a continuous damage variable which modifies the mechanical and hydraulic properties of the porous medium. The formation of such hydromechanical damage, and the resulting increase in hydraulic conductivity, is investigated for a pressurised injection into sandstone. Copyright © 2014 John Wiley & Sons, Ltd.