Evidence for high‐temperature fractionation of lithium isotopes during differentiation of the Moon

Lithium isotope and abundance data are reported for Apollo 15 and 17 mare basalts and the LaPaz low‐Ti mare basalt meteorites, along with lithium isotope data for carbonaceous, ordinary, and enstatite chondrites, and chondrules from the Allende CV3 meteorite. Apollo 15 low‐Ti mare basalts have lower Li contents and lower δ⁷Li (3.8 ± 1.2‰; all uncertainties are 2 standard deviations) than Apollo 17 high‐Ti mare basalts (δ⁷Li = 5.2 ± 1.2‰), with evolved LaPaz mare basalts having high Li contents, but similar low δ⁷Li (3.7 ± 0.5‰) to Apollo 15 mare basalts. In low‐Ti mare basalt 15555, the highest concentrations of Li occur in late‐stage tridymite (>20 ppm) and plagioclase (11 ± 3 ppm), with olivine (6.1 ± 3.8 ppm), pyroxene (4.2 ± 1.6 ppm), and ilmenite (0.8 ± 0.7 ppm) having lower Li concentrations. Values of δ⁷Li in low‐ and high‐Ti mare basalt sources broadly correlate negatively with ¹⁸O/¹⁶O and positively with ⁵⁶Fe/⁵⁴Fe (low‐Ti: δ⁷Li ≤4‰; δ⁵⁶Fe ≤0.04‰; δ¹⁸O ≥5.7‰; high‐Ti: δ⁷Li >6‰; δ⁵⁶Fe >0.18‰; δ¹⁸O <5.4‰). Lithium does not appear to have acted as a volatile element during planetary formation, with subequal Li contents in mare basalts compared with terrestrial, martian, or vestan basaltic rocks. Observed Li isotopic fractionations in mare basalts can potentially be explained through large‐degree, high‐temperature igneous differentiation of their source regions. Progressive magma ocean crystallization led to enrichment in Li and δ⁷Li in late‐stage liquids, probably as a consequence of preferential retention of ⁷Li and Li in the melt relative to crystallizing solids. Lithium isotopic fractionation has not been observed during extensive differentiation in terrestrial magmatic systems and may only be recognizable during extensive planetary magmatic differentiation under volatile‐poor conditions, as expected for the lunar magma ocean. Our new analyses of chondrites show that they have δ⁷Li ranging between ?2.5‰ and 4‰. The higher δ⁷Li in planetary basalts than in the compilation of chondrites (2.1 ± 1.3‰) demonstrates that differentiated planetary basalts are, on average, isotopically heavier than most chondrites.     

Input data resolution‐induced uncertainty in watershed modelling

The temporal‐spatial resolution of input data‐induced uncertainty in a watershed‐based water quality model, Hydrologic Simulation Program‐FORTRAN (HSPF), is investigated in this study. The temporal resolution‐induced uncertainty is described using the coefficient of variation (CV). The CV is found to decrease with decreasing temporal resolution and follow a log‐normal relation with time interval for temperature data while it exhibits a power‐law relation for rainfall data. The temporal‐scale uncertainties in the temperature and rainfall data follow a general extreme value distribution and a Weibull distribution, respectively. The Nash‐Sutcliffe coefficient (NSC) is employed to represent the spatial resolution induced uncertainty. The spatial resolution uncertainty in the dissolved oxygen and nitrate‐nitrogen concentrations simulated using HSPF is observed to follow a general extreme value distribution and a log‐normal distribution, respectively. The probability density functions (PDF) provide new insights into the effect of temporal‐scale and spatial resolution of input data on uncertainties involved in watershed modelling and total maximum daily load calculations. This study exhibits non‐symmetric distributions of uncertainty in water quality modelling, which simplify weather and water quality monitoring and reducing the cost involved in flow and water quality monitoring. Copyright © 2011 John Wiley & Sons, Ltd.     

Location,location, location: changes in the diversity of animal resources exploited by Tardiglacial humans in northern Spain

Prey diversity of Homo sapiens in north Iberia exhibited shifts associated with climate warming after the Last Glacial Maximum, as deduced from animal remains obtained from Upper Palaeolithic caves in Asturias (northern Spain). Significant association of prey diversity and river proximity was found during adverse climate conditions, indicating opportunistic predation. A high increase of prey diversity was found when small animals (including fish) were taken into account in archaeological records, highlighting the importance of this type of prey in Palaeolithic diets. Copyright © 2009 John Wiley & Sons, Ltd.     

Climate change influences on pollinator,forest, and farm interactions across a climate gradient

Improved cookstoves have been identified in Mexico as a key opportunity to advance sustainable local development priorities in disadvantaged regions while mitigating climate change. This paper reviews the Patsari Cookstove Project initiated in 2003 by an NGO, Interdisciplinary Group on Appropriate Rural Technology (GIRA). The project applied an interdisciplinary and participative user-centered approach to disseminate improved cookstoves in rural Mexico, with a special focus on indigenous and poor rural communities. To date, GIRA and the Patsari Network have disseminated thousands of stoves using a “training to trainers” model. Benefits from the project include tangible improvements in users’ health, as well as savings in time and money expended on fuelwood procurement and use. The project has also documented substantive environmental benefits from significant mitigation of greenhouse gas (GHG) emissions associated with traditional open fires. To sustain scaling up efforts over the long-term, two networks have been created: The Patsari Network, which includes several organizations promoting Patsari stoves for household users, and the Tsiri Network, which supports local food security and the empowerment of indigenous women through the promotion of institutional cookstoves. Through appropriately designed and implemented local interventions, the project demonstrates that the goals of advancing sustainable local development in rural areas and climate change mitigation may not be contradictory, and may in fact reinforce one another.     

Hard x-ray and Microwave Flux Spectra of the 2 November 1991 Solar Flare

We analysed the hard X-ray and microwave flux spectra of the solar flare (BATSE No. 1791) on 2 November 1991, which started at 16:11:03 UT and ended at 16:56:10 UT. This flare is particularly interesting because of its deep cyclic intensity modulation. Data are available simultaneously from the 16-channel BATSE/LAD hard X-ray and 45-frequency OVRO microwave database. We quantitatively compare the time variations in profiles of the hard X-ray spectral photon index, the 50 keV X-ray flux, and microwave spectral indices (at both high and low frequency ends). As expected, the X-ray photon spectral index decreases as the hard X-ray flux increases. This pattern appears in all the sub-peaks. This is consistent with previous observations that hard X-ray emission hardens at the emission peak. However, the behaviour of the high-frequency microwave index is unexpected. We observe an anti-correlation between the high-frequency microwave index and the hard X-ray photon index during the course of the flare. Finally, we study the arrival time of microwave flux peaks as a function of frequency and find that the microwave peak at a higher frequency comes earlier than that at a lower frequency. A maximum delay of 72 s is found among the main peaks at different frequencies. Shorter delays are found for the other five sub-peaks.     

On the ring current energy injection rate

Assuming that the formation of the ring current belt is a direct consequence of an enhanced crosstail electric field and hence of an enhanced convection, we calculate the total ring current kinetic energy (K_R) and the ring current energy injection rate (U_R) as a function of the cross-tail electric field (E_CT); the cross-tail electric field is assumed to have a step function-like increase. The loss of ring current particles due to recombination and charge-exchange is assumed to be distributed over the whole ring current region. It is found that: (1) the steady-state ring current energy K_R is approximately linearly proportional to E_CT; (2) the characteristic time t_c for K_R to reach the saturation level is 3–4 h; (3) the injection rate U_R is proportional to E_CT^β where β ? 1.33?1.52; and (4) the characteristic time t_p for U_R to reach the peak value is 1–2 h and the peak U_R value is 50% higher than the steady-state value. Since β is now determined specifically for an enhanced convection, an observational determination of the relationship between E_CT(or φ_CT) and U_R is essential to a better understanding of ring current formation processes. If the observed β is greater than 1.5, additional processes (e.g. an injection of heavy ions from the ionosphere to the plasma sheet and subsequently to the ring current region) may be required.     

A dynamo theory of solar flares

It is proposed that the solar flare phenomenon can be understood as a manifestation of the electrodynamic coupling process of the photosphere-chromosphere-corona system as a whole. The system is coupled by electric currents, flowing along (both upward and downward) and across the magnetic field lines, powered by the dynamo process driven by the neutral wind in the photosphere and the lower chromosphere. A self-consistent formulation of the proposed coupling system is given. It is shown in particular that the coupling system can generate and dissipate the power of 10²⁹ erg s^#X2212;1 and the total energy of 10³² erg during a typical life time (10³ s) of solar flares. The energy consumptions include Joule heat production, acceleration of current-carrying particles along field lines, magnetic energy storage and kinetic energy of plasma convection. The particle acceleration arises from the development of field-aligned potential drops of 10–150 kV due to the loss-cone constriction effect along the upward field-aligned currents, causing optical, X-ray and radio emissions. The total number of precipitating electrons during a flare is shown to be of order 10³⁷–10³⁸.