A field comparison of two methods for the determination of copper complexation: Bacterial bioassay and fixed-potential amperometry

Complexation of copper added to seawater was determined by bacterial bioassay and fixedpotential amperometry. Consistent results were obtained by these two fundamentally different methods. The results of this study support the validity of both techniques and the field applicability of fixed-potential amperometry.The intercomparison studies were performed on samples collected at the N.Y.C. sewage sludge dumpsite and in relatively unpolluted coastal waters. In this limited study, the calculated free cupric ion concentrations at ambient total copper concentrations were similar at both sites.     

Intercrystalline cation partitioning between minerals of the triplite-zwieselite-magniotriplite and the triphylite-lithiophilite series in granitic pegmatites

Minerals of the triphylite-lithiophilite, Li(Fe, Mn)PO₄, and the triplite-zwieselite-magniotriplite series, (Mn, Fe, Mg)₂PO₄F, occur in the late stage period of pegmatite evolution. Unfortunately, neither are the genetic relationships between these phosphates fully understood nor are thermodynamic data known. Consequently, phosphate associations and assemblages from 8 granitic pegmatites — Clementine II, Rubicon II and III, and Tsaobismund (Namibia); Hagendorf-Süd and Rabenstein (Germany); Valmy (France); Viitaniemi (Finland) — have been tested for compositional zoning and intercrystalline partitioning of main elements by electron microprobe techniques. Although the selected pegmatites display varying degrees of fractionation, and the intergrowth textures indicate different genetic relationships between the phosphates, the plots of mole fractions X _Fe=Fe/(Fe+Mn+Mg+Ca), X _Mn=Mn/(Fe+Mn+Mg+Ca), and X _Mg=Mg/(Fe+Mn+Mg+Ca) can be fitted relatively well with smooth curves in Roozeboom diagrams. Their deviations from symmetrical distribution curves are mainly dependent upon X _Mg or X _Ca, and upon non-ideal solutions. Surprisingly small differences between the partition coefficients were detected for intergrowths of different origin. However, the partitioning of shared components among coexisting phases is clearly dependent upon the conditions of formation. Compositional zoning is observed only when both Fe–Mn phosphates are intergrown mutually or with other Fe–Mn–Mg mineral solid-solutios. Thus, the zoning does not seem to be due to continuous crystallization, but to later diffusion processes. The triplite structure has preference for Mn, Mg, and Ca, while Fe prefers minerals of the triphylite series. A quantification of main element fractionation between minerals of the triphylite and the triplite series is possible in the cases where diffusion can be excluded. For the Fe/(Fe+Mn) ratios of core compositions an equation with a high correlation coefficient (R=0.988) was determined: Fe/(Fe+Mn)_Tr=[Fe/(Fe+Mn)_Li]/{2.737-(1.737)[Fe/(Fe+Mn)_Li]} (Tr=triplite series, Li=triphylite series). Consequently, the Fe/(Fe+Mn) ratio of the triplite series can now also be used in the interpretation of pegmatite evolution, just like that of the triphylite series which has been successfully applied in the past.     

Multispectral remote sensing of biomass burning in West Africa

Remote sensing measurements provide a vauable means of determining the extent of burning areas and of estimating the overall distribution of pollutant sources (identified from experimental studies) in time and space. This distribution has to be taken into account in the boundary conditions of chemistry atmospheric models.Recent methods developed for the remote sensing of active fires in tropical or temperated forest zones, have been found to be completely inadequate for fire detection on West African savannas. In order to accurately estimate the active fire distribution in the function of different sorts of West African savannas (Sahelian, Sudanian and Guinean) and forests, a multispectral methodology has been developed based on NOAA/11-AVHRR satellite data, with the purpose of eliminating as much as possible the problems related to large surface heterogeneity, confusion and bias, produced by clouds, smoke, haze, background emissivities, etc.Unlike other methods, the results show that the multispectral method, in spite of its selectivity, provides realistic results, and does not under- or over-estimate the number of fires that can be sensed by the satellite. Consequently, this methodology is more appropriate than the simplest ones for a systematic sensing of this phenomenon.     

Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.     

Remote sensing-modelisation approach for diurnal estimation of burnt biomass in the Central African Republic Savanna

Experimental studies and mesoscale modeling of atmospheric chemistry require a good knowledge of the sources of the atmospheric constituent, at a temporal scale of about one hour and at a spatial scale corresponding to the model grid. A combined remote sensing/modeling approach for the estimation of the diurnal distribution of the amount of biomass burning in Central African Republic (C.A.R.) savanna fires is proposed. The fire propagation model (BEHAVE) developed by Rothermel was adapted to the fuel characteristics encountered in C.A.R. Ground and airborne measurements with satellite images (NOAA/AVHRR) were used to predict an accurate estimate of the burnt biomass. This combination allows the calculation of the distribution of the number of fires during the day providing an evaluation of the instantaneous fluxes of the compounds emitted in the atmosphere by these fires.     

Numerical analyses of deformability tests in jointed rock — “Joint Perturbation” and “No Tension” Finite Element solutions

SummaryNumerical Analyses of Deformability Tests in Jointed Rock — Joint Perturbation and No Tension Finite Element Solutions Sound design of structures in or upon rock requires a thorough knowledge of the rock mass deformability. Field test data interpretation has generally relied upon analytical or Finite Element linear elastic solutions. However, when testing in jointed rock, these can no longer be readily used since the medium cannot resist the tension induced upon loading. Accordingly, other solutions are required. If the discontinuities of the rock mass can all be mapped and their surface properties determined, the Finite Element model will use a Joint Perturbation solution where the joint elements have variable stiffnesses to account for movements along the fractures. If the discontinuities cannot be satisfactorily mapped, a global approach is provided by a No Tension analysis of the stress transfer type. The two techniques are compared in the case of bore hole jack deformability tests and found to agree remarkably well, indicating an appreciable difference from results of linear elasticity.

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ZusammenfassungNumerische Analyse von Verformungsversuchen in geklüfteten Fels — Lösungen mittels Kluft-Perturbation und No Tension Analysis auf Grund der Methode der Finiten Elemente Der Entwurf von Bauwerken in oder auf Fels erfordert eine genaue Kenntnis des Formänderungsverhaltens der Felsmasse. Im allgemeinen basiert die Interpretation der Ergebnisse von Feldversuchen auf den Lösungen des zugehörigen Randwertproblems der linearen Elastostatik mittels klassischer analytischer Methoden oder der Methode der Finiten Elemente. Wenn die Versuche aber in geklüftetem Fels durchgeführt werden, müssen die theoretischen Methoden modifiziert werden, da das Medium keine Zugspannungen aufnehmen kann. Zwei Fälle können unterschieden werden. Erstens: die Kluftflächen der Felsmasse können geometrisch erfaßt und ihre Oberflächeneigenschaften können bestimmt werden; in diesem Falle kann die Finite-Elemente-Lösung eine Kluft-Perturbations-Methode verwenden, in welcher spezielle Kluft-Elemente verschiedener Steifigkeiten normal und tangential zu den Kluftflächen die Bewegungen entlang derselben bestimmen. Zweitens: die Diskontinuitäten der Felsmasse können nicht hinreichend beschrieben werden; für diesen Fall ist vorgekehrt durch die Finite-Element-Analyse vom Typ der Spannungsumlagerung unter Ausschaltung der Zugspannungen (No Tension Analysis), um das globale Verhalten der geklüfteten Felsmasse zu erfassen. Die Lösungen dieser beiden Methoden wurden für den Fall der Bohrloch-Verformungs-Tests verglichen; der Vergleich zeigt ausgezeichnete Übereinstimmung, im Gegensatz zu den Lösungen als lineares Elastizitätsproblem.

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RésuméLa méthode des Eléments Finis appliquée aux résultats d'essais de vérins cylindriques dans les roches fissurées — solutions dites Joint Pertubé et Sans Traction La construction de structures sur ou dans des roches nécessite une connaissance approfendie de la déformabilité du massif rocheux. L'analyse des résultats d'essais en place se fait généralement à l'aide de solutions analytiques ou par Eléments Finis, qui supposent une élasticité linéaire du milieu. De fait, dans les roches fissurées, ces solutions sont inadéquates puisque le milieu ne peut résister aux sollicitations de traction. Il s'agit donc d'utiliser d'autres méthodes d'analyse. Lors qu'il est possible de déterminer la géométrie et les propriétés de toutes les discontinuités, l'on pourra utiliser une solution par Eléments Finis, dite Joint Perturbé dans laquelle la rigidité de surface du joint (ou fissure) peut varier lorsque des movements prennent place au niveau du joint. Si cela est impossible, il faudra utiliser une approche globale dite Sans Traction qui redistribue les contraintes de traction et les dissipe. On compare ces deux types de solutions dans le cas des essais de vérins cylindriques unidirectionnels. Leurs résultats sont identiques et ont nettement différents de ceux obtenus avec une solution élastique linéaire.

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Research supported by the National Aeronautics and Space Administration — Contract NAS 8-21432.

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With 8 Figures     

Détermination des coefficients de diffusion verticale entre 0 ET 100 M a l'aide du radon et du ThB

Résumé Le radon (Rn₈₆ ²²²) et les descendants du thoron (ThB ou Pb₈₂ ²¹²) sont utilisés comme traceurs pour l'étude des échanges verticaux de matière. Diverses méthodes permettant le calcul des coefficients de diffusion sont présentées soit dans l'hypothèse simplificatrice du régime stationnaire, soit dans le cas plus général du régime dépendant du temps. L'application de ces méthodes au calcul des coefficients de diffusion sur des données fournies à partir d'un modèle de simulation numérique permet de préciser le degré d'approximation représenté par les diverses hypothèses simplificatrices. Les méthodes de calcul présentées sont appliquées aux mesures expérimentales du radon et du ThB. Ces mesures ont été réalisées de manière continue durant deux ans en trois points de mesures, entre 0 et 100 m de hauteur. Une statistique est présentée sur la variation diurne des échanges et la variation saisonnière de cette variation diurne, ainsi qu'un exemple particulier du traitement des données en régime dépendant du temps.

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Continuous measurements of the concentrations of radon and thorium B have been carried out at 3 levels (1.5, 30 and 100 m) during a period of 2 yr (from October 1966 to October 1968) at the site of the future airport of Paris, at Roissy-en-France; at the same time, standard meteorological elements have been measured at the station by the Météorologie Nationale and the vertical gradients (wind and temperature profiles in the first 100 m) by J. Saissac. The work has been undertaken in order to determine the vertical exchange of matter near the ground.The computation of the exchange coefficients has been carried out by using the standard diffusion equation (K theory). The results in the literature as well as statistical analysis of our data lead us to believe that the flux of Rn and ThB at the ground can be considered as horizontally homogeneous in the neighbourhood of the measurement site (the soil is geologically homogeneous over a large area). The differential equation is thus simplified, containing only one space parameter (z), and timet.In this paper we describe the principal computation methods used for determining the exchange coefficients from the measurement of the vertical gradients of tracers. In order to illustrate the approximation errors and fields of applicability of different methods, we have applied them to the data provided from a numerical integration of the diffusion equation, in which one can introduce any profile of diffusivity.We show that during stable periods, the value of the flux of Rn or ThB can be determined forz = 0.Generally, during daylight hours when the motion near the ground is strongly turbulent, the vertical gradient of concentration is not measurable with sufficient accuracy.The daytime diffusion coefficient is therefore not computed by the general methods presented above. This deficiency can be overcome by assuming that the ratio between the mean concentration observed during these periods and the value of the flux at ground level are characteristic of the whole mixing layer. The values of the exchange coefficients obtained by this method are included and range from 5 to 30 m²s^-1.The application of the proposed methods to the experimental results has been made for two atmospheric states. Firstly, we have used a simplified method (stationary state) which is applied to the whole experimental data set. We present the diurnal variation, the most probable value of the diffusion coefficients and the seasonal evolution. The values obtained from Rn and ThB measurements have been compared.

     

Seeing Conditions at Sutherland. Results of the 1992/93 seeing campaign

In order to decide whether the seeing conditions at SAAO/Sutherland justify the erection of a 3.5 m telescope and also to compare Sutherland with the Gamsberg/Namibia site, a seeing campaign covering 15 months has been carried out. For direct comparison with the results of the seeing campaign at Gamsberg twenty years before the same QUESTAR telescope was employed. The seeing is determined by the scattering of the star-trail exposed on a film in the focal plane of the telescope. The campaign commenced in February 1992. Up to May 1993, data for 204 nights, that is 47.3% of the total number of nights, were collected. Due to wind speeds above 30 km h^-1, 25 out of the 204 nights were not considered in the final reduction. The useful 179 nights are evenly distributed over the campaign period. The median seeing value for the whole period is = 0.52. There are differences during the year: the best season gives = 0.42, the worst = 0.67. Each night was divided into three intervals, although data for each of the three intervals were not always available. Generally, there is an improvement in the seeing during the course of a night. The results are compared to the seeing values of Gamsberg/Namibia and ESO/La Silla.     

Flexible Automatic Scheduling for Autonomous Telescopes: The MAJORDOME

We have developped a new method for the scheduling ofastronomical automatic telescopes, in the framework of theautonomous TAROT instrument. The MAJORDOME software canhandle a variety of observations, constrained, periodic,etc., and produces a timeline for the night, which may bemodified at any time to take into account the specificconditions of the night. The MAJORDOME can also handletarget of opportunity observations without delay.     

Finite element models for rock fracture mechanics

A finite element model for the prediction of discrete fracture propagation in rock structures loaded in compression is presented. The model integrates any one of three theories for mixed-mode fracture initiation; it contains an energy balance algorithm for predicting crack increment length, and incorporates recent developments in finite element stress-intensity factor computation. The predictions of the model are compared with the observed fracture response of a real rock structure. Results show that the model accurately predicts both stable and unstable fracture progagations observed experimentally.