Geochemical evaluation of Niger Delta sedimentary organic rocks: a new insight

A geochemical evaluation of Niger Delta organic matter was carried out using supercritical fluid extraction (SFE) sample preparation procedure. Comparison of geochemical significance of gas chromatographic data of rock extracts of SFE with those of Soxhlet extraction method from previous studies was made in order to establish the usefulness of SFE in geochemical exploration. The assessment of geochemical character of the rock samples from the comparison and interpretation of other geochemical parameters were used to give more insights into understanding the source rocks characteristics of onshore and shelf portions of the Niger Delta Basin. The results of the gas chromatographic (GC) analysis of the rock extracts across the lithostratigraphic units show that Pr/Ph, Pr/nC₁₇, Pr/nC₁₈, CPI and odd/even preference ranged from 0.07 to 12.39, 0.04 to 6.66, 0.05 to 13.80, 0.12 to 8.4 and 0.06 to 8.12, respectively. The Rock-Eval pyrolysis data and geochemical ratios and parameters calculated from the GC data showed that most of the samples are mature and have strong terrestrial provenance while a few samples have strong marine provenance. The few marine source rocks are located in the deeper depth horizon. Pr/Ph and standard geochemical plots indicate that most of samples were derived from organic matter deposited in less reducing conditions, i.e. more of oxidizing conditions while a few samples have predominantly influence of reducing conditions. The results of trace metal analysis of older samples from Agbada Formation also indicate marine and mixed organic matter input deposited in less reducing conditions. The results obtained in this study are comparable with those obtained from previous studies when Soxhlet extraction method was used and also indicated the presence of more than one petroleum systems in the Niger Delta.     

Estimating the geostrophic velocity obtained by HF radar observations in the upstream area of the Kuroshio

A method to extract geostrophic current in the daily mean HF radar data in the Kuroshio upstream region is established by comparison with geostrophic velocity determined from the along-track altimetry data. The estimated Ekman current in the HF velocity is 1.2% (1.5%) and 48° (38°)-clockwise rotated with respect to the daily mean wind in (outside) the Kuroshio. Furthermore, additional temporal smoothing is found necessary to remove residual ageostrophic currents such as the inertial oscillation. After removal of the ageostrophic components, the HF geostrophic velocity agrees well with that from the altimetry data with rms difference 0.14 (0.12) m/s in (outside) the Kuroshio.     

A Multiple Flare Scenario where the Classic Long-Duration Flare Was Not the Source of a CME

A series of flares (GOES class M, M and C) and a CME were observed in close succession on 20 January 2004 in NOAA 10540. Radio observations, which took the form of types II, III and N bursts, were associated with these events. We use the combined observations from TRACE, EIT, Hα images from Kwasan, MDI magnetograms and GOES to understand the complex development of this event. Contrary to a standard interpretation, we conclude that the first two impulsive flares are part of the CME launch process while the following long-duration event flare represents simply the recovery phase. Observations show that the flare ribbons not only separate but also shift along the magnetic inversion line so that magnetic reconnection progresses stepwise to neighboring flux tubes. We conclude that “tether cutting” reconnection in the sheared arcade progressively transforms it to a twisted flux tube, which becomes unstable, leading to a CME. We interpret the third flare, a long-duration event, as a combination of the classical two-ribbon flare with the relaxation process following forced reconnection between the expanding CME structure and neighboring magnetic fields. Electronic Supplementary Material  The online version of this article () contains supplementary material, which is available to authorized users.     

Output-only identification of the modal and physical properties of structures using free vibration response

The viability of a complete structural characterization of civil structures is explored and discussed. In particular, the identification of modal (i.e. natural frequencies, damping ratios and modal shapes) and physical properties (i.e. mass and stiffness) using only the structure’s free decay response is studied. To accomplish this, modal analysis from free vibration response only (MAFVRO) and mass modification (MM) methodologies are engaged along with Wavelet based techniques for optimal signal processing and modal reconstruction. The methodologies are evaluated using simulated and experimental data. The simulated data are extracted from a simple elastic model of a 5 story shear building and from a more realistic nonlinear model of a RC frame structure. The experimental data are gathered from shake table test of a 2-story scaled shear building. Guidelines for the reconstruction procedure from the data are proposed as the quality of the identified properties is shown to be governed by adequate selection of the frequency bands and optimal modal shape reconstruction. Moreover, in cases where the structure has undergone damage, the proposed identification scheme can also be applied for preliminary assessment of structural health.     

A contrast of two typical LUCC processes and their driving forces in oases of arid areas: A case study of Sangong River Watershed at the northern foot of Tianshan Mountains

Aerial photographs taken in 1978 and 1987, Landsat TM images in 1998 as well as soil, hydrology and socio-economic data for the oases in Sangong River Watershed were processed by Remote Sensing (RS) and Geographic Information System (GIS). There are two typical agricultural land uses in oases, Farm-based Land Use with large-scale intensified agricultural activities (FLU) and Household Responsibility-based Land Use with small-scale activities (HRLU). The Index Model of Land Use/Land Cover Change (LUCC), Weighted Index Sum (WIS) and logistic stepwise regression model were established to contrast the two typical LUCC processes and their driving forces. The land use patterns were dominated by cropland and grassland for the entire region, and cropland, residential and industrial land were increasing stably. In the HRLU areas, woodland and grassland declined dramatically, but in the FLU areas, grassland decreased only by 12.0%, whereas woodland increased by 13.7%. LUCC was stronger in the earlier stage (1978–1987) than in the later stage (1987–1998) for the entire region. LUCC was more intense in the HRLU areas than in the FLU areas during the entire period (1978–1998). Policy was a key factor in the land use change, and water resources were a precondition in land use. Under the control of policy and water resources, the main human driving factors included population and economy, and the main natural restrictions were soil fertility and groundwater depth. Human driving factors controlled the land change in the HRLU areas, but natural restriction factors dominated in the FLU areas. In the mean time, intensification of LUCC in the region had some spatiotemporal implications with a fluctuation of impact factors.     

Soil and Vegetation Spectral Coupling Difference (SVSCD) for Minerals Extraction from Hyperion Data in Vegetation Covered Area

Remote sensing data have been widely applied to extract minerals in geologic exploration, however, in areas covered by vegetation, extracted mineral information has mostly been small targets bearing little information. In this paper, we present a new method for mineral extraction aimed at solving the difficulty of mineral identification in vegetation covered areas. The method selected six sets of spectral difference coupling between soil and plant (SVSCD). These sets have the same vegetation spectra reflectance and a maximum different reflectance of soil and mineral spectra from Hyperion image based on spectral reflectance characteristics of measured spectra. The central wavelengths of the six, selected band pairs were 2314 and 701 nm, 1699 and 721 nm, 1336 and 742 nm, 2203 and 681 nm, 2183 and 671 nm, and 2072 and 548 nm. Each data set’s reflectance was used to calculate the difference value. After band difference calculation, vegetation information was suppressed and mineral abnormal information was enhanced compared to the scatter plot of original band. Six spectral difference couplings, after vegetation inhibition, were arranged in a new data set that requires two components that have the largest eigenvalue difference from principal component analysis (PCA). The spatial geometric structure features of PC1 and PC2 was used to identify altered minerals by spectral feature fitting (SFF). The collecting rocks from the 10 points that were selected in the concentration of mineral extraction were analyzed under a high-resolution microscope to identify metal minerals and nonmetallic minerals. Results indicated that the extracted minerals were well matched with the verified samples, especially with the sample 2, 4, 5 and 8. It demonstrated that the method can effectively detect altered minerals in vegetation covered area in Hyperion image.     

Simplification and Validation of a Spectral-Tensor Model for Turbulence Including Atmospheric Stability

A spectral-tensor model of non-neutral, atmospheric-boundary-layer turbulence is evaluated using Eulerian statistics from single-point measurements of the wind speed and temperature at heights up to 100 m, assuming constant vertical gradients of mean wind speed and temperature. The model has been previously described in terms of the dissipation rate \(\epsilon \), the length scale of energy-containing eddies \(\mathcal {L}\), a turbulence anisotropy parameter \(\varGamma \), the Richardson number Ri, and the normalized rate of destruction of temperature variance \(\eta _\theta \equiv \epsilon _\theta /\epsilon \). Here, the latter two parameters are collapsed into a single atmospheric stability parameter z / L using Monin–Obukhov similarity theory, where z is the height above the Earth’s surface, and L is the Obukhov length corresponding to \(\{Ri,\eta _\theta \}\). Model outputs of the one-dimensional velocity spectra, as well as cospectra of the streamwise and/or vertical velocity components, and/or temperature, and cross-spectra for the spatial separation of all three velocity components and temperature, are compared with measurements. As a function of the four model parameters, spectra and cospectra are reproduced quite well, but horizontal temperature fluxes are slightly underestimated in stable conditions. In moderately unstable stratification, our model reproduces spectra only up to a scale \(\sim \) 1 km. The model also overestimates coherences for vertical separations, but is less severe in unstable than in stable cases.     

Undrained creep failure of a drainage canal slope stabilized with deep cement mixing columns

This paper presents an analysis of the slope failure of a Suvarnabhumi drainage canal during construction. The Suvarnabhumi drainage canal project includes a large drainage canal with a road on both sides. The width of the bottom of the drainage canal is 48.0 m, the depth of the drainage canal is 3.0 m, and the length of the drainage canal is 10.5 km. Because the project was constructed on very soft Bangkok clay, deep cement mixing (DCM) columns were employed to increase the stability of the excavated canal. The failure of the drainage canal slope occurred 25 days after the end of excavation. The field monitoring data show that lateral movement of the canal slope continuously increased with time, which caused failure due to the instability of the canal slope. The time-dependent deformation and undrained creep behavior of very soft clay was suspected to be the cause of the canal failure. A laboratory investigation of undrained creep behavior and a finite element analysis (FEA) using the soft soil creep (SSC) model were performed to confirm the causes of the canal failure. The results indicate that very soft clay specimens that are subjected to deviator creep stress levels of 70 and 100 % of the peak strength failed by creep rupture within 60 days and 8 min, respectively. The factor of safety for the canal slope, which was obtained from the FEA, shows significant reduction from the initial value of 1.710 to 1.045 within 24 days after the end of excavation due to the effect of undrained creep. This paper also describes a solution method that is applied to a new section of the canal. Field monitoring and an FEA of the new trial section were performed to prove the effectiveness of the solution method.