Climate change in lowland Central America during the late deglacial and early Holocene

The transition from arid glacial to moist early Holocene conditions represented a profound change in northern lowland Neotropical climate. Here we report a detailed record of changes in moisture availability during the latter part of this transition (～11 250 to 7500 cal. yr BP) inferred from sediment cores retrieved in Lake Petén Itzá, northern Guatemala. Pollen assemblages demonstrate that a mesic forest had been largely established by ～11 250 cal. yr BP, but sediment properties indicate that lake level was more than 35 m below modern stage. From 11 250 to 10 350 cal. yr BP, during the Preboreal period, lithologic changes in sediments from deep‐water cores (>50 m below modern water level) indicate several wet–dry cycles that suggest distinct changes in effective moisture. Four dry events (designated PBE1‐4) occurred centred at 11 200, 10 900, 10 700 and 10 400 cal. yr BP and correlate with similar variability observed in the Cariaco Basin titanium record and glacial meltwater pulses into the Gulf of Mexico. After 10 350 cal. yr BP, multiple sediment proxies suggest a shift to a more persistently moist early Holocene climate. Comparison of results from Lake Petén Itzá with other records from the circum‐Caribbean demonstrates a coherent climate response during the entire span of our record. Furthermore, lowland Neotropical climate during the late deglacial and early Holocene period appears to be tightly linked to climate change in the high‐latitude North Atlantic. We speculate that the observed changes in lowland Neotropical precipitation were related to the intensity of the annual cycle and associated displacements in the mean latitudinal position of the Intertropical Convergence Zone and Azores–Bermuda high‐pressure system. This mechanism operated on millennial‐to‐submillennial timescales and may have responded to changes in solar radiation, glacial meltwater, North Atlantic sea ice, and the Atlantic meridional overturning circulation (MOC). Copyright © 2005 John Wiley & Sons, Ltd.     

Multiscale characterization and modeling of granular materials through a computational mechanics avatar: a case study with experiment

Through a first-generation computational mechanics avatar that directly links advanced X-ray computed tomographic experimental techniques to a discrete computational model, we present a case study where we made the first attempt to characterize and model the grain-scale response inside the shear band of a real specimen of Caicos ooids subjected to triaxial compression. The avatar has enabled, for the first time, the transition from faithful representation of grain morphologies in X-ray tomograms of granular media to a morphologically accurate discrete computational model. Grain-scale information is extracted and upscaled into a continuum finite element model through a hierarchical multiscale scheme, and the onset and evolution of a persistent shear band is modeled, showing excellent quantitative agreement with experiment in terms of both grain-scale and continuum responses in the post-bifurcation regime. More importantly, consistency in results across characterization, discrete analysis and continuum response from multiscale calculations are found, achieving the first and long sought-after quantitative breakthrough in grain-scale analysis of real granular materials.     

Structure and properties of the Adriatic crust in the central‐eastern Southern Alps (Italy) from local earthquake tomography

Structure and properties of the Adriatic crust were determined from local earthquake tomography around the Giudicarie fault zone (central‐eastern Southern Alps, Italy). Tomographic results, based on well‐suited 436 revised earthquakes (period 1994–2007), have a resolution comparable to the scale of regional geological domains and tectonic structures. The observed strong velocity anomalies correlate well with lithological variations corresponding to different geological domains (particularly magmatic complexes at depth) and with high fracturing and/or presence of fluids along active fault systems (South Giudicarie and Valsugana–Bassano del Grappa–Montello thrusts).     

The effect of different intensity measures and earthquake directions on the seismic assessment of skewed highway bridges

In this study the probable seismic behavior of skewed bridges with continuous decks under earthquake excitations from different directions is investigated.A 45° skewed bridge is studied.A suite of 20 records is used to perform an Incremental Dynamic Analysis(IDA) for fragility curves.Four different earthquake directions have been considered:-45°, 0°, 22.5°, 45°.A sensitivity analysis on different spectral intensity measures is presented; efficiency and practicality of different intensity measures have been studied.The fragility curves obtained indicate that the critical direction for skewed bridges is the skew direction as well as the longitudinal direction.The study shows the importance of finding the most critical earthquake in understanding and predicting the behavior of skewed bridges.     

A new macromodel for the assessment of the seismic response of infilled RC frames

Numerous research studies have proved that numerical models aiming at an accurate evaluation of the seismic response of RC framed buildings cannot ignore the inelastic behaviour of infills and the interaction between infill and frame elements. To limit the high computational burden of refined non-linear finite element models, in the latest decades, many researchers have developed simplified infill models by means of single or multiple strut-elements. These models are low time-consuming and thus adequate for static and dynamic analyses of multi-storey structures. However, their simulation of the seismic response is sometimes unsatisfying, particularly in the presence of infill walls with regular or (particularly) irregular distributions of openings. This paper presents a new 2D plane macro-element, which provides a refined simulation of the non-linear cyclic response of infilled framed structures at the expense of a limited computational cost. The macro-element consists of an articulated quadrilateral panel, a single 1D diagonal link, and eight 2D links and is able to model the shear and flexural behaviour of the infill and the non-linear flexural/sliding interaction between infill and surrounding frame. The proposed macro-element has been implemented into the open source software OpenSees and used to simulate the response of single-storey, single-span RC infilled frame prototypes tested by other authors. The above prototypes are selected as made of different masonry units and characterised by full or open geometric configuration.     

Detection of HCO+ towards Cygnus OB2 No. 12

HCO⁺ has been detected for the first time towards the star Cygnus OB2 No. 12 through emission of the 1–0 rotational transition at 89 GHz. The CO( J =2−1) transition has also been observed. The observations are consistent with a model of dense regions embedded in a low-density clump gas. If actually present, the dense component would have an aggregate size L 1300 au, in agreement with estimates of small-scale density fluctuations observed along diffuse lines of sight.     

Chemical characteristics of groundwater around two massive sulphide deposits in an area of previous mining contamination, Iberian Pyrite Belt, Spain

A detailed chemical study of groundwater was carried out to elucidate the processes controlling the oxidation and dissolution of sulphide minerals at two massive sulphide deposits in the Iberian Pyrite Belt (IPB), i.e. the mined La Zarza deposit and the unmined Masa Valverde deposit. It was found that major-element compositions varied according to the hydrological regime, La Zarza being in a relatively high area with groundwater recharge (and disturbance due to the human factor) and Masa Valverde being in a relatively low area with groundwater discharge. The variations mainly concern pH, Eh, SO₄ and Na concentrations. Metal concentrations were determined (a) by ICP-MS after filtration, and (b) in some cases by voltammetric measurement of Cu, Pb, Zn, Cd and Mn using the Voltammetric In situ Profiling (VIP) System, which allows detection of only the mobile fractions of trace elements (i.e., free metal ions and small labile complexes a few nanometers in size). If one compares the results obtained by each of the two methods, it would appear that the groundwater shows significant enhancement of metal solubility through complexing with organic matter and/or adsorption onto colloids and/or small particles. In areas of sulphide oxidation, however, this solubility enhancement decreases according to Cu>Zn>Cd>Pb. Under very low redox conditions, the attained metal concentrations can be several orders of magnitude (up to 10⁸–10⁹ for Cu and 10²–10³ for Pb) larger than those expected from equilibrium with respect to sulphide minerals as calculated with the EQ3NR geochemical code; Zn concentrations, however, are close to equilibrium with respect to sphalerite. The implication of these results is discussed with respect both to mineral exploration and to environmental issues.