Deglaciation and proglacial lakes

Glaciers and ice sheets are important constituents of the Earth's land surface. Current worldwide retreat of glaciers has implications for the environment and for civilisation. There are a range of geomorphic changes occurring in cold environments and it is anticipated that these will be accentuated as a consequence of climate change. In particular, the number and size of proglacial lakes is currently increasing as a result of deglaciation and their significance for the physical environment and for society is becoming increasingly apparent. This article provides an overview of the major interdependent relationships between climate change, glaciers and proglacial lake development. In particular, it describes the key processes and impacts associated with proglacial lake evolution with reference to examples drawn from the European Alps, North America, the Himalayas, the Andes, Greenland, New Zealand and Iceland.     

Thermal equation of state of CaIrO<Subscript>3</Subscript> post-perovskite

The pressure–volume–temperature (P–V–T) relation of CaIrO₃ post-perovskite (ppv) was measured at pressures and temperatures up to 8.6 GPa and 1,273 K, respectively, with energy-dispersive synchrotron X-ray diffraction using a DIA-type, cubic-anvil apparatus (SAM85). Unit-cell dimensions were derived from the Le Bail full profile refinement technique, and the results were fitted using the third-order Birth-Murnaghan equation of state. The derived bulk modulus \( K_{T0} \) at ambient pressure and temperature is 168.3 ± 7.1 GPa with a pressure derivative \( K_{T0}^{\prime } \) = 5.4 ± 0.7. All of the high temperature data, combined with previous experimental data, are fitted using the high-temperature Birch-Murnaghan equation of state, the thermal pressure approach, and the Mie-Grüneisen-Debye formalism. The refined thermoelastic parameters for CaIrO₃ ppv are: temperature derivative of bulk modulus \( (\partial K_{T} /\partial T)_{P} \) = ?0.038 ± 0.011 GPa K^?1, \( \alpha K_{T} \) = 0.0039 ± 0.0001 GPa K^?1, \( \left( {\partial K_{T} /\partial T} \right)_{V} \) = ?0.012 ± 0.002 GPa K^?1, and \( \left( {\partial^{2} P/\partial T^{2} } \right)_{V} \) = 1.9 ± 0.3 × 10^?6 GPa² K^?2. Using the Mie-Grüneisen-Debye formalism, we obtain Grüneisen parameter \( \gamma_{0} \) = 0.92 ± 0.01 and its volume dependence q = 3.4 ± 0.6. The systematic variation of bulk moduli for several oxide post-perovskites can be described approximately by the relationship K _T0  = 5406.0/V(molar) + 5.9 GPa.     

Isotopic measurements in the Cape York Peninsula area,North Qeensland

K‐Ar and Rb‐Sr isotopic measurements have been made on the north‐south belt of igneous and metamorphic rocks from the Peninsula Ridge and Yambo Inlier of Cape York Peninsula. Four periods of Palaeozoic igneous activity appear to have been denned. These are (⁸⁷’Rb^λ = 1.39 X 10^–11y–1) about 415 m.y., about 400 m.y., 385–390 m.y., and 255–280 m.y., with the youngest dates to the north and northeast. The largest volume of magma, the Kintore Adamellite was emplaced during the 285–390 m.y. period. Initial ⁸⁷Sr/⁸⁶Sr ratios range from 0.715 (a granodiorite) through 0.72–0.74 (muscovite adamellite) to 0.76 (leuco‐adamellite), which suggests a high component of old crustal material in the latter types.

The host metamorphics grade from greenschist facies in the west to almandine‐amphibolite facies in the centre and south. Limited direct data suggest that the greenschists are older than 1400 m.y. This is supported by intrusive dolerite dating greater than 1800 m.y. Rocks possibly 2000 m.y. old are thus adjacent to the Australian northeast coast and place drastic limitations on the possibility of continual continental growth to the east.

Rb/Sr measurements on minerals of the almandine amphibolite rocks record the major Kintore event. Total rock measurements have high uncertainties but give only slightly older figures. Initial ⁸⁷Sr/⁸⁶Sr ratios of these apparent total rock isochrons are high, 0.735–0.745. Gross isotopic redistribution must have occurred during the Palaeozoic metamorphism.

The Rb/Sr isotopic and geochemical relationships suggest that some of the granitic rocks have been derived from the equivalent of the present greenschist facies suite, and that the almandine amphibolite facies was, in part, remetamorphosed during the Palaeozoic and is possibly partly residual after metamorphic segregation.

The region has been examined from the plate tectonic point of view and shows that many of the requirements of a cordilleran‐type mountain belt of Dewey & Bird (1970) existed during the mid‐upper Palaeozoic. The Palmerville Fault and the Hodgkinson Basin are key units in this interpretation.

Dolerite, possibly 2000 m.y. old, could be contemporaneous with voluminous dolerites of similar age from the Kimberley region (Australia) and of Venezuela and Guyana. They may be a useful continental breakup indicator, as are the Gondwana dolerites.     

Secular variations in seawater chemistry controlling dolomitization in shallow reflux systems: insights from reactive transport modelling

Dolomitization often plays a critical role in the pore network development of platform carbonates, with implications for reservoir quality distribution. Understanding both the hydrological system driving dolomitization and the chemistry of the fluids involved is fundamental to constrain predictions of the geometry and the petrophysical properties of dolomite bodies. Here, the role of secular variations in seawater Mg/Ca as a control on dolomitization and early porosity modification was evaluated using one‐dimensional reactive transport models and fluids based on modern (aragonite sea), Mississippian and Aptian (calcite sea) seawaters. The sensitivity of dolomitization to a range of extrinsic controls (brine salinity, temperature, fluid flow rate and pCO₂) and to intrinsic reactivity of the sediments (effective reactive surface area) was also explored. Simulations suggest faster calcite replacement by dolomite for seawaters with higher Mg/Ca, indicating that dolomitization potential is determined more by Mg/Ca rather than saturation index. Increasing evaporative concentration enhances reaction rate independent of the effect of enhanced density‐driven fluid flux. In addition to brine composition, effective surface area of precursor sediments and temperature exert a critical control on replacement rate, while secular variations of pH and carbonate alkalinity associated with changes in pCO₂ are only secondary controls. Above flow rates of 0·01 m yr^?1 replacive dolomitization is reaction‐limited rather than flux limited, favouring alteration of fine‐grained carbonates and suggesting that preferential alteration of grainstone units is rare unless head gradients are low. Post‐replacement dolomite cementation is flux dependent, and thus favoured in areas of high head gradient and high permeability sediments and, contrary to replacement, supersaturation is a more important driver than Mg/Ca. While uncertainties remain regarding low‐temperature dolomitization kinetics, the capability of numerical simulations to decouple individual controls provides new insights which can be used, in conjunction with traditional comparative sedimentology, to generate more rigorous conceptual models for individual reservoir settings.