Secular variations in seawater chemistry controlling dolomitization in shallow reflux systems: insights from reactive transport modelling

Dolomitization often plays a critical role in the pore network development of platform carbonates, with implications for reservoir quality distribution. Understanding both the hydrological system driving dolomitization and the chemistry of the fluids involved is fundamental to constrain predictions of the geometry and the petrophysical properties of dolomite bodies. Here, the role of secular variations in seawater Mg/Ca as a control on dolomitization and early porosity modification was evaluated using one‐dimensional reactive transport models and fluids based on modern (aragonite sea), Mississippian and Aptian (calcite sea) seawaters. The sensitivity of dolomitization to a range of extrinsic controls (brine salinity, temperature, fluid flow rate and pCO₂) and to intrinsic reactivity of the sediments (effective reactive surface area) was also explored. Simulations suggest faster calcite replacement by dolomite for seawaters with higher Mg/Ca, indicating that dolomitization potential is determined more by Mg/Ca rather than saturation index. Increasing evaporative concentration enhances reaction rate independent of the effect of enhanced density‐driven fluid flux. In addition to brine composition, effective surface area of precursor sediments and temperature exert a critical control on replacement rate, while secular variations of pH and carbonate alkalinity associated with changes in pCO₂ are only secondary controls. Above flow rates of 0·01 m yr^?1 replacive dolomitization is reaction‐limited rather than flux limited, favouring alteration of fine‐grained carbonates and suggesting that preferential alteration of grainstone units is rare unless head gradients are low. Post‐replacement dolomite cementation is flux dependent, and thus favoured in areas of high head gradient and high permeability sediments and, contrary to replacement, supersaturation is a more important driver than Mg/Ca. While uncertainties remain regarding low‐temperature dolomitization kinetics, the capability of numerical simulations to decouple individual controls provides new insights which can be used, in conjunction with traditional comparative sedimentology, to generate more rigorous conceptual models for individual reservoir settings.     

Shelf-basin exchange in the Laptev Sea in the warming climate: a model study

GCM-based forecast simulations predict continuously increasing seasonality of the sea ice cover and an almost ice-free, summer-time, Arctic Ocean within several decades from the present. In this study we use a primitive equation ocean model: NEMO, coupled with the sea ice model LIM2, to test the hypothesis that under such an increased range in seasonal ice cover the intensity of shelf-basin water exchange will significantly increase. We use the simulated results for the Laptev Sea from a global model run 1958–2007 and compare results for two years with anomalously high and low summer sea ice extents: 1986–1987 and 2006–2007. The shelf–basin fluxes of volume, heat and salt during specific seasons are evaluated and attributed to plausible driving processes, with particular attention to dense water cascading. Analyses of the model temperature distribution at the depth of the intermediate maximum, associated with Atlantic Water, have shown a marked increase of the amount of the local origin cold water in late winter 2007 in the region, where dense water typically appears as a result of its formation on the shelf and subsequent downslope leakage. Calculation of the shelf-basin exchange during March-May in both years confirmed a substantial increase (a factor of two) of fluxes in “ice-free” 2007 compared to the “icy” 1987. According to several past model studies, dense water production on Arctic shelves in winter driven by ice freezing and brine rejection is not likely to cease in a warmer climate, but rather to increase. There is also observational evidence that cascading in the seasonally ice covered seas (e.g. the Barents Sea) is much more efficient than it is in the permanently ice covered Arctic Ocean, which supports these model results.     

A new deal for lone parents? Training lone parents for work in West London

In this paper we explore the impacts of the training programmes offered to lone mothers with young children on the Government's 'New Deal for Lone Parents' in one local labour market: West London. Our research suggests that regulatory workfare policies are (re)producing and reinforcing gendered inequalities in the labour market by encouraging lone mothers to undertake training in feminised occupational areas such as childcare. We will argue that in a local economy such as West London where more childcare workers are desperately needed to enable other more highly skilled workers to take up employment opportunities, such training programmes may be doing little more than exacerbating the already gendered and class-based polarisation of the labour market – embedding low-skilled, poorly qualified lone mothers into low-paid jobs.     

First account of apochlorotic diatoms from intertidal sand of a south Florida beach

During the period January to December 2004, monthly intertidal sand samples were collected from John U. Lloyd State Park beach, Florida. This study is the first to report on spatial and temporal distributions of heterotrophic (apochlorotic) diatoms in a sub-tropical beach, or indeed any sandy beach. Two non-pigmented, apochlorotic diatom morphotypes (strains III and IV) were consistently isolated from two intertidal beach sites and neither conformed to the morphologies of described species. Apochlorotic diatoms were found throughout the year and formed significant peaks in April, attaining total diatom counts of 71.1 and 94.9 cells g⁻¹ wet sand, for the upper tidal zone and lower tidal zone, respectively. Valve morphology is described in detail for the two diatom morphotypes isolated from the beach sites (strains III and IV). Growth responses to changes in salinity (reflecting those of the intertidal zone) were examined in the laboratory for these diatoms. Both morphotypes were euryhaline, tolerating salinities between 10 and 50, and maximum growth rates were achieved at salinities between 20 and 40. Diatoms grew equally well whether grown in the light or the dark and showed no evidence of pigments when viewed by epifluorescence microscopy. The ability of diatoms to burrow into agar and carrageenan at different concentrations was tested. Both morphotypes were observed to develop burrows through non-nutrient agar up to twice the standard concentration (30 g agar l⁻¹). The ease with which these heterotrophic diatoms formed burrows suggests that they were digesting these complex carbohydrates (i.e. phycocolloids) as a nutrient source. Strain IV, however, failed to burrow in a different phycocolloid, carrageenan. Similar degradative actions in the field might have implications for the breakdown of recalcitrant materials or allow diatoms to effectively compete with bacteria for carbon and nutrients.     

‘Body training’: Investigating the embodied training choices of/for mothers in West London

Framed by the UK Government’s efforts to combat social exclusion by encouraging a shift from welfare to work through (re)training, this paper explores the types of training courses being offered to and taken by women with young children in West London. Drawing upon qualitative research, the paper explores the actual and desired uptake of ‘body training’ courses among mothers, linked, in part, to the current ‘body work’ skills gap in the local economy. The encouragement given to women and the interest they have in engaging in ‘body training’ is, we suggest, linked to the discursive construction and performance of a highly feminised and, often, maternal identity, which emphasises women’s caring role and the caring self. By probing the body/training nexus through the motivations and choices of mothers in West London the paper raises questions about gender identity and stereotyping in relation to training-for-work policies and the role of training in (re)inforcing the woman-body coupling within Western dualistic thought.     

Heterogeneous stretching, simple shear and basin development

The models of basin development which involve either homogeneous stretching of the whole lithosphere or displacement on a lithospheric-scale shear zone, are but two end members of a range of possible extensional models. The homogeneous extension model thins the lower lithosphere beneath the thinned upper crust and superimposes a thermal subsidence basin on the earlier fault bounded basin. The shear zone model offsets the zone of lower lithospheric stretching and thermal subsidence. It is more likely that the zones of upper and lower lithospheric stretching will be heterogeneous and patchy, but will often overlap in plan view. This will produce localised uplift and subsequent thermal subsidence within the faulted basin and may explain many of the anomalies between the various stretching estimates made using different structural, stratigraphic and geophysical techniques. The model which combines heterogeneous lithospheric stretching and associated simple shear may explain: (1) variations in dip of the major detachment zones in the large basins, (2) variations in types of strain on or beneath the detachment zones, (3) regional uplift of part of a basin, to erode the earlier fault blocks, and (4) the development of volcanism in basins with only low values of upper crustal extension. The zone of stretched lower crust and lithospheric mantle may lie beneath the centre of the zone of upper crustal stretching, or to one side. It may be linked to the upper crustal zone by faults which dip consistently in one direction, or by extensional systems which change their dominant dip direction with depth, pulling out the mid-crust as one or more wedges. Possible examples are discussed from the Basin and Range province and northwest European continental shelf.     

Deglaciation and proglacial lakes

Glaciers and ice sheets are important constituents of the Earth's land surface. Current worldwide retreat of glaciers has implications for the environment and for civilisation. There are a range of geomorphic changes occurring in cold environments and it is anticipated that these will be accentuated as a consequence of climate change. In particular, the number and size of proglacial lakes is currently increasing as a result of deglaciation and their significance for the physical environment and for society is becoming increasingly apparent. This article provides an overview of the major interdependent relationships between climate change, glaciers and proglacial lake development. In particular, it describes the key processes and impacts associated with proglacial lake evolution with reference to examples drawn from the European Alps, North America, the Himalayas, the Andes, Greenland, New Zealand and Iceland.     

The liminality of training spaces: Places of private/public transitions

This paper draws upon research, conducted for the London West Learning and Skills Council, on the training experiences of women with dependent children. One of the striking revelations of the research, we suggest, is the way in which training spaces are used and perceived by women, which are often at odds with government intentions. To help make sense of women’s use of, and motivation for, training we utilise the concept of ‘liminality’ and the private/public imbrication to explain the ways in which women use, or are discouraged from using, training spaces. Further, how the varied and multiple uses women in our research have put training to in their own lives has encouraged us to rethink the relationship between the private and the public more generally. In the light of this, we suggest that training and the places in which training take place, have been neglected processes and spaces within feminist geography and might usefully be explored further to add to an extensive literature on women’s caring and domestic roles and their role in the paid workplace.