Mapping of Ozone and Water in the Atmosphere of Mars near the 1997 Aphelion

We present absolute abundances and latitudinal variations of ozone and water in the atmosphere of Mars during its late northern spring (L_s=67.3°) shortly before aphelion. Long-slit maps of the a¹Δ_g state of molecular oxygen (O₂) and HDO, an isotopic form of water, were acquired on UT January 21.6 1997 using a high-resolution infrared spectrometer (CSHELL) at the NASA Infrared Telescope Facility. O₂(a¹Δ_g) is produced by ozone photolysis, and the ensuing dayglow emission at 1.27 μm is used as a tracer for ozone. Retrieved vertical column densities for ozone above ∼20 km ranged between 1.5 and 2.8 μm-atm at mid- to low latitudes (30°S-60°N) and decreased outside that region. A significant decrease in ozone density is seen near 30°N (close to the subsolar latitude of 23.5°N). The rotational temperatures retrieved from O₂(a-X) emissions show a mean of 172±2.5 K, confirming that the sensed ozone lies in the middle atmosphere (∼24 km). The ν₁ fundamental band of HDO near 3.67 μm was used as a proxy for H₂O. The retrieved vertical column abundance of water varies from 3 precipitable microns (pr-μm) at ∼30°S to 24 pr-μm at ∼60°N. We compare these results with current photochemical models and with measurements obtained by other methods.     

A Lost Realm in the Internal Domains of the Betic-Rif Orogen (Spain and Morocco): Evidence from Conglomerates and Consequences for Alpine Geodynamic Evolution

The Malaguide-Ghomaride Complex is capped by Upper Oligocene-Aquitanian clastic deposits postdating early Alpine orogenesis but predating the main tectonic-metamorphic evolution, end of nappe emplacement, unroofing, and exhumation of the metamorphic units of the Betic-Rif Orogen. Two conglomerate intervals within these deposits are characterized by clasts of sedimentary, epimetamorphic, and mafic volcanic rocks derived from Malaguide-Ghomaride units and by clasts of acidic magmatic and orthogneissic rocks of unknown provenance, here studied. Magmatic rocks originated from late-Variscan two-mica cordierite-bearing granitoids and, subordinately, from aplitic dikes. Orthogneisses derive from similar plutonic rocks but are affected by an Alpine metamorphic overprint evolving from greenschist (T=510&j0;-530 degrees C and P=5-6 kbar) to low-temperature amphibolite facies (T>550&j0;C and P<3 kbar). Such a plutonic rock suite is unknown in any Betic-Rif unit or in the basement of the Alboran Sea, and the metamorphic evolution in the orthogneisses is different from (and older than) that of Alpujarride-Sebtide rocks to which they were formerly ascribed. Magmatic and metamorphic rocks very similar to those studied characterize the basements of some Kabylia and Calabria-Peloritani units. Therefore, the source area is a currently lost continental-crust realm of Calabria-Peloritani-Kabylia type, located to the ESE of the Malaguide-Ghomaride Domain and affected by a pre-latest Oligocene Alpine metamorphism. Increasingly active tectonics transformed this realm into rising areas from which erosion fed small subsiding synorogenic basins formed on the Malaguide-Ghomaride Complex. This provenance analysis demonstrates that all these domains constituted a single continental-crust block until Aquitanian-Burdigalian times, before its dispersal around nascent western Mediterranean basins.     

The origin of the fumaroles of La Solfatara (Campi Flegrei, South Italy)

The analysis of gaseous compositions from Solfatara (Campi Flegrei, South Italy) fumaroles since the early 1980s, clearly reveals a double thermobarometric signature. A first signature at temperatures of about 360 °C was inferred by methane-based chemical-isotopic geoindicators and by the H₂/Ar geothermometer. These high temperatures, close to the critical point of water, are representative of a deep zone where magmatic gases flash the hydrothermal liquid, forming a gas plume. A second signature was found to be at around 200-240 °C. At these temperatures, the kinetically fast reactive species (H₂ and CO) re-equilibrate in a pure vapor phase during the rise of the plume. A combination of these observations with an original interpretation of the oxygen isotopic composition of the two dominant species, i.e. H₂O and CO₂, shed light on the origin of fumarolic fluids by showing that effluents are mixture between fluids degassed from a magma body and the vapor generated at about 360 °C by the vaporization of hydrothermal liquids. A typical ‘andesitic’ water type (δD ∼ −20‰, δ¹⁸O ∼10‰) and a CO₂-rich composition (X_CO2∼0.4) has been inferred for the magmatic fluids, while for the hydrothermal component a meteoric origin and a CO₂ fugacity fixed by fluid-rock reaction at high temperatures have been estimated. In the time the fraction of magmatic fluids in the fumaroles increased (up to ∼0.5) at each seismic and ground uplift crisis (bradyseism) which occurred at Campi Flegrei, suggesting that bradyseismic crises are triggered by periodic injections of CO₂-rich magmatic fluids at the bottom of the hydrothermal system.     

中国当代土地利用对区域气候影响的数值模拟

使用RegCM3区域气候模式，嵌套欧洲数值预报中心(ECMWF)ERA40再分析资料，分别进行了中国区域在实际植被和理想植被分布情况下各15年时间长度（1987-2001）的积分试验，以研究我国土地利用状况对气候的影响。通过两个试验结果的对比，研究了我国土地利用状况对气候的影响。分析主要集中于气温、降水等的变化上，并对结果进行了统计显著性检验。结果表明，当代土地利用/植被覆盖变化加强了中国地区冬、夏季的季风环流，同时改变了地表能量平衡状况，从而对各气候要素产生重要影响。冬季，植被改变引起长江以南降水减少、气温降低，长江以北降水增加。夏季，植被改变显著影响了南方地区的气候，使得这里降水增多，黄淮、江淮气温降低，华南气温上升；同时引起中国北方降水减少，气温在西北部分植被退化地区升高。植被变化对日最低、最高气温的影响更大。总体来说，土地利用引起了年平均降水在南方增加、北方减少，年平均气温在南方显著降低。     

Geophysical and geodetic observations in the messina straits

The present note is intended as a contribution to the clarification of the collision process, generally assumed to be active between the African and the Eurasian plates in the area of the Messina Straits.For this purpose detailed analyses are made of the surveys carried out in the Straits of Messina in order to investigate the 1908 earthquake. The magnitude and intensity are established; limits are set for the linear dimension of the fault and of the dislocation that gave rise to the earthquake and an estimate is then given of these parameters. The results are then set out of the investigation into the focal mechanism of the earthquake of 1908. The results are also studied of geodetic surveys carried out at the time for the purpose of measuring the variations in height that occurred during the earthquake.A study is also made of the results of geodetic surveys (some of which are still under way) designed to measure the horizontal movements of Sicily with respect to Calabria in order to study locally the continental collision process in the area of the Messina Straits.It is found that the old and recent geodetic measurements as well as the fault-plane solution of the old and recent earthquakes of that area and the slips associated with those earthquakes indicate a motion towards the north of Sicily with respect to Calabria.     

Evolution of the late Quaternary San Gregorio Magno tectono‐karstic basin (southern Italy) inferred from geomorphological,tephrostratigraphical and palaeoecological analyses: tectonic implications

The Pantano di San Gregorio Magno is a 4.7 km² large tectono‐karstic basin located in the axial belt of the Southern Apennines, an area affected by intense seismicity. The basin was formed in the Middle Pleistocene and is presently undissected. It is filled by lacustrine sediments (clays, silts and pyroclastic sands) passing laterally into alluvial fan deposits. Geomorphological investigations were integrated with tephrostratigraphical, palynological and palaeoecological analyses of a 61 m thick core (not reaching the bedrock). The multiproxy analysis of the S. Gregorio Magno record shows that, over the last 200k yr, the basin hosted a freshwater lake with an oscillating level. Age constraints provided by the tephrostratigraphic record allowed estimation of the sedimentation rate, which varied strongly through time. Evolution of the basin resulted from the complex combination of tectonic subsidence, karst processes and changing amounts of sedimentary inputs. The latter was influenced by allogenic contributions related both to primary and reworked volcanoclastic inputs and was climate‐driven. The overall evidence, which indicates that in the long‐term the accumulation rate substantially counterbalanced the accommodation space created by faulting, suggests that the basin evolution was also modulated by changing subsidence rates. Copyright © 2006 John Wiley & Sons, Ltd.     

Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes

This work focuses on a rigorous analysis of the physical–chemical, compositional and textural relationships of amphibole stability and the development of new thermobarometric formulations for amphibole-bearing calc-alkaline products of subduction-related systems. Literature experimental results (550–1,120°C, <1,200 MPa, −1 ≤ ΔNNO ≤ +5), H₂O–CO₂ solubility models, a multitude of amphibole-bearing calc-alkaline products (whole-rocks and glasses, representing 38 volcanoes worldwide), crustal and high-P (1–3 GPa) mantle amphibole compositions have been used. Calcic amphiboles of basalt-rhyolite volcanic products display tschermakitic pargasite (37%), magnesiohastingsite (32%) and magnesiohornblende (31%) compositions with aluminium number (i.e. Al# = ^[6]Al/Al_T) ≤ 0.21. A few volcanic amphiboles (~1%) show high Al# (>0.21) and are inferred to represent xenocrysts of crustal or mantle materials. Most experimental results on calc-alkaline suites have been found to be unsuitable for using in thermobarometric calibrations due to the high Al# (>0.21) of amphiboles and high Al₂O₃/SiO₂ ratios of the coexisting melts. The pre-eruptive crystallization of consistent amphiboles is confined to relatively narrow physical–chemical ranges, next to their dehydration curves. The widespread occurrence of amphiboles with dehydration (breakdown) rims made of anhydrous phases and/or glass, related to sub-volcanic processes such as magma mixing and/or slow ascent during extrusion, confirms that crystal destabilization occurs with relatively low T–P shifts. At the stability curves, the variance of the system decreases so that amphibole composition and physical–chemical conditions are strictly linked to each other. This allowed us to retrieve some empirical thermobarometric formulations which work independently with different compositional components (i.e. Si^*, Al_T, Mg^*, ^[6]Al^*) of a single phase (amphibole), and are therefore easily applicable to all types of calc-alkaline volcanic products (including hybrid andesites). The Si^*-sensitive thermometer and the fO₂–Mg^* equation account for accuracies of ±22°C (σ_est) and 0.4 log units (maximum error), respectively. The uncertainties of the Al_T-sensitive barometer increase with pressure and decrease with temperature. Near the P–T stability curve, the error is <11% whereas for crystal-rich (porphyritic index i.e. PI > 35%) and lower-T magmas, the uncertainty increases up to 24%, consistent with depth uncertainties of 0.4 km, at 90 MPa (~3.4 km), and 7.9 km, at 800 MPa (~30 km), respectively. For magnesiohornblendes, the ^[6]Al^*-sensitive hygrometer has an accuracy of 0.4 wt% (σ_est) whereas for magnesiohastingsite and tschermakitic pargasite species, H₂O_melt uncertainties can be as high as 15% relative. The thermobarometric results obtained with the application of these equations to calc-alkaline amphibole-bearing products were finally, and successfully, crosschecked on several subduction-related volcanoes, through complementary methodologies such as pre-eruptive seismicity (volcano-tectonic earthquake locations and frequency), seismic tomography, Fe–Ti oxides, amphibole–plagioclase, plagioclase–liquid equilibria thermobarometry and melt inclusion studies. A user-friendly spreadsheet (i.e. AMP-TB.xls) to calculate the physical–chemical conditions of amphibole crystallization is also provided.     

Assessment of RegCM4 simulated inter-annual variability and daily-scale statistics of temperature and precipitation over Mexico

The skill of a regional climate model (RegCM4) in capturing the mean patterns, interannual variability and extreme statistics of daily-scale temperature and precipitation events over Mexico is assessed through a comparison of observations and a 27-year long simulation driven by reanalyses of observations covering the Central America CORDEX domain. The analysis also includes the simulation of tropical cyclones. It is found that RegCM4 reproduces adequately the mean spatial patterns of seasonal precipitation and temperature, along with the associated interannual variability characteristics. The main model bias is an overestimation of precipitation in mountainous regions. The 5 and 95 percentiles of daily temperature, as well as the maximum dry spell length are realistically simulated. The simulated distribution of precipitation events as well as the 95 percentile of precipitation shows a wet bias in topographically complex regions. Based on a simple detection method, the model produces realistic tropical cyclone distributions even at its relatively coarse resolution (dx = 50 km), although the number of cyclone days is underestimated over the Pacific and somewhat overestimated over the Atlantic and Caribbean basins. Overall, it is assessed that the performance of RegCM4 over Mexico is of sufficient quality to study not only mean precipitation and temperature patterns, but also higher order climate statistics.     

Quantitative hazard and risk assessment for slow-moving landslides from Persistent Scatterer Interferometry

Preparation of reliable landslide hazard and risk maps is crucial for hazard mitigation and risk management. In recent years, various approaches have been developed for quantitative assessment of landslide hazard and risk. However, possibly due to the lack of new data, very few of these hazard and risk maps were updated after their first generation. In this study, aiming at an ongoing assessment, a novel approach for updating landslide hazard and risk maps based on Persistent Scatterer Interferometry (PSI) is introduced. The study was performed in the Arno River basin (central Italy) where most mass movements are slow-moving landslides which are properly within the detection precision of PSI point targets. In the Arno River basin, the preliminary hazard and risk assessment was performed by Catani et al. (Landslides 2:329–342, 2005) using datasets prior to 2002. In this study, the previous hazard and risk maps were updated using PSI point targets processed from 4 years (2003–2006) of RADARSAT images. Landslide hazard and risk maps for five temporal predictions of 2, 5, 10, 20 and 30 years were updated with the exposure of losses estimated in Euro (€). In particular, the result shows that in 30 years a potential loss of approximate €3.22 billion is expected due to these slow-moving landslides detected by PSI point targets.