Equilibration Scales in Silicic to Intermediate Magmas Implications for Experimental Studies

Experimental phase equilibrium studies are increasingly beingused for the determination of intensive variables (P, T, fH₂O,fO₂ ) in silicic to intermediate magmas. In contrast, silicicigneous bodies are now perceived as open, periodically recharged,systems involving only limited chemical equilibration. Thus,the use of laboratory-determined crystal–liquid equilibriumdata needs clarification. Here we review the field, petrologicaland geochemical evidence concerning states and scales of chemicalequilibrium in silicic magma bodies. It is concluded that totalchemical equilibrium is generally not the rule. However, a subsystemin local equilibrium (the reactive magma) can be identified.Equilibration scales in silicic magmas are rate-limited eitherby diffusive flux in crystals (DICL regime) or by diffusiveflux in the melt (MD regime). The recognition that equilibriumin magmas is limited to a reactive subsystem requires phaseequilibrium studies to be chemically scaled. Experiments, eitherof total or partial equilibrium type, should aim at a closereproduction of equilibrium states specific to natural systems.The laboratory reconstruction of the natural equilibrium statesguarantees a precise determination of the pre-eruptive parametersand a reliable application of the experimental data to activevolcanic systems. KEY WORDS: silicic magmas; chemical equilibrium; timescales; experimental studies     

Modelling Microbial Degradation Coupled to Reactive Transport in Groundwater: A Benchmark Analysis

Microbes are ubiquitous in groundwater systems, and they play an important role in the redox state of groundwater and especially on the fate of organic contaminants. In this context, numerical simulations that couple microbial processes to reactive transport models are becoming more popular. In the present work, we revisit the mathematical ground of microbial redox reactions and perform a benchmark analysis of the simulation of aerobic benzene degradation in a shallow and oxidizing aquifer. Numerical results indicate that the two codes tested (one using the finite elements approach and the other using the finite differences approach) lead to very similar results. In addition, the coupling of heterogeneous geochemical reactions to the benchmarked example problem provides a solid basis for the understanding of the redox reactions and the changes on the carbon system triggered by the aerobic degradation of benzene.     

Discussion: a critique of Possible waterways between the Marmara Sea and the Black Sea in the late Quaternary: evidence from ostracod and foraminifer assemblages in lakes ?znik and Sapanca, Turkey, Geo-Marine Letters, 2011

The identification of past connection routes between the Black Sea and the Sea of Marmara, other than the traditional one through to the Bosphorus Strait, would be of considerable interest to the international scientific community. Nazik et al. (Geo-Mar Lett 31:75?C86 (2011) doi:10.1007/s00367-010-0216-9) suggest the possibility of two alternative waterway connections via lakes Sapanca and ?znik. Their Black Sea to Sea of Marmara multi-connection hypothesis, which is based on undated marine fossils collected in both lakes from surficial grab samples, conflicts with many earlier studies. In this contribution, the hypothesis and the underlying data are discussed in the light of previous tectonic, sedimentological and limnological findings showing that it is impossible to have had marine connections through lakes Sapanca and ?znik during the last 11.5?ka. Global sea-level trends and tectonic uplift rates would accommodate a connection between the Sea of Marmara and Lake ?znik in the middle Pleistocene. Uplift rates for the northern block of the North Anatolian Fault, when compared with the global sea-level curve, clearly indicate that there cannot have been a connection through the ?zmit Gulf?CLake Sapanca?CSakarya Valley for at least the past 500?ka. Moreover, borehole sediments along the western shores of Lake Sapanca, which reach down to the bedrock, do not contain any marine fossils.     

Large-Scale Temperature Changes across the Southern Andes: 20th-Century Variations in the Context of the Past 400 Years

Long-term trends of temperature variations across the southern Andes (37–55° S) are examined using a combination of instrumental and tree-ring records. A critical appraisal of surface air temperature from station records is presented for southern South America during the 20th century. For the interval 1930–1990, three major patterns in temperature trends are identified. Stations along the Pacific coast between 37 and 43° S are characterized by negative trends in mean annual temperature with a marked cooling period from 1950 to the mid-1970s. A clear warming trend is observed in the southern stations (south of 46°S), which intensifies at higher latitudes. No temperature trends are detected for the stations on the Atlantic coast north of 45° S. In contrast to higher latitudes in the Northern Hemisphere where annual changes in temperature are dominated by winter trends, both positive and negative trends in southern South America are due to mostly changes in summer (December to February) temperatures. Changes in the Pacific Decadal Oscillation (PDO) around 1976 are felt in summer temperatures at most stations in the Pacific domain, starting a period with increased temperature across the southern Andes and at higher latitudes.Tree-ring records from upper-treeline were used to reconstruct past temperature fluctuations for the two dominant patterns over the southern Andes. These reconstructions extend back to 1640 and are based on composite tree-ring chronologies that were processed to retain as much low-frequency variance as possible. The resulting reconstructions for the northern and southern sectors of the southern Andes explain 55% and 45% ofthe temperature variance over the interval 1930–1989, respectively. Cross-spectral analysis of actual and reconstructed temperatures over the common interval 1930–1989, indicates that most of the explained varianceis at periods >10 years in length. At periods >15 years, the squaredcoherency between actual and reconstructed temperatures ranges between 0.6 and 0.95 for both reconstructions. Consequently, these reconstructions are especially useful for studying multi-decennial temperature variations in the South American sector of the Southern Hemisphere over the past 360 years. As a result, it is possible to show that the temperatures during the 20thcentury have been anomalously warm across the southern Andes. The mean annual temperatures for the northern and southern sectors during the interval 1900–1990 are 0.53 °C and 0.86 °C above the1640–1899 means, respectively. These findings placed the current warming in a longer historical perspective, and add new support for the existence of unprecedented 20th century warming over much of the globe. The rate of temperature increase from 1850 to 1920 was the highest over the past 360 years, a common feature observed in several proxy records from higher latitudes in the Northern Hemisphere.Local temperature regimes are affected by changes in planetary circulation, with in turn are linked to global sea surface temperature (SST) anomalies. Therefore, we explored how temperature variations in the southern Andes since 1856 are related to large-scale SSTs on the South Pacific and South Atlantic Oceans. Spatial correlation patterns between the reconstructions and SSTs show that temperature variations in the northern sector of the southern Andes are strongly connected with SST anomalies in the tropical and subtropical Pacific. This spatial correlation pattern resembles the spatial signature of the PDO mode of SST variability over the South Pacific and is connected with the Pacific-South American (PSA) atmospheric pattern in the Southern Hemisphere. In contrast, temperature variations in the southern sector of the southern Andes are significantly correlated with SST anomalies over most of the South Atlantic, and in less degree, over the subtropical Pacific. This spatial correlation field regressed against SST resembles the `Global Warming' mode of SST variability, which in turn, is linked to the leading mode of circulation in the Southern Hemisphere. Certainly, part of the temperature signal present in the reconstructions can be expressed as a linear combination of four orthogonal modes of SST variability. Rotated empirical orthogonal function analysis, performed on SST across the South Pacific and South Atlantic Oceans, indicate that four discrete modes of SST variability explain a third, approximately, of total variance in temperature fluctuations across the southern Andes.     

Climate and irrigation scenario analyses using three-dimensional numerical modelling: a case study of the Nasia sub-basin in the White Volta Basin,Ghana

A groundwater resource characterisation and assessment model was developed for Nasia river sub-basin in the White Volta Basin, Ghana. The model is useful to policymakers for planning and sustainable management of groundwater resources in the basin for domestic and irrigation purposes. A conceptual model was constructed that characterized boundary conditions and hydrostratigraphy, and estimated recharge rates and hydraulic and storage parameters. From current understanding of the hydrogeological dynamics, three hydrostratigraphic layers were delineated. The conceptual model was converted to a three-dimensional steady-state groundwater flow model using MODFLOW. Recharge rates estimated from the base model indicate a minimum of 1.1% and maximum of 6.2% of the total rainfall. The hydraulic conductivity ranged between 0.20 and 15 m/day. Four possible scenarios were simulated: (1) increased population, (2) climate variations (reduced recharge), (3) increased abstraction for irrigation, and (4) worst-case scenario which is a combination of the first three scenarios. Results from scenarios 1 and 2 indicated that, under such conditions, the groundwater resources could be sustained and no significant effect on any of the water budget indicators was observed. For scenario 3, there was significant drop in hydraulic head in the central portions of the study area. The scenario 4 simulation indicated that there was significant reduction in groundwater levels and groundwater discharge into streams under these stressors. Such reduction can affect stream levels in the basin and, subsequently, the ecosystem. These findings are valid within the limits of uncertainty in the hydrogeological data that were used in this study.

     

A nonhomogeneous Poisson process geostatistical model

This paper introduces a new geostatistical model for counting data under a space-time approach using nonhomogeneous Poisson processes, where the random intensity process has an additive formulation with two components: a Gaussian spatial component and a component accounting for the temporal effect. Inferences of interest for the proposed model are obtained under the Bayesian paradigm. To illustrate the usefulness of the proposed model, we first develop a simulation study to test the efficacy of the Markov Chain Monte Carlo (MCMC) method to generate samples for the joint posterior distribution of the model’s parameters. This study shows that the convergence of the MCMC algorithm used to simulate samples for the joint posterior distribution of interest is easily obtained for different scenarios. As a second illustration, the proposed model is applied to a real data set related to ozone air pollution collected in 22 monitoring stations in Mexico City in the 2010 year. The proposed geostatistical model has good performance in the data analysis, in terms of fit to the data and in the identification of the regions with the highest pollution levels, that is, the southwest, the central and the northwest regions of Mexico City.     

Primary production in the Strait of Gibraltar: Carbon fixation rates in relation to hydrodynamic and phytoplankton dynamics

Primary production was studied at nine sites distributed within the Strait of Gibraltar (Southern Spain) and North-Western (NW) Alboran Sea by analyzing photosynthesis-irradiance (P–I) relationships and integrated primary production rates in relation to the different types of Deep Chlorophyll Maxima (DCM) detected in the area. The characteristics of the DCM were examined by several methods, including flow cytometry, quantification of transparent expolymer particles and fluorimetric measurements that were applied in order to assess the photo-physiological state of the phytoplankton assemblages with respect to their species composition and water column structure (hydrology). The photosynthetic parameters (derived from P–I relationships) and integrated primary production (range 6–644 mg m⁻² d⁻¹) responded greatly to the diverse DCM identified and thereby the spatial variability of the primary production observed in the region was found to depend upon the occurrence of the different types of phytoplankton accumulations, which were themselves indicative of the previous history of the water column. The net contribution of the primary production to the air–sea CO₂ exchange process was also evaluated in the area. Results indicated that this region behaved as a net sink for the atmospheric CO₂, with the intensity of the flux being strongly modulated by the wind intensity.     

Review and Proposed Method to Study the Damage Orientation of Earthquake Effects in Pre-Instrumental Earthquakes

Izvestiya, Physics of the Solid Earth - The information and seismic parameters gained from pre-instrumental earthquakes are essential to improve the seismic catalogs and hazard studies. The...