Sources and behavior of arsenic and trace elements in groundwater and surface water in the Poopó Lake Basin,Bolivian Altiplano

Water management in semiarid and arid catchments such as the Poopó Lake Basin requires improved understanding of the complex behavior of the various contaminants, which affect the drinking water quality and considered as crucial for sustainable development of the region. Mechanisms of arsenic (As) release in the surface and groundwater were studied. Hydrochemical data for surface water (4 samples) and groundwater (28 samples) were collected in a small watershed in the Poopó catchment at the highland of the Bolivian Andes (Altiplano). All of them show high electrical conductivity values and moderately oxidizing conditions. The surface water contains high concentration of sulfate and the trace elements As, Zn and Pb in the zone affected by acid mine drainage. There is a large variability of the concentration of As and of the trace elements in the groundwater in the five different regions within the Poopó catchment. The metal concentrations sensitive to changes of redox state and results of speciation modeling suggest that As (V) is a predominant aqueous species, which conforms to the prevailing oxidizing conditions in the shallow groundwater environment. Two generalized trends for As distribution were identified in groundwater: (a) high concentrations are found in the arid zone (100–250 μg/L) in the southern (region III) and in the northwestern (region V) regions, and (b) low concentrations (<50 μg/L) are found in the remaining part of the basin (region I, II and IV). However, the spatial distribution within these regions needs to be investigated further. A conclusion from the present study is that there are multiple sources of As as well as other trace elements (such as Cd, Mn and Zn) in the Poopó Lake Basin. Among the sources and the processes which led to the mobility of As and other trace metals in the region are: (a) weathering of sulfide minerals, (b) oxidation of pyrite and/or arsenopyrite in mineralized areas and (c) desorption from hydrous ferric oxide (HFO) surfaces. In non-mining areas, volcanic ash is suggested to be a significant source of As.     

Provenance of deep-water reservoir sandstones from the Jubarte oil field,Campos Basin,Eastern Brazilian Margin

The provenance of the Maastrichtian deep-water reservoir sandstones from the Jubarte oil field (Campos Basin, eastern Brazil), was studied using an integrated approach that included quantitative petrography, conventional heavy mineral analysis, garnet mineral chemistry and zircon geochronology. The reservoirs are predominantly coarse, poorly-sorted sandstones with feldspathic composition derived from uplifted basement terrains. The fourth- and fifth-order depositional sequences analyzed show no major variations in composition or in provenance through time. However, variations in apatite:tourmaline presents potential to be used as a parameter for sandstone correlation within the field. The composition of heavy minerals indicates derivation from high temperature and low-to-medium pressure aluminous metapelitic rocks, from granites and subordinate mafic rocks, derived from the Cabo Frio Tectonic Domain and the Oriental terrain of Ribeira orogen, characterizing a supply route from SW to NE. The low ZTR index, as well as the absence of low-grade stable heavy minerals and of metasedimentary rock fragments, suggest that by the end of Cretaceous all supracrustal, low-grade terrains had already been totally eroded, and that plutonic, infracrustal rocks were exposed, similarly to the present situation.     

Mode trapping in sdO models

Mode trapping of high-radial order gravity modes was found for a particular sdO model. The trapping is caused by the change in composition from the helium radiative shell to the hydrogen burning shell. A non-adiabatic effect of this trapping is the higher tendency to instability of the trapped modes. Low- to intermediate-radial order pressure modes (in sdO models they correspond to mixed modes with most nodes in the P-mode region) are found to be trapped by the chemical transition from the carbon-oxygen core to the He burning shell. As the trapping is produced in the deep interior of the star, where energy interchange is negligible at the p-mode frequencies, it has no particular effect on the driving.     

Extreme events and disasters: a window of opportunity for change? Analysis of organizational,institutional and political changes,formal and informal responses after mega-disasters

Disaster associated with natural hazards can lead to important changes—positive or negative—in socio-ecological systems. When disasters occur, much attention is given to the direct disaster impacts as well as relief and recovery operations. Although this focus is important, it is noteworthy that there has been little research on the characteristics and progress of change induced by disasters. Change, as distinct from impacts, encompasses formal and informal responses to disaster events and their direct and indirect impacts. While smaller disasters do not often lead to significant changes in societies and organizational structures, major disasters have the potential to change dominant ways of thinking and acting. Against this background, the article presents an analytical framework for distinguishing change from disaster impacts. Drawing from research in Sri Lanka and Indonesia, formal and informal changes after the Indian Ocean Tsunami of 2004 are examined and discussed against the background of the conceptual framework. The changes examined range from the commencement of the peace process in Aceh, Indonesia, to organizational and legal reforms in Sri Lanka. The article concludes that change-making processes after disasters need to be understood more in depth in order to derive important strategic policy and methodological lessons learned for the future, particularly in view of the increasing complexity and uncertainty in decision making due to climate change.     

Estimation of aquifer hydraulic parameters from surface geophysical measurements: a case study of the Upper Cretaceous aquifer, central Sinai, Egypt

The integration of geophysical data with direct hydrogeological measurements can provide a minimally invasive approach to characterize the subsurface at a variety of resolutions and over many spatial scales. The field of hydrogeophysics has attracted much attention during the last two decades. In this domain, the geophysical data inverted to geophysical models are interpreted in terms of the hydrogeology to serve as a basis for the definition of hydraulic models in the areas of interest. The hydraulic conductivity (K) value measured in a reference borehole has been combined with the electrical conductivity obtained from nearby geo-electromagnetic sounding data in the Cenomanian (Upper Cretaceous) aquifer, central Sinai, Egypt. The resulting relation was interpreted with Dar Zarrouk parameters to infer the transmissivity variations at other vertical electrical sounding locations, where K values are unknown. Coincident transient electromagnetic data have been adopted to increase accuracy while interpreting the aquifer geoelectrical properties. The results indicate that the transmissivity values in the aquifer of interest vary from 2,446 to 9,694 m²/day, and K varies from 12.9 to 57.0 m/day throughout the studied area.     

Late Cretaceous porphyry copper mineralization in Sonora,Mexico: Implications for the evolution of the Southwest North America porphyry copper province

Two porphyry Cu-Mo prospects in northern Sonora, Mexico (Fortuna del Cobre and Los Humos) located within the southwestern North American porphyry province have been dated in order to constrain the timing of crystallization and mineralization of these ore deposits. In Fortuna del Cobre, the pre-mineralization granodiorite porphyry yielded an U-Pb zircon age of 76.5?±?2.3 Ma, whereas two samples from the ore-bearing quartz feldespathic porphyry were dated at 74.6?±?1.3 and 75.0?±?1.4 Ma. Four molybdenite samples from Los Humos porphyry Cu prospect yielded a weighted average Re-Os age of 73.5?±?0.2 Ma, whereas two samples from the ore-bearing quartz monzonite porphyry gave U-Pb zircon ages of 74.4?±?1.1 and 74.5?±?1.3 Ma, showing a Late Cretaceous age for the emplacement of this ore deposit. The results indicate that Laramide porphyry Cu mineralization of Late Cretaceous age is not restricted to northern Arizona as previously thought and provide evidence for the definition of NS trending metallogenic belts that are parallel to the paleo-trench. Porphyry copper mineralization follows the inland migration trend of the magmatic arc as a result of the Farallon slab flattening during the Laramide orogeny.     

Calibration of Local Magnitude M<Subscript>L</Subscript> in the Azores Archipelago Based on Recent Digital Recordings

—The development of the digital seismic network in the Azores Archipelago during recent years made it possible to obtain the amplitudes (waveform) of recorded motion in a large set of stations. With this new data, maximum amplitudes of the Wood Anderson seismograph are computed, for each station/component, which, together with epicentral distances, allows for the estimation of local magnitude M _L . We used data recorded in 8 digital permanent three-component stations, with inter-stations distances up to 300 km, in the period June 1998 – June 2000, corresponding to a set of 1315 events with magnitude (M _L or M _D ) 2<M<5.8 and epicenters located in the Azores region, to estimate the coefficients of the equation to compute M _L , as well as to determine the corrections to be applied to each station. The new set of parameters, formed by attenuation coefficients and station corrections, were introduced in the calculations of the M _L , leading to smaller dispersions in the analyzed dataset. We also conclude that the attenuation in the first 150 km is similar to the California values, although higher for longer distances.     

Coda Q before and after the eruptions of 13 November 1985, and 1 September 1989, at Nevado del Ruiz Volcano, Colombia

 Coda Q^–1 was calculated at Nevado del Ruiz Volcano (NRV) before and after two phreatomagmatic eruptions (November 1985, September 1989) and for a period of stability (May 1987) using a functional form for coda derived from a single scattering model (Sato 1977). Substantial changes were found before and after the eruptions. The highest value of Q^–1 was found during the November 1985 eruption, an intermediate value for the September 1989 eruption, and the lowest value for May 1987. It seems that the changes in coda Q^–1 at NRV have a still-unknown relationship with the volume or magnitude of the eruption. A relatively strong frequency dependence was found for all periods. Also Q^–1 clearly changed with time, suggesting that the scattering was strong for the eruption of November 1985 and decreased for the eruption of September 1989, and that the intrinsic absorption probably increased. This suggests the possibility that crystallization is taking place in the NRV magma. The clear change of coda Q^–1 before and after the eruptions at NRV also suggests the possibility that coda Q^–1 is a premonitory tool of activity at this volcano. Received: 25 October 1996 / Accepted: 21 January 1998