Characteristics of carbonyl compounds in ambient air of Shanghai,China

The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m⁻³ respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.     

Interdecadal change in the connection between Hadley circulation and winter temperature in East Asia

Based on NCEP/NCAR reanalysis data, the interdecadal variability of Hadley circulation （HC） and its association with East Asian temperature in winter are investigated. Results indicate that the Northern Hemisphere winter HC underwent apparent change in the 1970s, with transition occurring around 1976/77. Along with interdecadal variability of HC, its linkage to surface air temperature （SAT） in East Asia also varied decadally, from weak relations to strong relations. Such a change may be related to the interaction between HC and the atmospheric circulation system over the Philippines, which is associated with the East Asian winter monsoon （EAWM）. Before the 1970s, the connection between HC and the anticyclonic circulation around the Philippines was insignificant, but after the late 1970s their linkage entered a strong regime. The intensification of this connection may therefore be responsible for the strong relations between HC and East Asian winter temperatures after the late 1970s.     

Implementation of a surface runoff model with Horton and Dunne mechanisms into the regional climate model RegCM_NCC

A surface runoff parameterization scheme that dynamically represents both Horton and Dunne runoff generation mechanisms within a model grid cell together with a consideration of the subgrid-scaie soil heterogeneity, is implemented into the National Climate Center regional climate model （RegCM_NCC）. The effects of the modified surface runoff scheme on RegCMANCC performance are tested with an abnormal heavy rainfall process which occurred in summer 1998. Simulated results show that the model with the original surface runoff scheme （noted as CTL） basically captures the spatial pattern of precipitation, circulation and land surface variables, but generally overestimates rainfall compared to observations. The model with the new surface runoff scheme （noted as NRM） reasonably reproduces the distribution pattern of various variables and effectively diminishes the excessive precipitation in the CTL. The processes involved in the improvement of NRM-simulated rainfall may be as follows： with the new surface runoff scheme, simulated surface runoff is larger, soil moisture and evaporation （latent heat flux） are decreased, the available water into the atmosphere is decreased; correspondingly, the atmosphere is drier and rainfall is decreased through various processes. Therefore, the implementation of the new runoff scheme into the RegCMANCC has a significant effect on results at not only the land surface, but also the overlying atmosphere.     

论青藏高原隆起作用于大气的临界高度

在以前工作的基础上，从大气动力学、热力学及气候学的角度，进一步论证了在青茂高原隆起过程中存在一个临界高度ｈｃ（－１．５－２ｋｍ）。当高原隆起突破这一临界高度时才开始对大气产生强烈的作用，从而造成大气环流、大气热力结构、亚洲区域以及全球气候等一系列巨大转变。     

农桐间作地热量平衡和水分利用状况研究

由实测资料系统分析了农桐间作地热量平衡各分量复杂的时空变化特征。结果表明：间作内外蒸发耗热（ＬＥ）仍是主要耗热项，湍流耗热（Ｈ）低于ＬＥ，但高于土壤热通量（Ｑ）；间作地各分量小于对照，但ＬＥ、Ｑ占净辐射（Ｒｎ）比值高于对照；泡桐林带对各分量的影响与间作结构及测点位置有关。然后计算了间作中小麦、棉花水分利用率（ＷＵＥ），其值与作物类型，生长期等因子有关，且间作地高于对照。     

O3浓度增加对冬小麦影响的试验研究

利用OTC 1型开顶式气室对冬小麦进行不同O3 浓度处理的试验研究。结果表明 ,O3 浓度增加 ,冬小麦发育期表现为开花前期有所延迟 ,开花后期的各发育期明显提前 ,生育期缩短 ,植株矮化 ,干物质累积量明显下降。无论是长时期通气处理还是阶段性通气处理 ,产量均明显降低     

Adaptation of Pressure Based CFD Solvers for Mesoscale Atmospheric Problems

General purpose Computational Fluid Dynamics (CFD) solvers are frequently used in small-scale urban pollution dispersion simulations without a large extent of ver- tical flow. Vertical flow, however, plays an important role in the formation of local breezes, such as urban heat island induced breezes that have great significance in the ventilation of large cities. The effects of atmospheric stratification, anelasticity and Coriolis force must be taken into account in such simulations. We introduce a general method for adapting pressure based CFD solvers to atmospheric flow simulations in order to take advantage of their high flexibility in geometrical modelling and meshing. Compressibility and thermal stratification effects are taken into account by utilizing a novel system of transformations of the field variables and by adding consequential source terms to the model equations of incompressible flow. Phenomena involving mesoscale to microscale coupled effects can be analyzed without model nesting, applying only local grid refinement of an arbitrary level. Elements of the method are validated against an analytical solution, results of a reference calculation, and a laboratory scale urban heat island circulation experiment. The new approach can be applied with benefits to several areas of application. Inclusion of the moisture transport phenomena and the surface energy balance are important further steps towards the practical application of the method.     

气候波动和人类活动对南水北调中线工程典型流域径流影响的定量评估

以南水北调中线工程典型流域汉江上游流域和滦河流域为研究对象,采用敏感性分析法、降水?径流双累积曲线法、累积量斜率变化率比较法定量评估了气候波动和人类活动对流域径流变化的影响。结果表明：汉江上游流域和滦河流域变异Ⅰ/Ⅱ期年均径流深相对于基准期分别减少了29.5% / 19.1%和49.8% / 70.0%;对于汉江上游流域,1991-1999年（变异Ⅰ期）气候波动是径流减少的主要影响因素,2000-2008年（变异Ⅱ期）人类活动则是径流减少的主要影响因素,且人类活动对汉江上游流域径流减少的影响逐步增加;对于滦河流域,1980-2010年（变异Ⅰ/Ⅱ期）人类活动一直是径流减少的主要影响因素,且气候波动和人类活动对径流减少的影响贡献率基本保持不变。