用变分法修正黑河试验数据的初步研究

为了对黑河试验观测资料进行订正,利用一个一维边界层垂直扩散模式和以拟牛顿极小化算法为基础的最优化方法建立了一个变分同化系统,其中,目标函数相对于控制变量的梯度用扰动法求取.并利用模式资料和黑河试验若干时刻的观测资料进行了一些数值试验.试验证明,将初始场变量与模式误差系数同时作为控制变量加以调整,能够有效调整初始场观测资料.并且,用变分同化方法能够较线性插值(时间、空间)方法更有效、合理的修正黑河试验观测资料场的种种缺陷.     

Exploring spatiotemporal relationships among meteorological,agricultural, and hydrological droughts in Southwest China

Each type of drought has different characteristics in different regions. It is important to distinguish different types of droughts and their correlations. Based on gauged precipitation, temperature, simulated soil moisture, and runoff data during the period 1951–2012, the relationships among meteorological, agricultural, and hydrological droughts were analyzed at different time scales in Southwest China. The standardized precipitation evapotranspiration index (SPEI), soil moisture anomaly percentage index (SMAPI), and standardized runoff index (SRI) were used to describe meteorological, agricultural, and hydrological droughts, respectively. The results show that there was a good correlation among the three indices. SMAPI had the best correlation with the 3 month SPEI and SRI values. It indicates that agricultural drought was characterized by a 3-month scale. The three drought indices displayed the similar special features such as drought scope, drought level, and drought center during the extreme drought of 2009–2010. However, the scope and level of SPEI were bigger than those of SMAPI and SRI. The propagation characteristics of the three types of droughts were significantly different. The temporal drought process in typical grids reflect that the meteorological drought occurred ahead of agricultural and hydrological droughts by about 1 and 3 months, respectively. Agricultural drought showed a stable drought process and reasonable time periods for the drought beginning and end. These results showed the quantitative relationships among three types of drought and thus provided an important supporting evidence for regional drought monitoring and strategic decisions.     

中国北方岩溶充水煤矿区矿床水文地质图编制方法与要求

编 制 《中国 北 方岩 溶充 水 煤矿 区矿 床 水文 地质 图 集》的目 的主 要 是为 了合 理 开发 煤炭 资 源和 利用 煤 系 基 盘中奥 陶 统 灰岩 地 下 水 ;图 中 内 容应 力 求 充 分反 映 矿 区 不同 充 水 类 型的 充 水 特 征、充 水程 度 、水质 好 坏 及 可利 用 的 水 量 ,为 矿山 综 合防 治水 和 排供 结合 宏 观决 策提 供 所需 的水 文 地质 依据 。     

Quantitative assessment of gas washing of oils in the Tazhong area of the Tarim Basin,Northwest China

Gas washing has been known in the Tazhong area of the Tarim Basin, but its quantitative assessment has not yet been reported. Here the influence of gas washing fractionation in the area was discussed based on the gas chromatogram data of 68 oils and the results of the mixing experiments of a black oil and a condensate. The results show that the intensity of gas washing fractionation decreased generally from northern to southern part and vertically from deep reservoirs to shallow reservoirs. The gas washing fractionation was mainly controlled by fault systems in this area, with the increase of n-alkane mass depletion positively correlated to the number and scale of faults. Gas washing fractionation appears to have affected the hydrocarbon property, and as a result the diversity of the crude oils is markedly controlled by gas washing. In addition, the occurrence of waxy oil in this area may be resulted from multiple factors including gas washing, mixed filling and migration fractionation. Supported by National Basic Research Program of China (Grant No. 2006CB202303) and the National Natural Science Foundation of China (Grant No. 40672091)     

Evaluation of an automated EA-IRMS method for total carbon analysis of atmospheric aerosol at HEKAL

Comprehensive atmospheric studies have demonstrated that carbonaceous particles are one of the main components of atmospheric aerosols over Europe. The aim of our study was to establish an automated elemental analyser interfaced to a stable isotope mass spectrometer (EA-IRMS) method at the Hertelendi Laboratory of Environmental Studies (HEKAL), as a suitable method of quantification of total carbon mass in individual PM_2.5 aerosol samples. Total carbon (TC) mass and simultaneous stable isotopic ratios were determined for both test standard and genuine aerosol samples. Finally, the results were compared to the ones obtained independently by an alternative sealed tube combustion method developed previously at HEKAL. The TC recovery tests of standard material prepared by the sealed tube method confirmed at least a carbon recovery yield of 92% for a broad range of carbon mass (100–2000 μg). The stable isotopic results confirmed that sealed tube method is reproducible and suitable to be used as a reference to verify our new EA-IRMS method. The EA-IRMS TC measurements of genuine aerosols gave on average 3% higher carbon recovery yield, relative to the uncorrected results of the sealed tube method. The comparison of the stable isotopic results by the two methods for aerosols also showed minimal differences. Consequently, the possibility of simultaneous TC and stable isotopic analyses makes the EA-IRMS method a very attractive alternative for continuous measurement of aerosols, with an accuracy and reliability similar to other commercial devices.     

Summer distribution and geochemical composition of suspended-particulate matter in the east china sea

The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The spatial variability of SPM distribution (0.3–6.5 mg l⁻¹) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water (mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations were highly significant. Particulate CaCO₃ distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total area of 0.45 × 10⁶ km² of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate that continental sources and cross-shelf transport modulate ECS particulate matter in summer.     

中国城镇化与耕地变化时空耦合研究

利用全国(港澳台地区除外)1985—2013年的面板数据,分析各省份城镇化水平的演进态势及耕地数量的动态变化,并分不同时段测算各省份城镇化发展水平与耕地资源变动的耦合协调程度。结果表明:(1)1985年以来,全国大部分地区的城镇化水平整体上都呈现上升的变化趋势,东三省城镇化水平稳定上升但活力不足,西北多省份上升中波动较大,西南地区水平偏低。(2)全国耕地资源在20世纪80年代普遍减少,后期多省份有所增加,但京、津、沪、苏、粤等地的耕地面积一直在以一定的速率减少。(3)全国城镇化与耕地资源关系的协调度呈现西高东低、北高南低的空间格局。较多地区在快速城镇化进程中城镇化发展与耕地资源的协调度呈恶化趋势。     

Isotopic Characteristics and Key Factors Favoring the Formation of Fuwan Super-large Silver Deposit in Guangdong Province

Rb-Sr isochron age of fluid inclusions in quartz from the Fuwan super-large silver deposit is 68 - 6 Ma, the silver deposit is characterized by high μ values (10.67 - 10.95 ), which are much higher than those of the ore-hosted Paleozoic strata and are close to those of ores hosted in the Proterozoic metamorphic basement in western Guangdong Province. Based on the Pb isotopic characteristics, coupled with much high background silver contents (200-1000ng/g) in the Proterozoic basement and relatively low silver contents in the Paleozoic strata in the region of the Sanshui Basin, it is concluded that the ore-forming material of the super-large silver deposit came mainly from the old basement. The super-large silver deposit related genetically to the intense volcanic activities during the Upper Cretaceous to Eogene. The formation of the Fuwan super-large silver deposit is controlled by the following favorable geological conditions : ( 1 ) The intersection of deep faults and contemporaneous faults at the margin of the Sanshui Basin led to the formation of an excellent structure as passageway for ore fluids; (2) The special ore-hosted rock association forms a ore gathering-trap structure that favors the precipitation of ore; (3) The silver-rich old basement, multi-stage mineralization and multi-episode volcanic activities which constitute a geothermal convection system.     

中国上地幔角闪石及其成因意义

我国土地幔成因角闪石以高铝(一般>2.0)为特征,以TiO_2、Cr_2O_3含量差异相区别,划分为韭闪石和钛角闪石两大类。韭闪石又有四种不同的成因类型:贫铬、钛型(Cr_2O_3=0.15％,TiO_2=0.07％),富铬型(Cr_2O_3=2.18％),富钛型(TiO_2=3.14％)和富铬、钛型(Cr_2O_3=2.59％,TiO_2=3.16％)。除贫铬、钛型韭闪石发现于苏北-胶南高压变质岩石中外,其它三种韭闪石(产于大陆区)和钛角闪石(产于台湾西部)均来自各种地幔橄榄岩、辉石岩及新生代玄武岩中。不管它们的产出方式如何(填隙、嵌晶、巨晶和包裹体子矿物),都直接或间接与地幔流体的交代作用有关,但各具成因之特点。     

陕西小秦岭金矿深部找矿潜力分析

小秦岭金矿位于华北地台南缘小秦岭隆起北部的太华台拱区,矿床成因类型为石英脉—构造蚀变岩型;区内太古界太华群地层既是赋矿地层也是矿源层,矿体严格受脆韧性构造带控制,燕山期岩浆岩为金的活化、运移提供了热动力。