The study of metal contamination in urban topsoils of Mexico City using GIS

This research presents and discusses information concerning the spatial distribution of heavy metals (Pb, Cu, Zn, Ba, Co, Cr, Ni and V) in the urban environments of Mexico City using geographical information system and statistical analysis. Superficial soil samples (n = 146) were analyzed. The highest contamination indices were found in the north and center zone of the metropolitan area. In contrast, the surrounding rural fields show a lower impact grade. The higher concentrations of Pb, Cu, Zn and Ba were observed as being related to high vehicular traffic, nevertheless other elements such as Co, Cr, Ni and V do not show anthropogenic influence and their content can be attributed to the parental rock. The results are compared with previous surveys carried out in 2003 in order to evaluate temporal deposition trends. No changes were found on reported concentrations except for Cu and Zn, whose concentration has increased in later years. The results suggest that spatial distribution analysis and results in comparison with previous studies could be useful for the management and sustainable development of the metropolitan area of Mexico City.     

The formation of porphyry copper deposits

Copper is a moderately incompatible chalcophile element. Its behavior is strongly controlled by sulfides. The speciation of sulfur is controlled by oxygen fugacity. Therefore, porphyry Cu deposits are usually oxidized (with oxygen fugacities > ΔFMQ +2) (Mungall 2002; Sun et al. 2015). The problem is that while most of the magmas at convergent margins are highly oxidized, porphyry Cu deposits are very rare, suggesting that high oxygen fugacity alone is not sufficient. Partial melting of mantle peridotite even at very high oxygen fugacities forms arc magmas with initial Cu contents too low to form porphyry Cu deposits directly (Lee et al. 2012; Wilkinson 2013). Here we show that partial melting of subducted young oceanic slabs at high oxygen fugacity (>ΔFMQ +2) may form magmas with initial Cu contents up to >500 ppm, favorable for porphyry mineralization. Pre-enrichment of Cu through sulfide saturation and accumulation is not necessarily beneficial to porphyry Cu mineralization. In contrast, re-melting of porphyritic hydrothermal sulfide associated with iron oxides may have major contributions to porphyry deposits. Thick overriding continental crust reduces the “leakage” of hydrothermal fluids, thereby promoting porphyry mineralization. Nevertheless, it is also more difficult for ore forming fluids to penetrate the thick continental crust to reach the depths of 2–4 km where porphyry deposits form.     

Contamination and distribution of heavy metals in urban and suburban soils in Zhangzhou City,Fujian, China

The urban environment is of growing concern as its continued population increase in China. Due to the urbanization and industrialization, heavy metals have been continuously discharged into the soil recently, and creating the anthropogenic contamination. This study investigated heavy metals contamination in urban and suburban soils in Zhangzhou City, Fujian, China. Multivariate analysis and geographical information system technology were employed in source identification and contamination assessment of heavy metals in the city soils. The survey results indicated that the urban soils were contaminated by heavy metals, especially by Hg, Cd and Pb. The multivariate analysis demonstrated that the distribution of Cu, Zn, Cr and Ni was controlled by pedogenesis, Cd and Pb had been disturbed by industrialization in some urban locations, and Hg was mainly influenced by the hot-spring in some urban park sites. The distribution of heavy metals and soil pollution index suggested the soils of Zhangzhou City have been affected by human activities.     

Raman spectra of methane hydrate up to 86 GPa

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.     

Hydrogeology and sustainable future groundwater abstraction from the Agua Verde aquifer in the Atacama Desert,northern Chile

The hyper-arid conditions prevailing in Agua Verde aquifer in northern Chile make this system the most important water source for nearby towns and mining industries. Due to the growing demand for water in this region, recharge is investigated along with the impact of intense pumping activity in this aquifer. A conceptual model of the hydrogeological system is developed and implemented into a two-dimensional groundwater-flow numerical model. To assess the impact of climate change and groundwater extraction, several scenarios are simulated considering variations in both aquifer recharge and withdrawals. The estimated average groundwater lateral recharge from Precordillera (pre-mountain range) is about 4,482 m³/day. The scenarios that consider an increase of water withdrawal show a non-sustainable groundwater consumption leading to an over-exploitation of the resource, because the outflows surpasses inflows, causing storage depletion. The greater the depletion, the larger the impact of recharge reduction caused by the considered future climate change. This result indicates that the combined effects of such factors may have a severe impact on groundwater availability as found in other groundwater-dependent regions located in arid environments. Furthermore, the scenarios that consider a reduction of the extraction flow rate show that it may be possible to partially alleviate the damage already caused to the aquifer by the continuous extractions since 1974, and it can partially counteract climate change impacts on future groundwater availability caused by a decrease in precipitation (and so in recharge), if the desalination plant in Taltal increases its capacity.     

Effectiveness of Mg–Al-layered double hydroxide for heavy metal removal from mine wastewater and sludge volume reduction

Health hazards from heavy metal pollution in water systems are a global environmental problem. Of similar concern is sludge that results from wastewater treatment due to unsatisfactory sludge management technology. Therefore, the effectiveness of using Mg–Al-layered double hydroxide in the removal of heavy metals from mine wastewater was tested and compared with that of calcium hydroxide [Ca(OH)₂], which is a common treatment method for heavy metal removal. Initially, the mine wastewater contained cations of the heavy metals iron (Fe), zinc (Zn), copper (Cu), and lead (Pb). The Mg–Al-layered double hydroxides were able to remove 371, 7.2, 121, and 0.4 mg/L of these pollutants, respectively, using the co-precipitation method. The removal of these metals is most effective using 0.5 g Mg–Al-layered double hydroxide (Mg/Al molar ratio 4) and 20 min of shaking. Zn was removed by the formation of Zn(NO₃)(OH)·H₂O and Zn₅(NO₃)₂(OH)₈ when LDH, Mg/Al molar ratios of 4 and 2, respectively, were used. Similarly, Fe, Cu, and Pb were removed by the formation of Fe–Al-layered double hydroxide, Cu₂(OH)₃·NO₃ and Pb₄(OH)₄(NO₃)₄, respectively. While Ca(OH)₂ is also capable of reducing the heavy metal concentrations below the Japanese recommended values, this analysis shows that using 0.5 g Mg–Al-layered double hydroxide is a better treatment condition for mine wastewater, because it generates lower sludge volumes than 0.1 g of Ca(OH)₂. The measured sludge volume was 1.5 mL for Mg–Al-layered double hydroxide and 2.5 mL for Ca(OH)₂, a nearly twofold further reduction.     

Hydrogeochemical effects of secondary forest in Guangxi Nongla karst areas in China

Rainfall, throughfall, stemflow and spring were studied in a secondary forest during a wet season from April to August in 2006. Some of the chemicals in throughfall, stemflow and spring were increased in contrast with incident rainfall. Specifically, Cl⁻, HCO₃ ⁻, Na⁺ and Ca²⁺ were leached negatively in throughfall, but K⁺ and Mg²⁺ were leached positively. In stemflow, Cl⁻ and Na⁺ were leached negatively, the others were leached positively and their concentrations were higher than those in throughfall. Total carbon, organic carbon and inorganic carbon in throughfall and stemflow were increased as rainfall went through the secondary forest. The concentration of free CO₂ in rainfall was lower than both, throughfall and stemflow; the relationship between total acidity and free CO₂ was linear. pH of throughfall and stemflow , such as maximum, minimum and mean, were lower than that of rainfall and the extent of pH in spring was changed minimally. We came to a conclusion that rainfall via the secondary forest can lead to further erosion, accelerate the biogeochemical cycle in epikarst zone, enhance the effective state of alkali elements in the soil, supply vegetation with more nutrients and advance vegetation’s growth and succession, which are reasonably sufficient to form a stable karst ecosystem.     

多功能定时控制器的设计

介绍了一种多功能定时控制器的设计方法,它是由８９Ｃ５１单片机和几个主要的集成电路芯片构成,并给出了监控软件的结构框图。     

A simplified analytical model for run-out prediction of flow slides in municipal solid waste landfills

Flow slides in municipal solid waste (MSW) landfills are common geoenvironmental issues in the urban environment and can pose a serious threat to the surrounding population and infrastructure. Prediction of the maximum run-out distance of flow slides in MSW landfills is therefore an essential part of hazard and risk assessment in engineering design. Based on the framework for simple analysis originally developed by Hungr (1995), we propose a simplified analytical model for calculating dam breaks in a plastic fluid along a single inclined base. In the proposed model, a quarter-elliptical shape is used to describe the approximate configuration of the flow slide. Following this step, the physical laws relating to the conservation of mass and energy are used to calculate the potential flow. Of additional note is a boundary condition in mathematics relating to this simplified analytical model, which is also reported in this study. Taking the obvious mobility characteristics of the MSW at point of failure into consideration, a three-phase simplified model along double inclined bases has been further developed for run-out prediction of the flow slide in MSW landfill. The proposed three-phase model is then applied to estimate the maximum run-out distance of two typical flow failures of landfills located in Sarajevo and Bandung, which demonstrate the capability of the proposed simplified analytical model for use in hazard assessments of landfills.