The future of artificial satellite theories Hybrid ephemeris compression model

Since the time of Newton, astrodynamics has focused on the analytical solution of orbital problems. This was driven by the desire to obtain a theoretical understanding of the motion and the practical desire to be able to produce a computational result, Only with the advent of the computer did numerical integration become a practical consideration for solving dynamical problems. Although computer technology is not yet to the point of being able to provide numerical integration support for all satellite orbits, we are in a transition period which is being driven by the unprecedented increase in computational power, This transition will affect the future of analytical, semi-analytical and numerical artificial satellite theories in a dramatic way, In fact, the role for semi-analytical theories may disappear. During the time of transition, a central site may have the capacity to maintain the orbits using numerical integration, but the user may not have such a capacity or may need results in a more timely manner, One way to provide for this transition need is through the use of some type of satellite ephemeris compression. Through the combined use of a power series and a Fourier series, good quality ephemeris compression has been achieved for 7 day periods, The ephemeris compression requires less than 40 terms and is valid for all eccentricities and inclinations.     

Atmospheric C variations derived from tree rings during the early Younger Dryas

Atmospheric radiocarbon variations over the Younger Dryas interval, from 13,000 to 11,600 cal yr BP, are of immense scientific interest because they reveal crucial information about the linkages between climate, ocean circulation and the carbon cycle. However, no direct and reliable atmospheric ¹⁴C records based on tree rings for the entire Younger Dryas have been available. In this paper, we present (1) high-precision ¹⁴C measurements on the extension of absolute tree-ring chronology from 12,400 to 12,560 cal yr BP and (2) high-precision, high-resolution atmospheric ¹⁴C record derived from a 617-yr-long tree-ring chronology of Huon pine from Tasmania, Australia, spanning the early Younger Dryas. The new tree-ring ¹⁴C records bridge the current gap in European tree-ring radiocarbon chronologies during the early Younger Dryas, linking the floating Lateglacial Pine record to the absolute tree-ring timescale. A continuous and reliable atmospheric ¹⁴C record for the past 14,000 cal yr BP including the Younger Dryas is now available. The new records indicate that the abrupt rise in atmospheric Δ¹⁴C associated with the Younger Dryas onset occurs at 12,760 cal yr BP, 240 yrs later than that recorded in Cariaco varves, with a smaller magnitude of 40‰ followed by several centennial Δ¹⁴C variations of 20–25‰. Comparing the tree-ring Δ¹⁴C to marine-derived Δ¹⁴C and modelled Δ¹⁴C based on ice-core ¹⁰Be fluxes, we conclude that changes in ocean circulation were mainly responsible for the Younger Dryas onset, while a combination of changes in ocean circulation and ¹⁴C production rate were responsible for atmospheric Δ¹⁴C variations for the remainder of the Younger Dryas.     

Regime-dependent evaluation of accumulated precipitation in COSMO

Regime-dependent evaluation is a relatively new approach to assess model performance. It consists of classifying the model biases according to a discrete number of regimes and evaluating model output within each regime. In this paper, the regimes are firstly defined by the large-scale atmospheric circulation, based on the objective Jenkinson-Collison classification technique which distinguishes synoptic patterns by strength, direction and vorticity of the geostrophic flow. Eight directional and two vorticity circulation regimes (circulation types) are specified. In this way, it is possible to quantify the model performance for cases with for example westerly winds only, or with cyclonic circulation only. A second regime classification is based on temperature, which allows for detection of temperature-dependent model performance. Modelled accumulated precipitation (mm/6?h) is evaluated with rain gauges for the years 2007 and 2008. Two variants of the COSMO model are evaluated: a fine-resolution version (2.8?km, COSMO-DE) and a coarse-resolution version (7?km, COSMO-EU). In COSMO-EU, a windward/leeward effect becomes visible since circulation is related to dominant wind direction, hence to windward and lee side of orography. In COSMO-DE, no circulation dependent but a height-related bias is identified and further explored, making use of temperature-dependent evaluation which unveils a positive model bias related to solid precipitation.     

U–Pb LA-SF-ICP-MS zircon geochronology of the Serbo-Macedonian Massif, Greece: palaeotectonic constraints for Gondwana-derived terranes in the Eastern Mediterranean

The Pirgadikia Terrane in northern Greece forms tectonic inliers within the Vardar suture zone bordering the Serbo-Macedonian Massif to the southwest. It comprises Cadomian basement rocks of volcanic-arc origin and very mature quartz-rich metasedimentary rocks. U–Pb laser ablation sector-field inductively-coupled plasma mass spectrometry analyses of detrital zircons from the latter reveal a marked input from a Cadomian–Pan-African source with minor contribution from Mesoproterozoic, Palaeoproterozoic and Archaean sources. The metasedimentary rocks are correlated with Ordovician overlap sequences at the northern margin of Gondwana on the basis of their maturity and zircon age spectra. The Pirgadikia Terrane can be best interpreted as a peri-Gondwana terrane of Avalonian origin, which was situated close to the Cadomian terranes in the Late Neoproterozoic–Early Palaeozoic, very much like the Istanbul Terrane. The second unit investigated is the Vertiskos Terrane, which constitutes the major part of the Serbo-Macedonian Massif in Greece. It comprises predominantly igneous rocks of Silurian age and minor metasedimentary rocks of unknown age and provenance. U–Pb analyses of detrital zircons from a garnetiferous mica schist of the Vertiskos Terrane indicate derivation from 550 to 1,150 Ma-old source rocks with a major Cadomian peak. This, combined with minor input of >1,950 Ma-old zircons and the absence of ages between ca. 1.2 and 1.7 Ga suggests a NW Africa source. The protolith age of the garnetiferous mica schist is presumably Early Ordovician. One sample of garnet-bearing biotite gneiss, interpreted as meta-igneous rock, comprises predominantly subhedral zircons of igneous origin with late Middle Ordovician to Silurian ages. We suggest that the rock association of the Vertiskos Terrane is part of an ancient active-margin succession of the Hun superterrane, comparable to successions of the Austro- and Intra-Alpine Terranes. The new data of this study provide evidence of occurrences of Avalonia- and Armorica-derived terranes in the Eastern Mediterranean and moreover help to clarify palaeogeographic reconstructions for the peri-Gondwana realm in the Early Palaeozoic.     

Capital and Empire: Geographies of Imperial London

The notion of empire has often been regarded in Europe as a matter of diffusion and expansion; something which happened over there rather than close to home. Yet the form, use and representation of modern European cities have been shaped by the global history of imperialism in ways that continue to matter even in an apparently post-imperial age. The signs of empire were prominently displayed within the built environments of all the major cities of late-nineteenth century Europe, as they came (in different ways) to play the role of regional, national and imperial capitals. In what was evidently a pan-European discourse on the imperial city between the mid-nineteenth century and the mid-twentieth, national models were defined in relation to other national models, in a spirit of competition as much as emulation. This paper examines the case of London. British architects and planners frequently complained that London lagged behind its rivals in the struggle for imperial primacy, given the absence of state-sponsored projects to parallel Haussmann's rebuilding of Paris or Leopold's grand plans for Brussels. At the intra-urban scale, the imperial city had a geography which mattered: in the case of London, different parts of the city were associated with different aspects of empire. More generally, it is clear that national debates over imperial urbanism were conditioned not simply by understandings of the global reach of European empires, but also by attitudes towards social, cultural and political change within Europe itself.     

Column tests to enhance sulphide precipitation with liquid organic electron donators to remediate AMD-influenced groundwater

Dump groundwaters in the former East-German lignite-mining district are characterized by high amounts of ferrous iron and sulphate. Both the pyrite weathering products endanger the surface water quality when discharged into lakes. Only the precipitation of both contaminants in the subsurface can prevent the further contamination of surface waters. The two-step process of microbial catalyzed sulphate reduction and iron sulphide precipitation is limited by the low availability of natural organic substances as electron donators. Therefore, a new remediation technique is developed based on the injection of a liquid organic electron donator (methanol) into the contaminated aquifer. The saturated aquifer is used as a bioreactor, where iron monosulphides are precipitated in the groundwater-filled pore space. Column experiments were performed under natural pressure and temperature conditions with natural anoxic groundwater and original sediments to test the remediation technology. The test showed that a complete iron removal (4 mmol/l), even under rather acid conditions (pH 3.8), is possible after having established an active sulphate reducer population. The turnover of the added organic substance with sulphate is complete and the amount of the resulting sulphide controls the effluent pH. In addition, intensified microbial activity triggers the turnover of natural organic substances. Also, natural Fe(III) hydroxides react with the sulphide produced. Considering the long natural retention times (decades), artificially enhanced FeS precipitation is spontaneous, although it shows kinetic behaviour in the range of days. In light of the promising results, the development of a field scale application of this technique is considered to be necessary. It will have to focus on the improved precipitation control of the FeS in the subsurface.     

Cyclicities in Triassic platform carbonates: synchronizing radio-isotopic and orbital clocks

ABSTRACT Sedimentary cycles recorded in young sediments are often attributed to fluctuations of the Earth's climate on a 10⁴−10⁶-year scale which in turn is governed by periodic variations in solar insolation linked to orbital (Milankovitch) parameters. A spectacular example of cyclic stratal patterns in ancient deposits is the Middle Triassic Latemar carbonate platform (W Dolomites, N Italy). Based on spectral analyses from previous studies, a superimposition of precession (∼20 ka) and eccentricity (∼100 ka) controlled sea-level fluctuations has been suggested to account for the stacking hierarchy at Latemar, with ∼20 ka being assigned to each highest-order depositional cycle. Zircon U–Pb isotopic ages from volcanic-ash layers within the cyclic succession, corroborated by biostratigraphic constraints, suggest that the average time interval for every individual cycle is significantly smaller than the shortest Milankovitch period and therefore challenge previously published interpretations relating distinct spectral peaks to the above mentioned hierarchy. However, our new spectral data indicate that cyclicities resembling Milankovitch characteristics might exist, but on an entirely different scale. Our findings show that frequency spectra should only be interpreted in combination with robust age control. They also encourage the search for complementary mechanisms controlling carbonate deposition.     

The relationship between the distribution of nitrogen impurity centres in diamond crystals and their internal structure and mechanism of growth

Fifty diamond crystals of different morphological types (octahedra, dodecahedroids, cubes and single tetrahexahedroid) with differing internal structures were examined using methods of cathodoluminescence (CL), anomalous birefringence and local infrared (IR) analysis. The main objective of the study was to examine the regularities of nitrogen impurity distribution in diamond with differing internal structures. Almost all the analyzed octahedra, as well as dodecahedroids with zonal structures and the blocky dodecahedroids, are characterized either by nearly isothermic growth conditions or by a decrease in formation temperature during the crystallization process. In contrast to zoned octahedra and dodecahedroids, dodecahedroids with zonal–sectorial and sectorial internal structures show a notably different distribution of nitrogen defects, with N_tot generally decreasing from crystal cores to marginal areas, and degree of nitrogen aggregation increasing in the same direction. From this, it would follow that in these crystals, the temperature of diamond formation of the outer crystal zones is approximately 40–50 °C higher than that of the inner zones. The same result (15 to 80 °C) was obtained for diamond crystals with cubic habit, which generally show a fibrous internal structure, reflecting normal mechanisms of growth. The anomalous distribution of nitrogen centres in diamond crystals that grew through the normal mechanism, with a high rate of growth and in an oversaturated medium, might point to non-equilibrium relationships between the concentrations of different nitrogen centres. It is likely that in crystals of this type, the rate of growth is higher than the rate of structural nitrogen aggregation. Thus, it appears that in these peculiar crystals of diamond we deal with non-equilibrium concentrations of nitrogen B centres and, consequently, with anomalous, non-actual diamond formation temperatures.     

Neoproterozoic ‘anomalous’ kimberlites of Guaniamo, Venezuela: Mica kimberlites of ‘isotopic transitional’ type

In Venezuela, kimberlites have so far only been found in the Guaniamo region, where they occur as high diamond grade sheets in massive to steeply foliated Paleoproterozoic granitoid rocks. The emplacement age of the Guaniamo kimberlites is 712±6 Ma, i.e., Neoproterozoic. The Guaniamo kimberlites contain a high abundance of mantle minerals, with greater than 30% olivine macrocrysts. The principal kimberlite indicator minerals found are pyrope garnet and chromian spinel, with the overwhelming majority of the garnets being of the peridotite association. Chrome-diopside is rare, and picroilmenite is uncommon. Chemically, the Guaniamo kimberlites are characterized by high MgO contents, with low Al₂O₃ and TiO₂ contents and higher than average FeO and K₂O contents. These rocks have above average Ni, Cr, Co, Th, Nb, Ta, Sr and LREE concentrations and very low P, Y and, particularly, Zr and Hf contents. The Nb/Zr ratio is very distinctive and is similar to that of the Aries, Australia kimberlite. The Guaniamo kimberlites are similar in petrography, mineralogy and mantle mineral content to ilmenite-free Group 2 mica kimberlites of South Africa. The Nd-Sr isotopic characteristics of Guaniamo kimberlites are distinct from both kimberlite Group 1 and Group 2, being more similar to transitional type kimberlites, and in particular to diamondiferous kimberlites of the Arkhangelsk Diamond Province, Russia. The Guaniamo kimberlites form part of a compositional spectrum between other standard kimberlite reference groups. They formed from metasomatised subcontinental lithospheric mantle and it is likely that subduction of oceanic crust was the source of this metasomatised material, and also of the eclogitic component, which is dominant in Guaniamo diamonds.