A survey of groundwater quality in Tulum region,Yucatan Peninsula,Mexico

The city of Tulum, in the state of Quintana Roo (Mexico) depends almost exclusively on groundwater for water supply. The groundwater is exploited from a coastal aquifer which contains a karst network that is considered as one of the largest ones on earth. Given the nature of karst aquifers, the whole area is very sensitive to contaminants and bacteria transport, because flow paths, residence time and degradation rates differ significantly from what can be observed in the porous aquifer. The present study focuses on isotopes (¹⁸O and ²H), dissolved ions’ concentration and Escherichia coli (E. coli). The result of our survey points out the anthropic impact on groundwater quality. Furthermore, the chloride concentrations illustrate the influence of seawater mixing and geological heterogeneity over the study area. Due to an exponential growth of the tourism industry, the needs in terms of water supply and water treatment increase significantly. Tulum is a coastal city, facing a coral reef and is bordered by the Sian Ka’an biosphere reserve, therefore, an environmental issue is added to the sanitary issue, both being the basis of the local economic development. Our results show that E. coli remains a major issue, as several samples tested were contaminated, in particular those in the city center. Ions’ survey shows an anthropic impact through nitrate, phosphate and fluoride concentrations, but the obtained values are not alarming. Considering the saline intrusion, chloride concentrations indicate that the area below the Tulum city center seems to be less permeable (and maybe less karstified) than the surrounding areas, as groundwater is less subject to seawater mixing than other sampling sites at similar distance to the coast.     

Orthopyroxene oikocrysts in the MG1 chromitite layer of the Bushveld Complex: implications for cumulate formation and recrystallisation

Two typical mineral textures of the MG 1 chromitite of the Bushveld Complex, South Africa, were observed; one characterised by abundant orthopyroxene oikocrysts, and the other by coarse-grained granular chromitite with only minor amounts of interstitial material. Oikocrysts form elongate clusters of several crystals aligned parallel to the layering, and typically have subhedral, almost chromite-free, core zones containing remnants of olivine. The core zones are surrounded by poikilitic aureoles overgrowing euhedral to subhedral chromite chadacrysts. Chromite grains show no preferred crystal orientation, whereas orthopyroxene grains forming clusters commonly share the same crystallographic orientation. Oikocryst core zones have lower Mg# and higher concentrations of incompatible trace elements compared to their poikilitic aureoles. Core zones are relatively enriched in REE compared to a postulated parental magma (B1) and did not crystallise in equilibrium with the surrounding minerals, whereas the composition of the poikilitic orthopyroxene is consistent with growth from the B1 magma. These observations cannot be explained by the classic cumulus and post-cumulus models of oikocryst formation. Instead, we suggest that the oikocryst core zones in the MG1 chromitite layer formed by peritectic replacement of olivine primocrysts by reaction with an upwards-percolating melt enriched in incompatible trace elements. Poikilitic overgrowth on oikocryst core zones occurred in equilibrium with a basaltic melt of B1 composition near the magma-crystal mush interface. Finally, adcumulus crystallisation followed by grain growth resulted in the surrounding granular chromitite.     

PC1 with a broad frequency spectrum — “Goose pulsations”

Geomagnetic pulsations in the frequency range of Pc1 pearl waves with the dynamic spectra having a very narrow spectrum width at the beginning of the event and a very broad spectrum width (Δf/f₀ ∼ 1) in the later part of the event are analyzed. One of the observed events shown by the dynamic spectrum resembles a goose with the beak at the beginning of the event and with the wing in the later part of the event. Various interpretations of these geomagnetic pulsations are presented taking into account nonlinear effects, quasilinear interaction of electromagnetic ion-cyclotron waves with energetic, anisotropic protons and modulation of plasma parameters in the magnetosphere by Pc3–5 hydromagnetic waves. The ionospheric effect in the signal formation is determined by the ionospheric Alfvén resonator. It can control the frequency range of the dynamic spectra, but not the internal structure of the signal.     

Spatial structure of standing wave electromagnetic fields at the lower harmonics of the ionospheric Alfvén resonator

During the multiband wave Pc1 event on March 7, 2001 the EISCAT UHF and VHF incoherent scatter radars operated simultaneously covering an exceptionally wide altitude range of the ionosphere ～90—2000 km. This made possible to test the ionospheric Alfvén resonator (IAR) model over a large altitude range. The three lowest IAR eigenfrequencies, where the most of the Pc1 pulsation signal bands occur, were selected for the spatial analysis of the standing wave electromagnetic fields, applying the full-wave numerical simulation method. The altitude spread of amplitude maxima and nodes together with polarization characteristics of oscillation maxima in the horizontal plane are presented. The comparison of the standing wave oscillations on the altitude profile with the signal amplitude observed on the ground is also presented.     

Reconstructing ice-flow fields from streamlined subglacial bedforms: A kriging approach

The orientation of several landforms, e.g. drumlins, flutes, crag-and-tails, and mega-scale glacial lineations, records the direction of the overlying ice flow that created them. Populations of such features are used routinely to infer former ice-flow patterns, which serve as the building blocks of reconstructions of palaeo ice-sheet evolution. Currently, the conceptualisation of flow patterns from these flow-direction records is done manually and qualitatively, so the extractable glaciological information is limited. We describe a kriging method (with Matlab code implementation) that calculates continuous fields of ice-flow direction, convergence, and curvature from the flow-direction records, and which yields quantitative results with uncertainty estimates. We test the method by application to the subglacial bedforms of the Tweed Valley Basin, UK. The results quantify the convergent flow pattern of the Tweed Palaeo-Ice Stream in detail and pinpoint its former lateral shear margins and where ice flowed around basal bumps. Ice-flow parameters retrieved by this method can enrich ice-sheet reconstructions and investigations of subglacial till processes and bedform genesis. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Time-domain sparsity promoting least-squares reverse time migration with source estimation

Least-squares reverse-time migration is well known for its capability to generate artefact-free true-amplitude subsurface images through fitting observed data in the least-squares sense. However, when applied to realistic imaging problems, this approach is faced with issues related to overfitting and excessive computational costs induced by many wave-equation solves. The fact that the source function is unknown complicates this situation even further. Motivated by recent results in stochastic optimization and transform-domain sparsity promotion, we demonstrate that the computational costs of inversion can be reduced significantly while avoiding imaging artefacts and restoring amplitudes. While powerful, these new approaches do require accurate information on the source-time function, which is often lacking. Without this information, the imaging quality deteriorates rapidly. We address this issue by presenting an approach where the source-time function is estimated on the fly through a technique known as variable projection. Aside from introducing negligible computational overhead, the proposed method is shown to perform well on imaging problems with noisy data and problems that involve complex settings such as salt. In either case, the presented method produces high-resolution high-amplitude fidelity images including an estimate for the source-time function. In addition, due to its use of stochastic optimization, we arrive at these images at roughly one to two times the cost of conventional reverse-time migration involving all data.     

Field expressions of the transformation of debris flows into turbidity currents, with examples from the Polish Carpathians and the French Maritime Alps

Various transformation mechanisms can generate turbidity currents from subaqueous debris flows. Different transformation mechanisms have been described and interpreted in the past from laboratory experiments and from deposits, but the two approaches have not generally been linked. This has made the genetic interpretation and comparison of deposits difficult. In this paper a generic classification scheme of debrite–turbidite couplets is proposed based on transformation mechanisms inferred from laboratory experiments. Five different flow types (called A–E herein) and their resulting deposits are detailed, but they are all part of a continuous spectrum, and a mixture of types is likely to be found in the field. Type A flows are strong, dense debris flows that undergo little transformation. Their deposit will be a debrite overlain by a thin turbidite, which is separated from it by a clear grain size break. Type B flows are weaker and can develop waves at the debris flow-turbidity current interface. The deposit will be a debrite with a wavy top overlain by a turbidite that is thicker than for type A flows. For type C flows, the interfacial waves will grow so much that the debris flow disintegrates into separate parts. The deposit will consist of debrite lenses encased in a turbidite. Type D flows will undergo even more mixing than type C flows so that the debrite parts will be mixed. Their deposit will be a turbidite with laterally varying areas of debrite characteristics near the bed. Type E flows will be so transformed that the debris flow character has disappeared and the flow is a turbidity current with high sediment concentration. The deposit will be largely turbiditic. The flow types and deposits will be illustrated with some examples from two field areas: the Polish Carpathians and the French Maritime Alps.     

Characterization of indoor and outdoor atmospheric pollutants impacting architectural monuments: the case of San Jerónimo Monastery (Granada, Spain)

Indoor and outdoor concentrations of atmospheric gaseous pollutants as well as composition, size, and morphology of particulate matter have been investigated at the monastery of San Jerónimo in Granada (Southern Spain). Complementary micro- and nano-analytical techniques were applied; elemental and mineralogical composition and morphological characteristics of particulate matter were investigated combining electron probe microanalysis at the single particle level, and bulk aerosol samples were analyzed using energy-dispersive X-ray fluorescence, X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray analyzer and transmission electron microscopy (TEM). Microclimatic conditions at the monastery were monitored, and gas concentrations were assessed by means of diffusion tubes subsequently analyzed with ion chromatography. Results revealed high abundances of soil dust particles (aluminosilicates, calcite, dolomite, quartz), salt aerosols (chlorides, sulfates and ammonium-rich salts), and NO₂ and SO₂ both outdoors and indoors. Amorphous black carbon particles had surprisingly high abundances for Granada, a non-industrialized city. The composition of indoor particles corresponds to severe weathering affecting the construction materials and artworks inside the church; moreover their composition promotes a feedback process that intensifies the deterioration. Chemical reactions between chloride-rich salts and pigments from paintings were confirmed by TEM analyses. Indoors, blackening of surface decorative materials is fostered by particle re-suspension due to cleaning habits in the monastery (i.e. dusting). This is the first air quality study performed in a monument in the city of Granada with the aim of developing a strategy for preventive conservation.