Platinum-group elements, S, Se and Cu in highly depleted abyssal peridotites from the Mid-Atlantic Ocean Ridge (ODP Hole 1274A): Influence of hydrothermal and magmatic processes

Highly depleted harzburgites and dunites were recovered from ODP Hole 1274A, near the intersection between the Mid-Atlantic Ocean Ridge and the 15°20′N Fracture Zone. In addition to high degrees of partial melting, these peridotites underwent multiple episodes of melt–rock reaction and intense serpentinization and seawater alteration close to the seafloor. Low concentrations of Se, Cu and platinum-group elements (PGE) in harzburgites drilled at around 35–85 m below seafloor are consistent with the consumption of mantle sulfides after high degrees (>15–20 %) of partial melting and redistribution of chalcophile and siderophile elements into PGE-rich residual microphases. Higher concentrations of Cu, Se, Ru, Rh and Pd in harzburgites from the uppermost and lowest cores testify to late reaction with a sulfide melt. Dunites were formed by percolation of silica- and sulfur-undersaturated melts into low-Se harzburgites. Platinum-group and chalcophile elements were not mobilized during dunite formation and mostly preserve the signature of precursor harzburgites, except for higher Ru and lower Pt contents caused by precipitation and removal of platinum-group minerals. During serpentinization at low temperature (<250 °C) and reducing conditions, mantle sulfides experienced desulfurization to S-poor sulfides (mainly heazlewoodite) and awaruite. Contrary to Se and Cu, sulfur does not record the magmatic evolution of peridotites but was mostly added in hydrothermal sulfides and sulfate from seawater. Platinum-group elements were unaffected by post-magmatic low-temperature processes, except Pt and Pd that may have been slightly remobilized during oxidative seawater alteration.     

A multidimensional fuzzy least-squares regression approach for estimating hydraulic gradients in unconfined aquifer formations and its application to the Gulf Coast aquifer in Goliad County,Texas

Epistemic uncertainties arise during the estimation of hydraulic gradients in unconfined aquifers due to planar approximation of the water table as well as data gaps arising from factors such as instrument failures and site inaccessibility. A multidimensional fuzzy least-squares regression approach is proposed here to estimate hydraulic gradients in situations where epistemic uncertainty is present in the observed water table measurements. The hydraulic head at a well is treated as a normal (Gaussian) fuzzy variable characterized by a most likely value and a spread. This treatment results in hydraulic gradients being characterized as normal fuzzy numbers as well. The multidimensional fuzzy least-squares regression has an exact analytical form and as such can be implemented easily using matrix algebra methods. However, the method was noted to be sensitive to round-off and truncation errors when the epistemic uncertainties are small. A closeness index based on the cardinality of a fuzzy number is used to evaluate how well the regression model fits the fuzzy hydraulic head observations. A fuzzy Euclidian distance measure is used to compare two fuzzy numbers and to evaluate how fuzziness in the observed hydraulic heads affects the fuzziness in the estimated hydraulic gradients. The Euclidian distance measure is also used to ascertain the influence of each well on the fuzzy hydraulic gradient estimation. The fuzzy regression framework is illustrated by applying it to evaluate hydraulic gradients in the unconfined portion of the Gulf Coast aquifer in Goliad County, TX. The results from the case-study indicate that there is greater uncertainty associated with the estimation of the hydraulic gradients in the vertical (Z-axis) direction. The epistemic uncertainties in the hydraulic head data at the wells have a significant impact on the gradient estimates when they are of the same order of magnitude as the most likely values of the observed heads. The influence analysis indicated that 5 of the 13 wells in the network had a critical influence on at least one of the hydraulic gradients. Three wells along the northeastern section of the study area and bordering the Victoria County were noted to have the least influence on the regression estimates. The fuzzy regression framework along with the associated goodness-of-fit and influence measures provides a useful set of tools to characterize the uncertainties in the hydraulic heads and gradients arising from data gaps and planar water table approximation.     

The Coupling State of an Idealized Stable Boundary Layer

The coupling state between the surface and the top of the stable boundary layer (SBL) is investigated using four different schemes to represent the turbulent exchange. An idealized SBL is assumed, with fixed wind speed and temperature at its top. At the surface, two cases are considered, first a constant temperature, 20 K lower than the SBL top, and later a constant 2 K h⁻¹ cooling rate is assumed for 10 h after a neutral initial condition. The idealized conditions have been chosen to isolate the influence of the turbulence formulations on the coupling state, and the intense stratification has the purpose of enhancing such a response. The formulations compared are those that solve a prognostic equation for turbulent kinetic energy (TKE) and those that directly prescribe turbulence intensity as a function of atmospheric stability. Two TKE formulations are considered, with and without a dependence of the exchange coefficients on stability, while short and long tail stability functions (SFs) are also compared. In each case, the dependence on the wind speed at the SBL top is considered and it is shown that, for all formulations, the SBL experiences a transition from a decoupled state to a coupled state at an intermediate value of mechanical forcing. The vertical profiles of potential temperature, wind speed and turbulence intensity are shown as a function of the wind speed at the SBL top, both for the decoupled and coupled states. The formulation influence on the coupling state is analyzed and it is concluded that, in general, the simple TKE formulation has a better response, although it also tends to overestimate turbulent mixing. The consequences are discussed.     

Sampling Strategies for Uncertainty Reduction in Categorical Random Fields: Formulation,Mathematical Analysis and Application to Multiple-Point Simulations

Mathematical Geosciences - The task of optimal sampling for the statistical simulation of a discrete random field is addressed from the perspective of minimizing the posterior uncertainty of...     

HVSR estimation of site effects in Melilla (Spain) and the damage pattern from the 01/25/2016 Mw 6.3 Alborán Sea earthquake

The January 25, 2016, Mw 6.3 Alborán Sea earthquake shook the autonomous city of Melilla (Spain) with a macro-seismic intensity of VI (EMS-98). In spite of this low intensity, significant non-structural damages were reported, whose cost was estimated in more than 13 million euros. The damages were concentrated in the modernist district, which is considered the most important and valuable part of the city. This scenario is not new in Melilla, since historical and instrumental seismicity studies based on intensities felt in Melilla have revealed that earthquakes with intensities of V–VI have a return period of approximately 25 years. However, seismic microzonation studies have not been carried out so far. In this paper, we present a seismic microzonation study based on seismic noise measurements and the foreshock, mainshock and aftershock records of the January 25, 2016, earthquake. The seismic signals were processed using the horizontal-to-vertical spectral ratio (HVSR) technique. The frequency amplification results were correlated with geological formations, and after that they were correlated with the distribution of damages. The lagoon and the recent alluvial deposits show the maximum number of damaged buildings and maximum frequency amplifications of 2–8 between 2 and 7 Hz. In the coastal deposits, some amplification in the same frequency range has been observed, but other formations show a minimum number of damaged buildings and a flat spectral response ratio. Two important factors in this damage pattern are the high vulnerability of ornamental facades characteristics (non-structural elements) of the modern architecture buildings and their location on the lagoon and the recent alluvial deposits where maximum site amplification is reached.

     

Speciation and Kinetics of Trihalomethane Formation in Drinking Water in Mexico

Water chlorination continues to be one of the most common water disinfection processes, especially in developing countries. When natural organic matter (NOM) is present, the process produces disinfection by-products (DBPs), some of them being trihalomethanes (THMs). This study determined the presence, speciation, and kinetics of THMs formation in the water supply for the northern area of the city of Toluca, Mexico. The results show that the concentrations of THMs are below the maximum allowable limits of 200 μg/L in accordance with NOM-127-SSA1-1994. Regarding THMs speciation, the presence of chloroform was more frequently observed in domestic water; furthermore, in one sample in which bromoform was present, it dominated over the chlorine species. Regarding the kinetics of THMs formation, a maximum concentration of THMs (THMs_Max) of 13.02 μg/L was obtained, and the time required to reach 50% THMs_Max ( t ₅₀) was 39.45 min.