The potential use of spent coffee ground (SCG) for the removal of copper has been investigated as a low‐cost adsorbent for the biosorption of heavy metals. Adsorption batch experiments were conducted to determine isotherms and kinetics. The biosorption equilibrium data were found to fit well the Freundlich model and an experimental maximum biosorption capacity of copper ions 0.214 mmol/g was achieved. The biosorption kinetics of SCG was studied at different adsorbate concentrations (0.1–1.0 mM) and stirring speeds (100–400/min). The results showed an increase in the copper ion uptake with raising the initial metal concentration and the kinetic data followed the pseudo‐second order rate expression. The effect of stirring speed was a significant factor for the external mass transfer resistance at 100/min and coefficients were estimated by the Mathews and Weber model. Biosorption of copper ions onto SCG was observed to be related mainly with the release of calcium and hydrogen ions suggesting that biosorption performance by SCG can be attributed to ion‐exchange mechanism with calcium and hydrogen ions neutralizing the carboxyl and hydroxyl groups of the biomass. 相似文献
Analytical pyrolysis-GC/MS and solid-state 13C NMR (nuclear magnetic resonance) were applied to the NaOH-extractable organic matter fraction of a colluvial soil from Galicia (NW Spain) that represents more than 8500 yr of accumulation. While molecular indicators of vegetation change were looked for, it seemed likely that any such signal was disturbed by the intense fire regime of the area. This conclusion was drawn from (1) the presence of three charcoal layers, (2) the high proportion of aryl C in NMR spectra (non-quantitative) and (3) the prevalence of benzenes and polycyclic aromatic hydrocarbons (PAHs) in the chromatograms (38 ± 6% of total identified peak area), also in charcoal-poor samples. If this conclusion is accurate, the area has been subjected to burning episodes for at least 8000 yr. Additionally, the results indicate that biomass burning residues (black carbon; BC) may become NaOH extractable after long periods of degradation in mineral soil. These results add to our knowledge of the long-term fate of BC in soil, which is a potential agent in the global C cycle. 相似文献
The Atlantic Forest biome has only 13 percent of its pristine vegetation cover left. This article analyzes the consequences of land changes on forest cover in the Paraíba Valley, São Paulo state, Brazil, from 1985 to 2011. Multitemporal satellite image classifications were carried out to map eight land use and land cover classes. The forest cover increased from 2,696 km2 in 1985 to 4,704 km2 in 2011, mostly over areas of degraded pastures. The highest rates of afforestation were observed within protected areas around eucalyptus plantations. On the other hand, deforestation processes were concentrated on areas covered by secondary forests. Socioeconomic changes taking place in particular Brazilian settings, such as industrialization and agricultural modernization, allied to the Paraíba Valley's natural biophysical constraints for agricultural production, have led the region to experience a remarkable case of forest transition. 相似文献
Mineral deposit grades are usually estimated using data from samples of rock cores extracted from drill holes. Commonly, mineral deposit grade estimates are required for each block to be mined. Every estimated grade has always a corresponding error when compared against real grades of blocks. The error depends on various factors, among which the most important is the number of correlated samples used for estimation. Samples may be collected on a regular sampling grid and, as the spacing between samples decreases, the error of grade estimated from the data generally decreases. Sampling can be expensive. The maximum distance between samples that provides an acceptable error of grade estimate is useful for deciding how many samples are adequate. The error also depends on the geometry of a block, as lower errors would be expected when estimating the grade of large-volume blocks, and on the variability of the data within the region of the blocks. Local variability is measured in this study using the coefficient of variation (CV). We show charts analyzing error in block grade estimates as a function of sampling grid (obtained by geostatistical simulation), for various block dimensions (volumes) and for a given CV interval. These charts show results for two different attributes (Au and Ni) of two different deposits. The results show that similar errors were found for the two deposits, although they share similar features: sampling grid, block volume, CV, and continuity model. Consequently, the error for other attributes with similar features could be obtained from a single chart. 相似文献
Large-scale impacts from natural disasters suffered by society encourage researchers and public agencies to develop methods to evaluate, mitigate, respond, and recover from these events. A key aspect for the calculation of the potential earthquake losses is to properly describe the characteristics and value of assets exposed to seismic hazard. This article describes a methodology to develop an exposure model at a census-block resolution for residential structures in Chile using statistical data. The methodology is based on three steps: (1) obtaining dwelling count, construction material and location from census data, (2) defining classification rules for dwellings associated with houses and apartment buildings, and (3) assigning structural typologies and replacement cost. The resulting exposure model consists of a database with the number of residential structures classified into 18 structural typologies at each census block and the associated replacement cost. A total of 4,259,804 residential structures were identified in the national exposure model. Overall, clay brick and concrete block masonry account for 53.5 % of the structures of the country followed by timber (33.7 %), reinforced concrete (8.1 %), and adobe (4.6 %). Also, a methodology using remote digital survey techniques is proposed and used to obtain local exposure models for the cities of Iquique, Rancagua, and Osorno. The results of the national exposure model are compared with the local exposure models. An important feature of the proposed methodologies is that the building stock is classified into structural typologies, which is a key aspect for conducting seismic risk assessment. The methodologies used to construct the national and local exposure models may be extrapolated to other countries by adjusting the classification rules. The exposure models that were constructed represent an important input for risk calculations, by improving the technical capabilities for seismic risk management of the country.
Natural Hazards - Debris flows represent great hazard to humans due to their high destructive power. Understanding their hydrogeomorphic dynamics is fundamental in hazard assessment studies,... 相似文献
This paper presents the experience of a service-learning course which used community geography to study a proposed research and community center in DeKalb, IL. The center was proposed as a jointly-developed project by the Northern Illinois University and local governmental entities. The original goal of the course was to explore the viability of the proposed project and solicit feedback from the community through traditional engaged planning and public participation. As students began interacting with university and residential communities, it became clear that both communities had input for the center, and found similarities in their experiences and perceptions. While noted divisions in interest groups are known in DeKalb, both communities found themselves surprisingly interested in meaningful discussion to better understand each other through their shared experiences. In response, our theoretical approach shifted to community geography. Students, university employees, and local residents introduced and analyzed questions together as researchers and participants, and developed recommendations to address shared concern. Students then prepared a report advocating for those concerns to submit to university and community leaders. Following the evolution of this project, this paper presents lessons learned and areas for application of community geography as a pedagogical technique, as an important component of geography curriculum, and as a research framework for town-gown relationship inquiry.
One of the main questions on Neoproterozoic geology regards the extent and dynamics of the glacial systems that are recorded in all continents. We present evidence for short transport distances and localized sediment sources for the Bebedouro Formation, which records Neoproterozoic glaciomarine sedimentation in the central-eastern São Francisco Craton (SFC), Brazil. New data are presented on clast composition, based on point counting in thin section and SHRIMP dating of pebbles and detrital zircon. Cluster analysis of clast compositional data revealed a pronounced spatial variability of clast composition on diamictite indicating the presence of individual glaciers or ice streams feeding the basin. Detrital zircon ages reveal distinct populations of Archean and Palaeoproterozoic age. The youngest detrital zircon dated at 874 ± 9 Ma constrains the maximum depositional age of these diamictites. We interpret the provenance of the glacial diamictites to be restricted to sources inside the SFC, suggesting deposition in an environment similar to ice streams from modern, high latitude glaciers. 相似文献
The High Resolution Imaging Science Experiment (HiRISE) on the Mars Reconnaissance Orbiter (MRO) acquired 8 terapixels of data in 9137 images of Mars between October 2006 and December 2008, covering ∼0.55% of the surface. Images are typically 5-6 km wide with 3-color coverage over the central 20% of the swath, and their scales usually range from 25 to 60 cm/pixel. Nine hundred and sixty stereo pairs were acquired and more than 50 digital terrain models (DTMs) completed; these data have led to some of the most significant science results. New methods to measure and correct distortions due to pointing jitter facilitate topographic and change-detection studies at sub-meter scales. Recent results address Noachian bedrock stratigraphy, fluvially deposited fans in craters and in or near Valles Marineris, groundwater flow in fractures and porous media, quasi-periodic layering in polar and non-polar deposits, tectonic history of west Candor Chasma, geometry of clay-rich deposits near and within Mawrth Vallis, dynamics of flood lavas in the Cerberus Palus region, evidence for pyroclastic deposits, columnar jointing in lava flows, recent collapse pits, evidence for water in well-preserved impact craters, newly discovered large rayed craters, and glacial and periglacial processes. Of particular interest are ongoing processes such as those driven by the wind, impact cratering, avalanches of dust and/or frost, relatively bright deposits on steep gullied slopes, and the dynamic seasonal processes over polar regions. HiRISE has acquired hundreds of large images of past, present and potential future landing sites and has contributed to scientific and engineering studies of those sites. Warming the focal-plane electronics prior to imaging has mitigated an instrument anomaly that produces bad data under cold operating conditions. 相似文献