同步辐射软X射线吸收谱与发射谱测定天然针铁矿能带结构

天然半导体矿物由于成分、缺陷复杂,传统测试方法如紫外可见漫反射等难以准确测定其禁带宽度.本文以针铁矿为例,通过第一性原理计算得到纯针铁矿及掺Al针铁矿的电子结构.计算结果显示,纯针铁矿导带底与价带顶均由Fe3d与O2p轨道组成,而当含杂质Al时,Al2p与O2p发生杂化参与了价带组成.在此基础上,利用同步辐射X射线氧的K边吸收谱与发射谱对纯针铁矿及天然针铁矿的能带结构进行了测定.结果表明,天然含Al的针铁矿禁带宽度为2.30eV,小于纯针铁矿(2.57eV).本研究提供了一种测定天然氧化物矿物禁带宽度的新方法,为深入研究天然半导体可见光催化活性产生机制提供了理论依据.     

辽东宽甸东北沟钼矿二长花岗岩年代学、地球化学及Hf同位素特征

东北沟钼矿是辽宁宽甸地区近些年发现的大型隐爆角砾岩型钼矿床。文章首次对东北沟钼矿床赋矿围岩二长花岗岩进行LA-MC-ICP-MS锆石U-Pb定年,主量元素、微量元素和Hf同位素地球化学研究,锆石U-Pb定年结果表明,二长花岗岩形成年龄为(129.4±0.3)Ma(MSWD=0.83),为燕山期构造岩浆活动产物。地球化学成分上,岩石具有富硅(SiO_2=62.21%~83.21%)、高钾(K_2O/Na_2O=3.35~20.27)和富碱(K_2O+Na_2O=5.82%~12.23%)的特点,属于钾玄岩系列。岩石富集轻稀土元素(LREE/HREE=10.26~24.21),亏损重稀土元素,具有弱负铕异常(δEu=0.63~1.07),富集大离子亲石元素(如K、Rb、Pb)和不相容元素(如Th、U)的特征,相对亏损高场强元素(如Nb、Ta、P、Ti)。锆石Hf同位素分析结果表明,东北沟钼矿二长花岗岩的ε_(Hf)(t)值为介于-12.4~-8.5,二阶段模式年龄(t_(DM2))介于442~1610 Ma,反映岩浆源区可能来源于中元古界古老地壳的再熔融。结合区域构造演化,成岩成矿构造背景为早白垩世古太平洋板块向欧亚之下俯冲,岩石圈减薄的构造环境。     

Rainfall over Oman and its teleconnection with El Niño Southern Oscillation

The Sultanate of Oman is located in the south-eastern part of the Arabian Peninsula and covers the larger part of the southern coasts of the Arabian Peninsula in both arid and semi-arid environments except for the southern part which is swept by the monsoon affecting the Arabian Sea during the period from June to September. The summer rainfall over Oman shows year-to-year variability, and this is caused by oceanic and atmospheric influences. In the present study, we tried to explore the influence of El Niño on the rainfall over Oman using different data sets. The empirical orthogonal function (EOF) technique employed to the zonal wind at 850 hPa for the 30-year period shows that the second and third modes of EOF are showing high variability over the Oman regions. The corresponding PCs were subjected to FFT analysis, and it showed a peak about 5–6 years. In addition to this, the zonal wind over the Oman regions is correlated with the global zonal wind and found a significant correlation (1 % significant level). It has already been proved that the wind and rainfall during summer monsoon is in phase. Moreover, the spectral analysis of rainfall at Masirah station and the Niño3.4 index show the similar mode of variability indicating a direct relationship. The correlation between rainfall and the Niño3.4 index is also showing a positive significant value, and therefore, it can be concluded that the El Niño in the Pacific favours rainfall over the Oman region.     

Multichannel analysis of surface waves (MASW) for seismic site characterization using 2D genetic algorithm at Bahrah area,Wadi Fatima,Saudi Arabia

The present study deals with the seismic site classification of Bahrah area, Wadi Fatima, to characterize the local site conditions. The dynamic behavior of sediments was studied by the application of surface wave inversion. The multichannel analysis of surface waves (MASW) shallow geophysical technique was utilized for site classification. MASW survey was carried out at 66 sites along with 13 seismic refraction profiles at suitable localities. MASW and seismic refraction profiles were processed and compared with the available borehole data. The integration of MASW techniques with seismic refraction and borehole data progressively enhanced the subsurface visualization and reliability of the shear wave velocity estimation in the subsurface in the study area. The subsurface shear-wave velocity model was achieved by the solution of an inverse problem-based dispersion of surface waves and propagation in a vertically heterogeneous medium. The 2D genetic algorithm was employed for the inversion of dispersion curves to obtain velocity and thickness of subsurface layers. The depth to engineering bedrock and velocity of shear waves in the first 30 m was deciphered and mapped. The depth of bedrock in study area varies from 4 to 30 m, and V _{S 30} ranges from 320 to 800 m/s. The most of study area falls in B and C class categories in addition to few sites of D class according to the NEHRP guidelines.     

Assessing groundwater storage changes in the Nubian aquifer using GRACE data

Gravity Recovery and Climate Experiment (GRACE) level two (L2) data is used in estimating the groundwater storage changes (GWSC) in the Nubian Sandstone Aquifer System (NSAS). This set of data consists of spherical harmonics coefficients with specific degree and order. The GRACE data is de-correlated using a sixth degree polynomial in order to reduce the effect of the noise error resulting from the correlation between the spherical harmonics coefficients with the same degree parity. The GRACE estimates of GWSC are smoothed using Gaussian filter with half width of 1000 km. This half width is chosen in order to maximize the correlation between the GRACE estimates of GWSC and previous modeling results of the NSAS. The loss in groundwater storage occurring in each of the four countries sharing the NSAS is calculated to assess the sustainability of using the NSAS as a water resource in each country. The overarching finding in this study is that NSAS is losing its groundwater storage at a very high rate. Also, it is found that Egypt is the fastest in losing its groundwater storage from the NSAS. This loss of groundwater storage in Egypt may not necessarily be resulting from in-country extractions because of the trans-boundary nature of this aquifer. The GRACE-based estimates are found to be close to available data and previous modeling results of the NSAS.     

Detachment folding in a Lower Cambrian–Upper Permian karst reservoir: 3D model of the Yubei 3D area (eastern Markit Slope,Tarim Basin,Northwest China)

A three-dimensional (3D) structural modeling of the Lower Cambrian–Upper Permian Yubei 3D area was performed to understand its structural evolution. This model reproduces the present-day structure of the basin and comprises 11 horizons within Lower Cambrian to Upper Permian rocks. The analysis is based on 3D depth views and faults. The results image salt movements due to tectonics and/or burial. From these observations, this paper deduces that salt structures are correlated to the main faults and tectonic events. From the model analysis, we interpret the timing and geometry of Tarim Basin tectonics. The fault geometry can be resolved based on the strike of the fault, the morphology of hanging wall strata, and the stratigraphic distribution. Emphasis is placed on gypsum rock detachment, considering its movements during the Middle Caledonian event and decoupling effects during tectonic evolution. Moreover, we point to the structural control of the Paleozoic basement and the crustal architecture (Yubei 3D Zone) on the geometry of the Tarim Basin.     

A GIS-index integration approach to groundwater suitability zoning for irrigation purposes

In recent decades, the high population growth has increased the demand for agricultural lands and products. Groundwater offers reliability and flexibility in access to water for irrigation purposes, especially in arid and semi-arid areas, such as Amol-Babol Plain, Iran. However, the quality and quantity of groundwater may not be suitable for irrigation purposes in all areas due to urbanizations, and intensive agricultural and industrial activities. Groundwater suitability zoning for irrigation purposes could be useful to improve water resources and land use planning, mostly in areas with water scarcity. Therefore, a GIS-based indices method is proposed to assess suitable zones for agricultural activities, integrating the irrigation water quality (IWQ) index and hydrogeological factors. IWQ index was utilized to assess groundwater quality based on salinity hazard, infiltration hazard, specific ions, and trace elements hazards, and miscellaneous effects such as pH, bicarbonate, and nitrate. The potential of the aquifer for irrigation water abstraction was investigated using hydrogeological surveys such as slope angle of the plain, hydraulic conductivity, and aquifer thickness. The groundwater suitability index classified most of the study area (more than 90 %) as “excellent” or “good” suitability zones for irrigation purposes. A limited area of around 5.6 % of the total area has moderate suitability for irrigation purposes due to the Caspian Seawater intrusion and the presence of fossil saline water. The proposed methodology provides useful information in order to allow irrigation management to prevent water and soil deterioration.     

Groundwater potential assessment in a sedimentary terrain,southwestern Nigeria

Geoelectrical resistivity techniques are increasingly being applied in addressing a wide range of hydrological, environmental, and geotechnical problems. This is due to their effectiveness in near-surface characterization. In the present study, a suite of vertical electrical soundings (VESs) was integrated with 2D geoelectrical resistivity and time-domain induced polarization (IP) imaging to characterize the near-surface and delineate the underlying aquifer in a sedimentary terrain. The geophysical survey was conducted as part of preliminary studies to evaluate the potential of groundwater resource in Iyana-Iyesi and Canaan Land area of Ota, southwestern Nigeria. A high-yield confined sandy aquifer overlain by a low-yield aquitard was delineated; overlying the aquitard is a very resistive and thick layer that is predominantly composed of kaolinitic swelling clay intercalated with phosphate mineral.     

Coal-measure source rock characteristics and burial evolution history in the Shisanjianfang Area,Tuha Basin

Shisanjianfang Area in the eastern margin of Taibei Sag, Tuha Basin, is an important region for oil and gas exploration. In this study, a large number of source rock geochemical data were used to analyze the geochemical characteristics of coal-measure source rocks in the Shisanjianfang Area, Tuha Basin, from three aspects, i.e., organic matter abundance, organic matter type, and organic maturity. The results show that the Jurassic Xishanyao Formation (J₂x) in the study area has great thickness, continuous distribution, and high source rock maturity, and is the major source rock horizon in the study area. The seismic data are used in combination with 1D and 2D basin simulation technology to study the distribution characteristics of the source rocks in Shisanjianfang Area. The results of the simulation research on the source rock maturity history in the study area indicate the following: (1) The source rocks in the Xishanyao Formation (J₂x) have a hydrocarbon generation threshold depth of 1800 m, threshold temperature of 95 °C, and hydrocarbon generation threshold time of about 162 Ma. (2) The Xishanyao Formation (J₂x) has a current formation temperature of 50~110 °C and Ro of 0.6~1.1 % in the peak oil generation stage. (3) The source rock maturity in the study area is shown as being higher in the west while lower in the east, and higher in the north while lower in the south, and the favorable exploration area mainly lies in the northwest of the study area. The results of this study could have important implications for the oil and gas exploration in the margins of Xiaocaohu Sag, Tuha Basin.     

Sensitivity analysis of runoff hydrographs due to temporal rainfall patterns in Makkah Al-Mukkramah region,Saudi Arabia

Runoff peak and volume in flood studies are estimated relying on temporal rainfall distribution from various storm patterns. Usually, SCS distributions types (I, II, III, IA) are commonly used. Using these distributions in runoff calculations assume that the in situ temporal rainfall pattern typically behaves as the one described by the SCS-type distribution, which is due to cyclonic frontal storms and actually developed in temperate environment. To what extent such assumption is valid in the arid environment? How much the impacts of rainfall temporal patterns are reflected in runoff volumes and peaks? The aim objectives of the current study are to answer the above two questions and clarify the validity of aforementioned assumption and exemplify such effect. Real rainfall data collected from rain gauges of Makkah Al-Mukkramah region over a period of more than 20 years are utilized. Temporal rainfall patterns and their parameters are deduced. Many hydrological simulations are performed and comparisons, in terms of runoff volume and peak flows, are made to show the effects of the common rainfall storm patterns and the developed rainfall storm patterns in the region based on the current study. Results indicate that major bursts of the design rainfall storm pattern are located in the first time of the storm period in the two quartiles which is mainly due to convective rainfall type in thunderstorms unlike the commonly used by SCS types relying on frontal cyclonic storms. Makkah Al-Mukkramah temporal rainfall pattern does not behave as the “typical pattern” assumed by SCS distributions that are deduced from different environments. The impacts of the temporal pattern reflected as an overestimate in the runoff peak reached to 68 %. The developed hyetographs and tables presented in the current study are recommended to enhance economical and rational design practice in watersheds of Makkah Al-Mukkramah region.