NanoSr – A New Carbonate Microanalytical Reference Material for In Situ Strontium Isotope Analysis

The in situ measurement of Sr isotopes in carbonates by MC‐ICP‐MS is limited by the availability of suitable microanalytical reference materials (RMs), which match the samples of interest. Whereas several well‐characterised carbonate reference materials for Sr mass fractions > 1000 µg g^?1 are available, there is a lack of well‐characterised carbonate microanalytical RMs with lower Sr mass fractions. Here, we present a new synthetic carbonate nanopowder RM with a Sr mass fraction of ca. 500 µg g^?1 suitable for microanalytical Sr isotope research (‘NanoSr’). NanoSr was analysed by both solution‐based and in situ techniques. Element mass fractions were determined using EPMA (Ca mass fraction), as well as laser ablation and solution ICP‐MS in different laboratories. The ⁸⁷Sr/⁸⁶Sr ratio was determined by well‐established bulk methods for Sr isotope measurements and is 0.70756 ± 0.00003 (2s). The Sr isotope microhomogeneity of the material was determined by LA‐MC‐ICP‐MS, which resulted in ⁸⁷Sr/⁸⁶Sr ratios of 0.70753 ± 0.00007 (2s) and 0.70757 ± 0.00006 (2s), respectively, in agreement with the solution data within uncertainties. Thus, this new reference material is well suited to monitor and correct microanalytical Sr isotope measurements of low‐Sr, low‐REE carbonate samples. NanoSr is available from the corresponding author.     

Patterns of fluid flow in the contact aureole of the Late Miocene Monte Capanne pluton (Elba Island,Italy): the role of structures and rheology

Fluid–rock interaction was investigated in the inner aureole of the Late Miocene Monte Capanne pluton on Elba Island (Tuscany, central Italy) by integrating structural, petrological, fluid inclusion, and stable isotope analyses. In the north-western sector of the aureole (Procchio–Spartaia area), calc–silicates alternate with nearly pure carbonate layers at the metre scale. Close to the pluton, the prograde metamorphic sequence includes calc–silicates that transition within a few metres to overlying nearly pure calcite marbles. The calc–silicates are extensively metasomatised to form massive wollastonite-grossular-bearing exoskarn. The mineralogical assemblage found in the marbles and the unshifted carbon and oxygen isotopic ratios in calcite attest that the fluid phase was internally buffered. On the other hand, the calc–silicates constituted channels for infiltration of disequilibrium fluids of magmatic origin. Fluid infiltration was enhanced by hydrofracturing and structurally-controlled by existing planar anisotropies in calc–silicates (layering and lithological boundaries). At the metamorphic peak (∼600°C and 1.5–2 kbar), the marble–calc–silicate interface acted as a barrier to fluids exsolved from the crystallising intrusions, separating two different flow patterns in the inner aureole: a high fluid–flux region on its higher grade side (Wol-zone) and a low fluid–flux region on the lower-grade side (Cpx zone). Results of this study: (1) documented that fluid pathways in the aureole rocks at the top of the pluton were largely horizontal, controlled by the lithological layering and the pluton–host rock contact; and (2) elucidated the primary control exerted by the structural and rheological properties of the host rocks on the geometry of fluid flow during pluton emplacement.     

Mineralogical and geochemical study of granular xenoliths from the Alban Hills volcano,Central Italy: bearing on evolutionary processes in potassic magma chambers

Granular xenoliths (ejecta) from pyroclastic deposits emplaced during the latest stages of activity of the Alban Hills volcano range from ultramafic to salic. Ultramafic types consist of various proportions of olivine, spinel, clinopyroxene and phlogopite. They show low SiO₂, alkalies and incompatible element abundances and very high MgO. However, Cr, Co and Sc are anomalously low, at a few ppm level. Olivine is highly magnesian (up to Fo%=96) and has rather high CaO (1% Ca) and very low Ni (around a few tens ppm) contents. These characteristics indicate a genesis of ultramafic ejecta by thermal metamorphism of a siliceous dolomitic limestone, probably with input of chemical components from potassic magma. The other xenoliths have textures and compositional characteristics which indicate that they represent either intrusive equivalents of lavas or cumulates crystallized from variably evolved ultrapotassic magmas. One sample of the former group has major element composition resembling ultrapotassic rocks with kamafugitic affinity. Some cumulitic rocks have exceedingly high abundances of Th (81–84 ppm) and light rare-earth elements (LREE) (La+Ce=421–498 ppm) and extreme REE fractionation (La/Yb=288–1393), not justified by their modal mineralogy which is dominated by sanidine, leucite and nepheline. Finegrained phases are dispersed through the fractures and within the interstices of the main minerals. Semiquantitative EDS analyses show that Th and LREE occur at concentration levels of several tens of percent in these phases, indicating that their presence is responsible for the high concentration of incompatible trace elements in the whole rocks. The interstitial position of these phases and their association with fluorite support a secondary origin by deposition from fluorine-rich fluids separated from a highly evolved potassic liquid. The Nd isotopic ratios of the cjecta range from 0.51182 to 0.51217. ⁸⁷Sr/⁸⁶Sr ratios range from 0.70900 to 0.71036. With the exception of one sample, these values are lower than those of the outcropping lavas, which cluster around 0.7105±3. This indicates either the occurrence of several isotopically distinct potassic magmas or a variable interaction between magmas and wall rocks. However, this latter hypothesis requires selective assimilation of host rocks in order to explain isotopic and geochemical characteristics of lavas and xenoliths. The new data indicate that the evolutionary processes in the potassic magmas of the Alban Hills were much more complex than envisaged by previous studies. Interaction of magmas with wall rocks may be an important process during magmatic evolution. Element migration by gaseous transfer, often invoked but rarely constrained by sound data, is shown to have occurred during the latest stages of magmatic evolution. Such a process was able to produce selective enrichment of Th, U, LREE and, to a minor degree, Ta and Hf in the wall rocks of potassic magma chamber. Finally, the occurrence of xenoliths with kamafugitic composition points to the existence of this type of ultrapotassic magma at the Alban Hills.     

A unified framework for earthquake risk assessment of transportation networks and gross regional product

Natural threats like earthquakes, hurricanes or tsunamis have had serious impacts on communities. In the past, major earthquakes in the United States like Loma Prieta 1989, Northridge 1994, or recent events in Italy like L’Aquila 2009 or Emilia 2012 emphasized the importance of preparedness and awareness to reduce social impacts. In addition to that, earthquake damaged businesses dramatically reduced the gross regional product. Generating scenario earthquakes in a proper way is important to suitably assess the risk in bridge networks and social losses in terms of gross regional product reduction. Seismic hazard is traditionally assessed by means of probabilistic seismic hazard analysis (PSHA). Although PSHA well represents the hazard at a specific location it is not suitable for spatially distributed systems. Scenario earthquakes can overcome this problem; they represent the actual distribution of ground shaking for a spatially distributed system while being hazard consistent. In this work a methodology to generate scenario earthquakes has been proposed using a novel approach with the aim of being the basic step for investigating possible earthquake consequences in seismic areas and contributing to reduce losses.     

Source controlled 87Sr/86Sr isotope variability in granitic magmas: The inevitable consequence of mineral-scale isotopic disequilibrium in the protolith

The broad Sr isotopic variability exhibited by granitoid rocks is commonly interpreted to reflect the mixing of magmas from different sources. However, evidence from granites and migmatites indicates that melting and magma extraction from crustal sources can occur sufficiently rapidly that trace-element and isotopic equilibration between liquid and residual phases is commonly not achieved. Additionally, evidence from unmelted high-grade metamorphic rocks indicates that major reactant minerals in the fluid-absent melting process, principally biotite and plagioclase, do not always attain equilibrium during regional metamorphism. When these two circumstances occur in combination, the melt does not inherit its radiogenic isotopic signature from the bulk source in a simple way. In such situations, the isotopic composition of the melt will be dependent on the isotopic compositions of the reactant phases and the stoichiometry of the melting reaction. This study has used information from experimental studies of fluid absent partial melting in metapelites and metagreywackes to investigate the consequences of Sr isotopic disequilibrium between the reactant minerals for magma composition. The study demonstrates that a range of isotopically distinct magmas can arise from progressive melting of a single source that is able to undergo melting through different reactions as temperature increases. When translated to the typically layered sources constituted by sedimentary and volcano-sedimentary rocks, this process will produce magmas characterized by Sr isotope variability that reflects the differences in melting reaction stoichiometry within the different layers, even with no bulk-rock isotopic variability between layers. This study demonstrates that the Sr isotope variability commonly observed within granitic suites, as well as at the grain and sub-grain scale within individual magmatic bodies, can be primary, reflecting differences in composition between magma batches produced from the progressive melting of a single source.     

Impact of projected climate change on hydrologic regime of the Upper Paraguay River basin

We present an assessment of climate change impacts on the hydrologic regime of the 600,000 km² Upper Paraguay River basin, located in central South America based on predictions of 20 Atmospheric/Ocean General Circulation Models (AOGCMs). We considered two climate change scenarios from the Intergovernmental Panel on Climate Change (IPCC) and two 30-years time intervals centered at 2030 and 2070. Projected temperature and precipitation anomalies estimated by the AOGCMs for the study site are spatially downscaled. Time series of projected temperature and precipitation were estimated using the delta change approach. These time series were used as input to a detailed coupled hydrologic-hydraulic model aiming to estimate projected streamflow in climate change scenarios at several control points in the basin. Results show that impacts on streamflow are highly dependent on the AOGCM used to obtain the climate predictions. Patterns of temperature increase persist over the entire year for almost all AOGCMs resulting in an increase in the evapotranspiration rate of the hydrological model. The precipitation anomalies show large dispersion, being projected as either an increase or decrease in precipitation rates. Based on these inputs, results from the coupled hydrologic-hydraulic model show nearly one half of projections as increasing river discharge, and other half as decreasing river discharge. If the mean or median of the predictions is considered, no discernible change in river discharge should be expected, despite the dispersion among results of the AOGCMs that reached +/?10 % in the short horizon and +/? 20 % in the long horizon, at several control points.     

The Maoxian landslide as seen from space: detecting precursors of failure with Sentinel-1 data

Post-event Interferometric Synthetic Aperture Radar (InSAR) analysis on a stack of 45 C-band SAR images acquired by the ESA Sentinel-1 satellites from 9 October 2014 to 19 June 2017 allowed the identification of a clear precursory deformation signal for the Maoxian landslide (Mao County, Sichuan Province, China). The landslide occurred in the early morning of 24 June 2017 and killed more than 100 people in the village of Xinmo. Sentinel-1 images have been processed through an advanced multi-interferogram analysis capable of maximising the density of measurement points, generating ground deformation maps and displacement time series for an area of 460 km² straddling the Minjiang River and the Songping Gully. InSAR data clearly show the precursors of the slope failure in the source area of the Maoxian landslide, with a maximum displacement rate detected of 27 mm/year along the line of sight of the satellite. Deformation time series of measurement points identified within the main scarp of the landslide exhibit an acceleration starting from April 2017. A detailed time series analysis leads to the classification of different deformation behaviours. The Fukuzono method for forecasting the time of failure appear to be applicable to the displacement data exhibiting progressive acceleration. Results suggest that satellite radar data, systematically acquired over large areas with short revisiting time, could be used not only as a tool for mapping unstable areas, but also for landslide monitoring, at least for some typologies of sliding phenomena.     

Reply to discussion on “Guidelines on the use of inverse velocity method as a tool for setting alarm thresholds and forecasting landslides and structure collapses” by F. Bozzano,P. Mazzanti,and S. Moretto

■■■The paper “Discussion to: Guidelines on the use of inverse velocity method as a tool for setting alarm thresholds and forecasting landslides and structure collapses by T. Carlà, E. Intrieri, F. Di Traglia, T. Nolesini, G. Gigli and N. Casagli” by Bozzano et al. brings forward new considerations on an issue of extreme concern in landslide risk management. To this day, the ability to predict catastrophic landslide failures from slope surface displacements is a problem dictated more by practical constraints rather than by theoretical uncertainties. In this sense, the development of data interpretation practices is crucial. This short reply provides a few further insights with regard to this subject, also in the context of the recently published literature.     

Late Pliocene and Pleistocene small mammal chronology in the Italian peninsula

The abundant documentation of small mammals in the Italian peninsula, collected over recent years, furnishes a detailed biochronological sequence mainly from the Late Pliocene onwards. An updated stratigraphic framework is here presented, based on the European small mammal biozonation. The Early Villanyian is characterized by Mimomys hassiacus, M. stehlini, and, later, poorly documented M. polonicus. The Late Villanyian localities are well characterized with M. pliocaenicus, M. pitymyoides and M. tigliensis. The older part of the Early Biharian is documented by assemblages containing Microtus (Allophaiomys) ex gr. pliocaenicus, M. pusillus, M. cf. ostramosensis and M. tornensis, while the later part of the Early Biharian, is characterized by advanced Microtus (Allophaiomys) species occurring together with M. pusillus or M. blanci. In the Late Biharian M. savini, Microtus hintoni-gregaloides, Microtus (Iberomys) ex gr. huescarensis-brecciensis and Terricola arvalidens occur. The Early Toringian with A. mosbachensis, Allocricetus bursae, Pliomys episcopalis and small-sized Microtus brecciensis, and the Late Toringian with A. terrestris in diversified associations are quoted. The most important faunal events are calibrated by independent chronological controls, thanks to the record of small mammals from lacustrine deposits. Several figures illustrate the most significant rodent species occurring in the succession of selected Italian localities.     

Development of water management strategies in southern Mesopotamia during the fourth and third millennium B.C.E.

The last two decades witnessed increasing scholarly interest in the history of water management in southern Mesopotamia. Thanks to many geoarchaeological research projects conducted throughout the central and southern Iraqi floodplains, a general understanding of the macrophases of anthropogenic manipulation of this vast hydraulic landscape has been achieved. However, current narratives mostly rely on studies at a regional scale and are based on excessively long chronological phases (often spanning a whole millennium). A finer-tuned analysis at a submillennial scale is needed to better appreciate the dynamics that led to the development of artificial canals and irrigation systems and the creation of harbours in cities and other navigation-related facilities. The Iraqi-Italian QADIS project is addressing this issue through a systematic geoarchaeological investigation in the south-eastern area of the Qadisiyah province. We aim to update the current narrative by analysing case studies involving specific periods of occupation. We performed 17 boreholes to propose a date on the functioning period of the hydraulic works in five selected archaeological sites of this region. This approach allowed us to understand changes in water management strategies in both the short and the medium term (i.e., on a scale of centuries). In this paper, we present the results for the fourth and third millennia B.C.E. This period witnessed a crucial passage from the basic exploitation of natural watercourses for irrigation and occasional navigation to the emergence of the first system of artificial canals and intraurban harbours.