Methodology of hydrogeological characterization of deep carbonate aquifers as potential reservoirs of groundwater. Case of study: the Jurassic aquifer of <Emphasis Type="Italic">El Maestrazgo</Emphasis> (Castellón,Spain)

A methodology for the characterization of deep carbonate aquifers has been developed and applied to El Maestrazgo Jurassic aquifer in Castellón, Spain. Characterization of these aquifer formations, located at more than 300 m deep, consisted of a previous phase of compilation, analysis and synthesis of the existing information about the area, followed by a coordinated combination of different speciality studies: geology, stratigraphy, structural analysis, hydrogeology, hydrochemistry, geophysics and remote sensing. Geological studies included geological mapping, definition of stratigraphical units and facies and structural analysis. The aim of the hydrogeology study was to define aquifer formations, recharge area, aquifer points inventory and groundwater flow directions for the establishment of piezometric and water quality observation nets. Special techniques were applied, like thermal infrared aerial images and the evaluation of submarine groundwater discharge by means of natural radium isotopes. Hydrochemical techniques, including majority elements characterization and stable isotopes (¹⁸O, ²H and ³H) determination, allowed classifying hydrochemical facies and establishing a renewal pattern for water within the system. Geophysics was useful in determining the aquifer geometry, the features of the basement and the petrophysical characteristics of the geological formations. Preliminary results show an important tectonic complexity and the possibilities for groundwater uses in the area of study.     

The response of vegetation at the end of the last glacial period (MIS 3 and MIS 2) in littoral areas of NW Iberia

This paper describes and discusses the palaeobotanical data obtained from organic levels of two exposed deposits on the Atlantic shore of the northwestern Iberian Peninsula. Radiocarbon dating assigns these levels to a period of marine regression at the end of MIS 3 and the beginning of the Last Glacial Maximum. The pollen record shows an initial predominance of tree taxa (mainly deciduous, including the presence of Fagus far from its current limit), followed by an episode of partial forest retraction related to the end of MIS 3 and the beginning of the Last Glacial Maximum. However, the presence of numerous tree taxa in the record, even during the cold intervals associated with Heinrich events, points to the existence of sheltered refugia for these species during this period, in keeping with the conclusions of recent reviews of the vegetation dynamics of this region for the Lateglacial and the Holocene.     

Space–time distribution of ancient and active alluvial karst subsidence: examples from the central Ebro Basin,Spain

Space and time variations of alluvial karst subsidence in the central Ebro Basin are analysed in trenches (paleodolines), aerial photographs (historical dolines) and field surveys (present-day active dolines). The measured subsidence rates, as well as a comparison between densities of paleodolines computed in randomly selected scan-lines and density of active dolines computed in maps, suggest that present-day subsidence in favourable areas is more intense than that of Pleistocene times. According to diachronic maps drawn from (a) different aerial photographs taken after 1946 and (b) field surveys on deformations in urbanized areas, subsidence behaved as a nearly steady process while the whole area was used for agriculture. In contrast, rapid changes (through periods of several tens of years) have occurred in urbanized areas, in which dolines expand their boundaries through small marginal collapses, shifting sharply their sinking centres to neighbouring sites. These rapid changes do not have an equivalent in observed paleodolines.     

Combining European Earth Observation products with Dynamic Global Vegetation Models for estimating Essential Biodiversity Variables

ABSTRACT

Global, fast and accessible monitoring of biodiversity is one of the main pillars of the efforts undertaken in order to revert it loss. The Group on Earth Observations Biodiversity Observation Network (GEO-BON) provided an expert-based definition of the biological properties that should be monitored, the Essential Biodiversity Variables (EBVs). Initiatives to provide indicators for EBVs rely on global, freely available remote sensing (RS) products in combination with empirical models and field data, and are invaluable for decision making. In this study, we provide alternatives for the expansion and improvement of the EBV indicators, by suggesting current and future data from the European Space Agencýs COPERNICUS and explore the potential of RS-integrated Dynamic Global Vegetation Models (DGVMs) for the estimation of EBVs. Our review found that mainly due to the inclusion of the Sentinel constellation, Copernicus products have similar or superior potential for EBV indicator estimation in relation to their NASA counterparts. DGVMs simulate the ecosystem level EBVs (ecosystem function and structure), and when integrated with remote sensing data have great potential to not only offer improved estimation of current states but to provide projection of ecosystem impacts. We suggest that focus on producing EBV relevant outputs should be a priority within the research community, to support biodiversity preservation efforts.     

A detailed study of the duality relation for the least squares adjustment in euclidean spaces

The Euclidean spaces with their inner products are used to describe methods of least squares adjustment as orthogonal projections on finite-dimensional subspaces. A unified Euclidean space approach to the least squares adjustment methods “observation equations” and “condition equations” is suggested. Hence not only the two adjustment solutions are treated from the view-point of Euclidean space theory in a unified frame but also the existing duality relation between the methods of “observation equations” and “condition equations” is discussed in full detail. Another purpose of this paper is to contribute to the development of some familiarity with Euclidean and Hilbert space concepts. We are convinced that Euclidean and Hilbert space techniques in least squares adjustment are elegant and powerful geodetic methods.     

A calibration system for superconducting gravimeters

A new method for the calibration of a superconducting gravity meter is described, in which a 273 Kg annular mass is placed around the meter and is moved up and down. The geometry of the apparatus is easy to model and the accuracy in the computation of the gravity variation induced by the mass, 6.7µgal, is limited only by the accuracy in the knowledge of value of the gravitational constant. Measurements done in 91 and 92 for the calibration of the instrument GWR-T015 are described. The calibration factor has been determined with a precision of about 0.3%.     

The new national climate change documents of Mexico: what do the regional climate change scenarios represent?

This paper presents a review of the methodology applied for generating the regional climate change scenarios utilized in important National Documents of Mexico, such as the Fourth National Communication to the United Nations Framework Convention on Climate Change, the Fourth National Report to the Convention on Biological Diversity and The Economics of Climate Change in Mexico. It is shown that these regional climate change scenarios, which are one of the main inputs to support the assessments presented in these documents, are an example of the erroneous use of statistical downscaling techniques. The arguments presented here imply that the work based on such scenarios should be revised and therefore, these documents are inadequate for supporting national decision- making.     

Degradation and Detoxification of Chlorophenols in Continuous‐Flow Fixed‐Bed Aerobic Reactors

An indigenous bacterial strain of Delftia sp. capable of degrading 2,4‐dicholorophenol and an indigenous bacterial community that degrades 2,4,6‐trichlorophenol (TCP) were employed to inoculate continuous down‐flow fixed‐bed reactors. Continuous‐reactors were constructed from PVC employing hollow PVC cylinders as support material. Synthetic wastewater was prepared by dissolving the corresponding chlorophenol in non‐sterile groundwater. Biodegradation was evaluated by spectrophotometry, chloride release, GC, and microbial growth. Detoxification was evaluated by using Daphnia magna as test organism. Delftia sp. was able to remove an average of 95.6% of DCP. Efficiency in terms of chemical oxygen demand (COD) was of 88.9%. The indigenous bacterial community that degrades TCP reached an average efficiency of 96.5 and 91.6% in terms of compound and COD removal, respectively. In both cases stoichiometric removal of chloride and detoxification was achieved. When synthetic wastewater feed was cut off for 7 days, both reactors showed a fast recovery after inflow restarting, reaching average outlet concentration values within 36 h. The promising behavior of the microorganisms and the low cost of the reactors tested allow us to suggest their possible application to remediation processes.     

Uranium pollution in an estuary affected by pyrite acid mine drainage and releases of naturally occurring radioactive materials

After the termination of phosphogypsum discharges to the Huelva estuary (SW Spain), a unique opportunity was presented to study the response of a contaminated environmental compartment after the cessation of its main source of pollution. The evolution over time of uranium concentrations in the estuary is presented to supply new insights into the decontamination of a scenario affected by Naturally Occurring Radioactive Material (NORM) discharges. The cleaning of uranium isotopes from the area has not taken place as rapidly as expected due to leaching from phosphogypsum stacks.An in-depth study using various techniques of analysis, including ²³⁴U/²³⁸U and ²³⁰Th/²³²Th ratios and the decreasing rates of the uranium concentration, enabled a second source of uranium contamination to be discovered. Increased uranium levels due to acid mine drainage from pyrite mines located in the Iberian Pyrite Belt (SW Spain) prevent complete uranium decontamination and, therefore, result in levels nearly twice those of natural background levels.