Trace element and Pb–B–Li isotope systematics of olivine-hosted melt inclusions: insights into source metasomatism beneath Stromboli (southern Italy)

We studied the elemental and isotopic (Pb, B and Li isotopes) composition of melt inclusions hosted in highly forsteritic (Fo_83–91) olivines that were collected from San Bartolo lava and pumice (ST79p, ST82p and ST531p) samples erupted by Stromboli in historical times. The studied melt inclusions have primitive calcalkaline to shoshonitic basaltic compositions. They cover a compositional range far wider than that exhibited by the whole-rocks and differ in key trace element ratios. San Bartolo melt inclusions are characterized by lower incompatible trace element abundances, higher ratios between fluid-mobile (B, Pb, U and LILE) and less fluid-mobile (REE, Th, HFSE) elements and lower La/Yb ratios relative to the pumice-hosted melt inclusions and pumiceous melts erupted during paroxysmal events. Trace elements, along with different Pb, B and Li isotopic signatures, attest to source heterogeneity on the small scale and provide new insights into subducted components beneath Stromboli. Results of a mixing model suggest that metasomatism of the mantle source of pumice-hosted melt inclusions was driven by solute-rich high-pressure fluids (<20%) expelled from the deep portion of the slab. Heterogeneous Pb isotopic composition together with light δ¹¹B (−8.6 to −13.7‰) and δ⁷Li (+2.3 to −1.7‰) indicates that high-pressure liquids were released in variable proportions from highly dehydrated metabasalts and metasediments. On the other hand, the elemental and isotopic (δ¹¹B ~ −1.9 to −5.9‰) composition of San Bartolo melt inclusions is better explained by the addition of a prevalent aqueous component (~2 to 4%) escaped at shallower depths from sediments and altered basaltic crust in almost equivalent proportions, with a smaller contribution by high-pressure fluids. Owing to the high-angle dip of the subducted cold Ionian slab, aqueous fluids and high-pressure fluids would rise through the mantle wedge and locally superimpose on each other, thus giving origin to variously metasomatized mantle domains.     

Microstructure characteristics during hydrate formation and dissociation revealed by X-ray tomographic microscopy

Despite much progress over the past years in fundamental gas hydrate research, frontiers to the unknown are the early beginning and early decomposition of gas hydrates in their natural, submarine environment: gas bubbles meeting ocean water and forming hydrate, and gas starting to escape from the surface of a hydrate grain. In this paper we report on both of these topics, and present three-dimensional microstructure results obtained by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM). Hydrates can precipitate when hydrate-forming molecules such as methane exceed solubility, and combine with water within the gas hydrate stability zone. Here we show hydrate formation on surfaces of bubbles from different gas mixtures and seawater, based on underwater robotic in situ experiments in the deep Monterey Canyon, offshore California. Hydrate begins to form from the surrounding water on the bubble surfaces, and subsequently grows inward into the bubble, evidenced by distinct edges. Over time, the bubbles become smaller while gas is being incorporated into newly formed hydrate. In contrast, current understanding has been that hydrate decomposition starts on the outer surface of hydrate aggregates and grains. It is shown that in an early stage of decomposition, newly found tube structures connect well-preserved gas hydrate patches to areas that are dissociating, demonstrating how dissociating areas in a hydrate grain are linked through hydrate that is still intact and will likely decompose at a later stage.

Alluvial terraces on the Ionian coast of northern Calabria, southern Italy: Implications for tectonic and sea level controls

In this paper we present the results of an integrated geomorphological, pedological and stratigraphical study carried out along the Ionian coast of northern Calabria (southern Italy). This area is characterised by the occurrence of five orders of alluvial terraces that are striking features of the landscape, where large and steep catchments debouch from the mountain front to the hilly coastal belt.Field investigations indicate that the deposits of all five terraces are suggestive of shallow gravel-bed braided streams.On the basis of the age of the Pleistocene substratum and morphostratigraphic correlation with marine terraces cropping out in the nearby areas, each order has been associated to specific marine oxygen isotope stages.Consequently, we focused on the interplay of allocyclic factors influencing stream aggradation/degradation. Soil features and other climatic proxies suggest that climate didn't play an important role with respect to tectonic and base-level changes in controlling fluvial dynamics.In particular, we recognised that during the middle Pleistocene the study area experienced a period of subaerial landscape modelling, as suggested by the thick and complex alluvial sequence of the highest terrace (T1). The onset of regional uplift marks a change in the geomorphic scenario, with tectonic and eustatically driven changes in base-level working together in causing switches in fluvial aggradational/erosional phases (T2–T5 terraces). Because of the uplift, river dissection occurred during phases of sea level fall, whereas aggradation phases occurred during periods of climate amelioration (sea level rise) just before highstands were attained.As a consequence, the stepped terraces in the study area reflect the interplay between tectonics (uplift) and sea level changes, in which terraces define episodes of relative sea level fall during the late Quaternary.     

The Calatabiano landslide (southern Italy): preliminary GB-InSAR monitoring data and remote 3D mapping

On 24 October 2015, following a period of heavy rainfall, a landslide occurred in the Calatabiano Municipality (Sicily Island, Southern Italy), causing the rupture of a water pipeline supplying water to the city of Messina. Following this event, approximately 250,000 inhabitants of the city suffered critical water shortages for several days. Consequently, on 6 November 2015, a state of emergency was declared (O.C.D.P. 295/2015) by the National Italian Department of Civil Protection (DPC). During the emergency management phase, a provisional by-pass, consisting of three 350-m long pipes passing through the landslide area, was constructed to restore water to the city. Furthermore, on 11 November 2015, a landslide remote-sensing monitoring system was installed with the following purposes: (i) analyse the landslide geomorphological and kinematic features in order to assess the residual landslide risk and (ii) support the early warning procedures needed to ensure the safety of the personnel involved in the by-pass construction and the landslide stabilization works. The monitoring system was based on the combined use of Ground-Based Interferometric Synthetic Aperture Radar (GB-InSAR) and terrestrial laser scanning (TLS). In this work, the preliminary results of the monitoring activities and a remote 3D map of the landslide area are presented.     

The distribution of meiofauna on back‐reef sandy platforms in the Maldives (Indian Ocean)

The Maldivian archipelago comprises some of the most characteristic and significant world atoll systems, but the meiobenthic assemblages of these islands continue to be largely unknown. To investigate variations in meiofaunal spatial distribution and biodiversity in back‐reef platforms, three transects were studied, two at Felidhoo (the north and east sides) and one at South Malé. The sedimentological features of the samples obtained were also analyzed to further current knowledge on the relationships that exist between sediments and meiofauna. Our results reveal that the meiofaunal assemblage at these locations is well diversified and includes 20 major taxa. Nematodes and copepods are dominant, together forming 68% of the total meiofauna, followed by platyhelminthes, polychaetes and ostracods. The nematode assemblage is very rich and composed of 34 families and 123 genera – 96 of which (78%) set new records for the Maldives. The structures of the meiofaunal and nematode assemblages are relatively similar on the ‘large‐scale’ level (i.e. when the different platforms are compared) and reveal a low β‐diversity. However, significant dissimilarities were detected within each platform, emphasizing that such ‘small‐scale’ differences are the main factors determining the structure of the meiofauna and, in particular, the nematode assemblages. Although significant differences were not detected between the transects, greater levels of dissimilarity were recognized at North Felidhoo. Here, the building of inclined deposit layers plays a significant role in increasing the heterogeneity of the platform habitats and sediments, confirming the great importance of sediment granulometry as an environmental variable. Indeed, a close relationship is observed between meiofauna (especially for the nematodes) and grain size, which appears to control the structure, diversity and trophic composition of the Maldivian meiofauna assemblages, thus highlighting the high biodiversity existing in the medium‐coarse sands.     

Chemical speciation of arsenic in different marine organisms: Importance in monitoring studies

Arsenic is a widely distributed element in the marine environment. Inorganic and organic compounds have extremely different toxicological effects, and their characterization is thus of great utility when monitoring and assessing the impact of arsenic pollution. In this study both the levels of total arsenic and its chemical speciation were analyzed in several marine organisms collected from Cienfuegos Bay (Cuba) following an episode of acute As-contamination. Fish from the more impacted site were characterized by elevated concentrations of arsenic (up to 500 microg/g d.w.) and inorganic species represented the predominant forms in muscle tissues of these organisms.     

A rapid approach to estimate the rockfall energies and distances at the base of rock cliffs

This paper presents a new methodology for estimating the expected energies and first impact distances at the base of a rock cliff, subject to the geometry and properties of the cliff and the representative block being known. The method is based on a sensitivity analysis, conducted by means of kinematic simulations and carried out for a large range of input parameters and their combinations, taking into account the uncertainty associated with their estimate. The proposed approach is validated by comparing predictions to experimental data and shows great potential for a quick qualitative hazard assessment.     

The genetic structure of the exotic ascidian Styela plicata (Tunicata) from Italian ports,with a re‐appraisal of its worldwide genetic pattern

The pleated ascidian Styela plicata (Lesueur, 1823) is a solitary species commonly found in ports and marinas around the world. It has been recorded in the Mediterranean region since the mid‐19th century. In the present work, the species’ genetic diversity was analysed, employing a 613‐bp portion of the mitochondrial cytochrome c oxidase subunit I (COI) gene from 149 individuals collected in 14 ports along Italian coasts at spatial scales ranging from 1 to approximately 2200 km. Haplotype and nucleotide diversity values were h = 0–0.933 (total h = 0.789) and π = 0–0.145 (total π = 0.0094), respectively. A general southward trend of increasing within‐population genetic diversity was observed. Analysis of molecular variance revealed significant genetic structuring but no significant differences were detected among basins, and no isolation by distance was found. Our data were integrated with the COI sequences available from previous studies and re‐analysed in order to investigate the possible routes of introduction of this ascidian into the Mediterranean Sea. The presence of the two COI haplogroups detected in previous molecular investigations on S. plicata at intercontinental spatial scale was confirmed in the Mediterranean Sea. The results revealed multiple introductions of S. plicata, although some locations appear to have experienced rapid expansion from few founding individuals with reduced genetic diversity. However, continuous introductions would confound the pattern deriving from single founder events and make it difficult to estimate the time needed for gene diffusion into established populations. This mixing of effects creates difficulties in understanding the past and current dynamics of this introduction, and managing this alien invasive ascidian whose genetic structure is continuously shuffled by vessel‐mediated transport.     

Detrending time series for astronomical variability surveys

We present a detrending algorithm for the removal of trends in time series. Trends in time series could be caused by various systematic and random noise sources such as cloud passages, changes of airmass, telescope vibration, CCD noise or defects of photometry. Those trends undermine the intrinsic signals of stars and should be removed. We determine the trends from subsets of stars that are highly correlated among themselves. These subsets are selected based on a hierarchical tree clustering algorithm. A bottom-up merging algorithm based on the departure from normal distribution in the correlation is developed to identify subsets, which we call clusters. After identification of clusters, we determine a trend per cluster by weighted sum of normalized light curves. We then use quadratic programming to detrend all individual light curves based on these determined trends. Experimental results with synthetic light curves containing artificial trends and events are presented. Results from other detrending methods are also compared. The developed algorithm can be applied to time series for trend removal in both narrow and wide field astronomy.