Microstructure characteristics during hydrate formation and dissociation revealed by X-ray tomographic microscopy

Despite much progress over the past years in fundamental gas hydrate research, frontiers to the unknown are the early beginning and early decomposition of gas hydrates in their natural, submarine environment: gas bubbles meeting ocean water and forming hydrate, and gas starting to escape from the surface of a hydrate grain. In this paper we report on both of these topics, and present three-dimensional microstructure results obtained by synchrotron radiation X-ray cryo-tomographic microscopy (SRXCTM). Hydrates can precipitate when hydrate-forming molecules such as methane exceed solubility, and combine with water within the gas hydrate stability zone. Here we show hydrate formation on surfaces of bubbles from different gas mixtures and seawater, based on underwater robotic in situ experiments in the deep Monterey Canyon, offshore California. Hydrate begins to form from the surrounding water on the bubble surfaces, and subsequently grows inward into the bubble, evidenced by distinct edges. Over time, the bubbles become smaller while gas is being incorporated into newly formed hydrate. In contrast, current understanding has been that hydrate decomposition starts on the outer surface of hydrate aggregates and grains. It is shown that in an early stage of decomposition, newly found tube structures connect well-preserved gas hydrate patches to areas that are dissociating, demonstrating how dissociating areas in a hydrate grain are linked through hydrate that is still intact and will likely decompose at a later stage.

Alluvial terraces on the Ionian coast of northern Calabria, southern Italy: Implications for tectonic and sea level controls

In this paper we present the results of an integrated geomorphological, pedological and stratigraphical study carried out along the Ionian coast of northern Calabria (southern Italy). This area is characterised by the occurrence of five orders of alluvial terraces that are striking features of the landscape, where large and steep catchments debouch from the mountain front to the hilly coastal belt.Field investigations indicate that the deposits of all five terraces are suggestive of shallow gravel-bed braided streams.On the basis of the age of the Pleistocene substratum and morphostratigraphic correlation with marine terraces cropping out in the nearby areas, each order has been associated to specific marine oxygen isotope stages.Consequently, we focused on the interplay of allocyclic factors influencing stream aggradation/degradation. Soil features and other climatic proxies suggest that climate didn't play an important role with respect to tectonic and base-level changes in controlling fluvial dynamics.In particular, we recognised that during the middle Pleistocene the study area experienced a period of subaerial landscape modelling, as suggested by the thick and complex alluvial sequence of the highest terrace (T1). The onset of regional uplift marks a change in the geomorphic scenario, with tectonic and eustatically driven changes in base-level working together in causing switches in fluvial aggradational/erosional phases (T2–T5 terraces). Because of the uplift, river dissection occurred during phases of sea level fall, whereas aggradation phases occurred during periods of climate amelioration (sea level rise) just before highstands were attained.As a consequence, the stepped terraces in the study area reflect the interplay between tectonics (uplift) and sea level changes, in which terraces define episodes of relative sea level fall during the late Quaternary.     

The Calatabiano landslide (southern Italy): preliminary GB-InSAR monitoring data and remote 3D mapping

On 24 October 2015, following a period of heavy rainfall, a landslide occurred in the Calatabiano Municipality (Sicily Island, Southern Italy), causing the rupture of a water pipeline supplying water to the city of Messina. Following this event, approximately 250,000 inhabitants of the city suffered critical water shortages for several days. Consequently, on 6 November 2015, a state of emergency was declared (O.C.D.P. 295/2015) by the National Italian Department of Civil Protection (DPC). During the emergency management phase, a provisional by-pass, consisting of three 350-m long pipes passing through the landslide area, was constructed to restore water to the city. Furthermore, on 11 November 2015, a landslide remote-sensing monitoring system was installed with the following purposes: (i) analyse the landslide geomorphological and kinematic features in order to assess the residual landslide risk and (ii) support the early warning procedures needed to ensure the safety of the personnel involved in the by-pass construction and the landslide stabilization works. The monitoring system was based on the combined use of Ground-Based Interferometric Synthetic Aperture Radar (GB-InSAR) and terrestrial laser scanning (TLS). In this work, the preliminary results of the monitoring activities and a remote 3D map of the landslide area are presented.     

SPH simulation of free surface flow over a sharp-crested weir

In this paper the numerical simulation of a free surface flow over a sharp-crested weir is presented. Since in this case the usual shallow water assumptions are not satisfied, we propose to solve the problem using the full weakly compressible Navier–Stokes equations with the Tait equation of state for water. The numerical method used consists of the new meshless Smooth Particle Hydrodynamics (SPH) formulation proposed by Ferrari et al. (2009) [8], that accurately tracks the free surface profile and provides monotone pressure fields. Thus, the unsteady evolution of the complex moving material interface (free surface) can been properly solved. The simulations involving about half a million of fluid particles have been run in parallel on two of the most powerful High Performance Computing (HPC) facilities in Europe. The validation of the results has been carried out analysing the pressure field and comparing the free surface profiles obtained with the SPH scheme with experimental measurements available in literature [18]. A very good quantitative agreement has been obtained.     

A stochastic model for the analysis of the temporal change of dry spells

In the present paper a stochastic approach which considers the arrival of rainfall events as a Poisson process is proposed to analyse the sequences of no rainy days. Particularly, among the different Poisson models, a non-homogeneous Poisson model was selected and then applied to the daily rainfall series registered at the Cosenza rain gauge (Calabria, southern Italy), as test series. The aim was to evaluate the different behaviour of the dry spells observed in two different 30-year periods, i.e. 1951–1980 and 1981–2010. The analyses performed through Monte Carlo simulations assessed the statistical significance of the variation of the mean expected values of dry spells observed at annual scale in the second period with respect to those observed in the first. The model has then been verified by comparing the results of the test series with the ones obtained from other three rain gauges of the same region. Moreover, greater occurrence probabilities for long dry spells in 1981–2010 than in 1951–1980 were detected for the test series. Analogously, the return periods evaluated for fixed long dry spells through the synthetic data of the period 1981–2010 resulted less than half of the corresponding ones evaluated with the data generated for the previous 30-year period.     

Spinning particles in Saturn's C ring from mid-infrared observations: Pre-Cassini mission results

Saturn's C ring thermal emission has been observed in mid-infrared wavelengths, at three different epochs and solar phase angles, using ground based instruments (CFHT in 1999 and VLT/ESO in 2005) and the Infrared Radiometer Instrument Spectrometer (IRIS) onboard the Voyager 1 spacecraft in 1980. Azimuthal variations of temperature in the C ring's inner region, observed at several phase angles, have been analyzed using our new standard thermal model [Ferrari, C., Leyrat, C., 2006. Astron. Astrophys. 447, 745-760]. This model provides predicted ring temperatures for a monolayer ring composed of spinning icy spherical particles. We confirm the very low thermal inertia (on the order of 10 ) found previously by Ferrari et al. [Ferrari, C., Galdemard, P., Lagage, P.O., Pantin E., Quoirin, C., 2005. Astron. Astrophys. 441, 379-389] that reveals the very porous regolith at the surface of ring particles. We are able to explain both azimuthal variations of temperature and the strong asymmetry of the emission function between low and high phase angles. We show that large particles spinning almost synchronously might be present in the C ring to explain differences of temperature observed between low and high phase angle. Their cross section might represent about 45% of the total cross section. However, their numerical fraction is estimated to only ∼0.1% of all particles. Thermal behavior of other particles can be modeled as isothermal behavior. This work provides an indirect estimation of the particle's rotation rate in Saturn's rings from observations.     

The imprint of the equation of state on the axial w-modes of oscillating neutron stars

We discuss the dependence of the pulsation frequencies of the axial quasi-normal modes of a non-rotating neutron star upon the equation of state describing the star interior. The continued fraction method has been used to compute the complex frequencies for a set of equations of state based on different physical assumptions and spanning a wide range of stiffness. The numerical results show that axial gravitational waves carry relevant information on both the structure of neutron star matter and the nature of the hadronic interactions.     

Petrogenesis and geodynamic significance of silicic volcanism in the western Trans-Mexican Volcanic Belt: role of gabbroic cumulates

In the western Trans-Mexican Volcanic Belt voluminous silicic volcanism has been associated with the rifting of the Jalisco block from mainland Mexico. Rhyolitic volcanism started at 7.5 Ma after a major pulse of basaltic volcanism aged 11–8.5 Ma associated with slab detachment. This was followed by a second period, between 4.9 and 2.9 Ma, associated with rhyolitic domes and ignimbrite coexisting with basaltic volcanism. The similarity in rare earth element contents between basalts and rhyolites excludes a simple liquid line of descent. The low Ba and Sr contents and the ferroan character of the rhyolites suggest extensive fractional crystallization. Late Miocene–early Pliocene rhyolite Sr isotope values are only slightly more radiogenic than the basalts, whereas Nd isotope ratios are indistinguishable. We successfully modelled the 7.5–3 Ma silicic magmatism as a result of partial melting of crustal gabbroic complexes that we infer to have formed in the mid-lower crust due to the high-density Fe-enriched composition of the late Miocene basaltic volcanism. Slab rollback since ~7.5 Ma favoured decompression melting and arrival of additional mafic magmas that intruded in the lower crust. These basalts heated and melted the gabbroic complexes forming the silicic magmas, which subsequently underwent assimilation and fractional crystallization processes. The first silicic pulse was emplaced during a period of low tectonic activity. Extensional faulting since the Pliocene favours the eruption of both silicic magma and lesser amount of mafic lavas.     

PCBs and PAHs in sea-surface microlayer and sub-surface water samples of the Venice Lagoon (Italy)

Polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) are two classes of micropollutants intensively monitored and regulated due to their toxicity, persistency and wide diffusion. Their concentrations have been investigated in sea-microlayer (SML) and sub-surface water (SSW) samples collected at two sites of the Venice Lagoon, a fragile ecosystem highly influenced by industrial and anthropogenic emissions. The total sigmaPCB concentration varies from 0.45 ng/l to 2.1 ng/l in SSW while a clear enrichment is observed in the SML, where it ranges from 1.2 ng/l to 10.5 ng/l. The total sigmaPAH concentration shows marked differences between the two stations and varies from 12.4 ng/l to 266.8 ng/l in SSW; in SML it is more uniform and ranges from 19.6 ng/l to 178.9 ng/l. The enrichment factors are not larger than 1 for both pollutants in the 'dissolved' phase, while they are most significant for the 'particulate' phase (sigmaPCB: 5-9; sigmaPAH: 4-14).     

An empirically derived lunar gravity field

The heat-flow experiment is one of the Apollo Lunar Surface Experiment Package (ALSEP) instruments that was emplaced on the lunar surface on Apollo 15. This experiment is designed to make temperature and thermal property measurements in the lunar subsurface so as to determine the rate of heat loss from the lunar interior through the surface. About 45 days (1 1/2 lunations) of data has been analyzed in a preliminary way. This analysis indicates that the vertical heat flow through the regolith at one probe site is 3.3 × 10^–6 W/cm² (±15%). This value is approximately one-half the Earth's average heat flow. Further analysis of data over several lunations is required to demonstrate that this value is representative of the heat flow at the Hadley Rille site. The mean subsurface temperature at a depth of 1 m is approximately 252.4K at one probe site and 250.7K at the other. These temperatures are approximately 35K above the mean surface temperature and indicate that conductivity in the surficial layer of the Moon is highly temperature dependent. Between 1 and 1.5m, the rate of temperature increase as a function of depth is 1.75K/m (±2%) at the probe 1 site. In situ measurements indicate that the thermal conductivity of the regolith increases with depth. Thermal-conductivity values between 1.4 × 10^–4 and 2.5 × 10^–4 W/cm K were determined; these values are a factor of 7 to 10 greater than the values of the surface conductivity. If the observed heat flow at Hadley Base is representative of the moonwide rate of heat loss (an assumption which is not fully justified at this time), it would imply that overall radioactive heat production in the Moon is greater than in classes of meteorites that have formed the basis of Earth and Moon bulk composition models in the past.Lamont-Doherty Geological Observatory Contribution Number 1800.