Chemical speciation of arsenic in different marine organisms: Importance in monitoring studies

Arsenic is a widely distributed element in the marine environment. Inorganic and organic compounds have extremely different toxicological effects, and their characterization is thus of great utility when monitoring and assessing the impact of arsenic pollution. In this study both the levels of total arsenic and its chemical speciation were analyzed in several marine organisms collected from Cienfuegos Bay (Cuba) following an episode of acute As-contamination. Fish from the more impacted site were characterized by elevated concentrations of arsenic (up to 500 microg/g d.w.) and inorganic species represented the predominant forms in muscle tissues of these organisms.     

Quaternary adakite—Nb-enriched basalt association in the western Trans-Mexican Volcanic Belt: is there any slab melt evidence?

A spatial and temporal association between adakitic rocks and Nb-enriched basalts (NEB) is recognised for the first time in the western sector of the Trans-Mexican Volcanic Belt in the San Pedro–Cerro Grande Volcanic Complex (SCVC). The SCVC is composed of subalkalic intermediate to felsic rocks, spanning in composition from high-silica andesites to rhyolites, and by the young transitional hawaiite and mugearite lavas of Amado Nervo shield volcano. Intermediate to felsic rocks of the SCVC show many geochemical characteristics of typical adakites, such as high Sr/Y ratios (up to 180) and low Y (<18 ppm) and Yb contents. Mafic Amado Nervo rocks have high TiO₂ (1.5–2.3 wt%), Nb (14–27 ppm), Nb/La (0.5–0.9) and high absolute abundances of HFSE similar to those shown by NEB. However, the Sr and Nd isotopic signature of SCVC rocks is different from that shown by typical adakites and NEB. Although the adakites–NEB association has been traditionally considered as a strong evidence of slab-melting, we suggest that other processes can lead to its generation. Here, we show that parental magmas of adakitic rocks of the SCVC derive their adakitic characteristic from high-pressure crystal fractionation processes of garnet, amphibole and pyroxene of a normal arc basalt. On the other hand, Amado Nervo Na-alkaline parental magmas have been generated by sediment melting plus MORB-fluid flux melting of a heterogeneous mantle wedge, consisting of a mixture of depleted and an enriched mantle sources (90DM + 10EM). We cannot exclude a contribution to the subduction component of slab melts, because the component signature is dominated by sediment melt, but we argue that caution is needed in interpreting the adakites–NEB association in a genetic sense.     

A rapid approach to estimate the rockfall energies and distances at the base of rock cliffs

This paper presents a new methodology for estimating the expected energies and first impact distances at the base of a rock cliff, subject to the geometry and properties of the cliff and the representative block being known. The method is based on a sensitivity analysis, conducted by means of kinematic simulations and carried out for a large range of input parameters and their combinations, taking into account the uncertainty associated with their estimate. The proposed approach is validated by comparing predictions to experimental data and shows great potential for a quick qualitative hazard assessment.     

The genetic structure of the exotic ascidian Styela plicata (Tunicata) from Italian ports,with a re‐appraisal of its worldwide genetic pattern

The pleated ascidian Styela plicata (Lesueur, 1823) is a solitary species commonly found in ports and marinas around the world. It has been recorded in the Mediterranean region since the mid‐19th century. In the present work, the species’ genetic diversity was analysed, employing a 613‐bp portion of the mitochondrial cytochrome c oxidase subunit I (COI) gene from 149 individuals collected in 14 ports along Italian coasts at spatial scales ranging from 1 to approximately 2200 km. Haplotype and nucleotide diversity values were h = 0–0.933 (total h = 0.789) and π = 0–0.145 (total π = 0.0094), respectively. A general southward trend of increasing within‐population genetic diversity was observed. Analysis of molecular variance revealed significant genetic structuring but no significant differences were detected among basins, and no isolation by distance was found. Our data were integrated with the COI sequences available from previous studies and re‐analysed in order to investigate the possible routes of introduction of this ascidian into the Mediterranean Sea. The presence of the two COI haplogroups detected in previous molecular investigations on S. plicata at intercontinental spatial scale was confirmed in the Mediterranean Sea. The results revealed multiple introductions of S. plicata, although some locations appear to have experienced rapid expansion from few founding individuals with reduced genetic diversity. However, continuous introductions would confound the pattern deriving from single founder events and make it difficult to estimate the time needed for gene diffusion into established populations. This mixing of effects creates difficulties in understanding the past and current dynamics of this introduction, and managing this alien invasive ascidian whose genetic structure is continuously shuffled by vessel‐mediated transport.     

Influence of the North Atlantic Oscillation on winter rainfall in Calabria (southern Italy)

Seasonal rainfall amounts, directly responsible for availability of water resources on a specified area, are strongly dependent on the climate system. In order to highlight some features of such dependence, generally circulation indexes based on the difference in the sea level pressure between two geographic areas are taken into account. In the present study, the relationships between winter rainfall series observed in the Calabria region (southern Italy) and the North Atlantic Oscillation Index (NAOI) have been analysed. Firstly, a correlation analysis between precipitation and the NAOI was performed. Subsequently, the influence of the different phases of the NAO on the winter precipitation has been detected by a composite analysis, and by identifying changes in the behaviour of the probability density functions (gamma distribution) fitted on monthly rainfall. The results evidence a clear link existing between the phases of the climatic index and the amount of winter rainfall.     

Comparison of the FLUKA calculations with CAPRICE94 data on muons in atmosphere

In order to benchmark the three-dimensional calculation of the atmospheric neutrino flux based on the FLUKA Monte Carlo code, muon fluxes in the atmosphere have been computed and compared with data taken by the CAPRICE94 experiment at ground level and at different altitudes in the atmosphere. For this purpose only two additions have been introduced with respect to the neutrino flux calculation: the specific solar modulation corresponding to the period of data taking and the bending of charged particles in the atmosphere. Results are in good agreement with experimental data, although improvements in the model are possible. At this level, however, it is not possible to disentangle the interplay between the primary flux and the interaction model.     

Relativistic models of magnetars: the twisted torus magnetic field configuration

We find general relativistic solutions of equilibrium magnetic field configurations in magnetars, extending previous results of Colaiuda et al. Our method is based on the solution of the relativistic Grad–Shafranov equation, to which Maxwell's equations can be reduced. We obtain equilibrium solutions with the toroidal magnetic field component confined into a finite region inside the star, and the poloidal component extending to the exterior. These so-called twisted torus configurations have been found to be the final outcome of dynamical simulations in the framework of Newtonian gravity, and appear to be more stable than other configurations. The solutions include higher-order multipoles, which are coupled to the dominant dipolar field. We use arguments of minimal energy to constrain the ratio of the toroidal to the poloidal field.     

Detrending time series for astronomical variability surveys

We present a detrending algorithm for the removal of trends in time series. Trends in time series could be caused by various systematic and random noise sources such as cloud passages, changes of airmass, telescope vibration, CCD noise or defects of photometry. Those trends undermine the intrinsic signals of stars and should be removed. We determine the trends from subsets of stars that are highly correlated among themselves. These subsets are selected based on a hierarchical tree clustering algorithm. A bottom-up merging algorithm based on the departure from normal distribution in the correlation is developed to identify subsets, which we call clusters. After identification of clusters, we determine a trend per cluster by weighted sum of normalized light curves. We then use quadratic programming to detrend all individual light curves based on these determined trends. Experimental results with synthetic light curves containing artificial trends and events are presented. Results from other detrending methods are also compared. The developed algorithm can be applied to time series for trend removal in both narrow and wide field astronomy.     

Einstein Gravity Explorer–a medium-class fundamental physics mission

The Einstein Gravity Explorer mission (EGE) is devoted to a precise measurement of the properties of space-time using atomic clocks. It tests one of the most fundamental predictions of Einstein’s Theory of General Relativity, the gravitational redshift, and thereby searches for hints of quantum effects in gravity, exploring one of the most important and challenging frontiers in fundamental physics. The primary mission goal is the measurement of the gravitational redshift with an accuracy up to a factor 10⁴ higher than the best current result. The mission is based on a satellite carrying cold atom-based clocks. The payload includes a cesium microwave clock (PHARAO), an optical clock, a femtosecond frequency comb, as well as precise microwave time transfer systems between space and ground. The tick rates of the clocks are continuously compared with each other, and nearly continuously with clocks on earth, during the course of the 3-year mission. The highly elliptic orbit of the satellite is optimized for the scientific goals, providing a large variation in the gravitational potential between perigee and apogee. Besides the fundamental physics results, as secondary goals EGE will establish a global reference frame for the Earth’s gravitational potential and will allow a new approach to mapping Earth’s gravity field with very high spatial resolution. The mission was proposed as a class-M mission to ESA’s Cosmic Vision Program 2015–2025.